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The tribocorrosion failure mechanism of nickel-aluminium bronze (NAB) in different halide concentrations of seawater was studied using a pin-on-disc tribometer that was modified to conduct in-situ electrochemical detection during the sliding process. It has been reported that high-halide-concentration seawater provided a good lubricating effect, and thus reduced the coefficient of friction and wear rate of NAB during the tribocorrosion process. However, the existence of halide ions corroded the passive film and hindered the repassivation of the damaged areas in the wear track, resulting in an increased corrosion rate. In addition, the morphology of the wear scar revealed the occurrence of abrasive, delamination, and adhesive wear of NAB in seawater. For the whole range of halide concentration values, a positive synergy between wear and corrosion was proven, and the quantification of this synergy was discussed in detail. The results show that the corrosion-wear synergism was decreased with increasing halide concentration in seawater, and the corrosion-induced wear was dominant in the two synergistic components.


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Tribocorrosion behavior of nickel-aluminium bronze sliding against alumina under the lubrication by seawater with different halide concentrations

Show Author's information Beibei ZHANG1,2Jianzhang WANG1( )Junya YUAN1,2Fengyuan YAN1( )
State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China
University of Chinese Academy of Sciences, Beijing 100049, China

Abstract

The tribocorrosion failure mechanism of nickel-aluminium bronze (NAB) in different halide concentrations of seawater was studied using a pin-on-disc tribometer that was modified to conduct in-situ electrochemical detection during the sliding process. It has been reported that high-halide-concentration seawater provided a good lubricating effect, and thus reduced the coefficient of friction and wear rate of NAB during the tribocorrosion process. However, the existence of halide ions corroded the passive film and hindered the repassivation of the damaged areas in the wear track, resulting in an increased corrosion rate. In addition, the morphology of the wear scar revealed the occurrence of abrasive, delamination, and adhesive wear of NAB in seawater. For the whole range of halide concentration values, a positive synergy between wear and corrosion was proven, and the quantification of this synergy was discussed in detail. The results show that the corrosion-wear synergism was decreased with increasing halide concentration in seawater, and the corrosion-induced wear was dominant in the two synergistic components.

Keywords: friction, wear, tribocorrosion, halide ions

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Publication history

Received: 12 October 2017
Revised: 12 January 2018
Accepted: 24 April 2018
Published: 06 November 2018
Issue date: October 2019

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© The author(s) 2018

Acknowledgements

The work was financially supported by the National Natural Science Foundation of China (Grant No. 51405478) and CAS "Light of West China" Program.

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