SAKKA MM, ANTAR Z, ELLEUCH K, et al. Tribological response of an epoxy matrix filled with graphite and/or carbon nanotubes. Friction, 2017, 5(2): 171-182. https://doi.org/10.1007/s40544-017-0144-z
Reinforced polymer–matrix composites are widely used under sliding contact conditions in various boating and automotive applications. In this paper, the friction and wear of bulk epoxy and carbon filler reinforced epoxy composites have been investigated using a pin-on-disc tribometer. The effect of different fillers on the tribological behavior of an epoxy has been studied using treated and untreated carbon nanotubes, graphite, and a mixture of graphite and carbon nanotubes. Filler addition greatly enhances the tribological properties of the epoxy resin, by reducing the friction coefficient and the wear rate. In addition, it was found that the treated carbon nanotubes/epoxy composites have the best tribological behavior. Moreover, a correlation between contact temperature and friction coefficient is reported. Finally, the wear mechanisms were determined by scanning electronic microscopy.
Tribological response of an epoxy matrix filled with graphite and/or carbon nanotubes
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M. M. SAKKA1(
), Z. ANTAR1, K. ELLEUCH1, J. F. FELLER2
Laboratoire de Génie des Matériaux et Environnement, ENIS, Université de Sfax, SfaxBP. 1173-3038, Tunisia
Smart Plastics Group, European University of Brittany (UEB), LIMATB-UBS, Lorient56321, France
Abstract
Reinforced polymer–matrix composites are widely used under sliding contact conditions in various boating and automotive applications. In this paper, the friction and wear of bulk epoxy and carbon filler reinforced epoxy composites have been investigated using a pin-on-disc tribometer. The effect of different fillers on the tribological behavior of an epoxy has been studied using treated and untreated carbon nanotubes, graphite, and a mixture of graphite and carbon nanotubes. Filler addition greatly enhances the tribological properties of the epoxy resin, by reducing the friction coefficient and the wear rate. In addition, it was found that the treated carbon nanotubes/epoxy composites have the best tribological behavior. Moreover, a correlation between contact temperature and friction coefficient is reported. Finally, the wear mechanisms were determined by scanning electronic microscopy.
Keywords:wear, carbon nanotubes, epoxy composites, friction temperature
References(57)
[1]
Briscoe B J, Sinha S K. Tribology of polymeric solids and their composites. In Wear─Materials, Mechanism and Practice, 2005:223–267.
Yousef S. Polymer nanocomposite components: A case study on gears. In Light Weight Composite Structures in Transport Design, Manufacturing, Analysis and Performance. 2016: 385-420.
KoikeH, KidaK, SantosE C, RozwadowskaJ, KashimaY, KanemasuK. Self-lubrication of PEEK polymer bearings in rolling contact fatigue under radial loads. 49:30–38(2012)10.1016/j.triboint.2011.12.005
Juvonen T, Selenius M. Joint bearing surfaces and replacement joint design. In Joint Replacement Technology (Second Edition). Finland, 2014: 167-185.
[5]
Joshi M, Chatterjee U. Polymer nano-composite: An advanced material for aerospace applications. In Advanced Composite Materials for Aerospace Engineering, Processing, Properties and Applications. New Delhi, 2016: 241–264.
Friedrich K, Schlarb A. Tribology of polymeric nano- composites. In Tribology and Interface Engineering Series, No. 55. Series Editor. Briscoe B J, 2008.
[7]
Cho D-H, Bhushan B. Friction and wear of various polymer pairs used for label and wiper in labeling machine. Tribol Int 98:10–19(2016)
Larsen J, Hinge M. Temperature- and time dependency on high friction poly(styrene-co-butyl methacrylate) coated paper Christoffer Bjerremand. Tribol Int 103:261–265(2016)
LauxK A, Jean-FulcrandA, SueH J, BremnerT, WongJ S S. The influence of surface properties on sliding contact temperature and friction for polyetheretherketone (PEEK). 103:397–404(2016)10.1016/j.polymer.2016.09.064
KatiyarJ K, SinhaS K, KumarA. Friction and wear durability study of epoxy-based polymer (SU-8) composite coatings with talc and graphite as fillers. 362–363:199–208(2016)10.1016/j.wear.2016.06.011
Zhang L, Zhang G, Chang L, Wetzel B, Jim B, Wang Q. Distinct tribological mechanisms of silica nano-particles in epoxy composites reinforced with carbon nanotubes, Tribol Int 104:225–236(2016)
ZhangG, SebastianR, BurkhartT, FriedrichK. Role of monodispersed nanoparticles on the tribological behavior of conventional epoxy composites filled with carbon fibers and graphite lubricants. 292–293:176–187(2012)10.1016/j.wear.2012.05.012
Zhang M Q, Rong M Z, Yu S L, Wetzel B, Friedrich K. Effect of particle surface treatment on the tribological performance of epoxy based nano-composites. Wear 253:1086–1093(2002)
Suresha B, Chandramohan G, Renukappa M N, Siddaramaiah. Mechanical and tribological properties of glass–epoxy composites with and without graphite. J Appl Polym Sci 103:2472–2480(2007)
Chang L, Zhang Z, Zhang H, Friedrich K. Effect of nanoparticles on the tribological behavior of short carbon fibre reinforced poly(etherimide) composites. Tribol Int 38:966–973(2005)
Shalwan A, Yousif B F. Influence of date palm fibre and graphite filler on mechanical and wear characteristics of epoxy composites. Materials and Design 59:264–273(2014)
ChauhanS R, ThakurS. Effects of particle size, particle loading and sliding distance on the friction and wear properties of chemosphere particulate filled vinyl ester composites. 51:398–408(2013)10.1016/j.matdes.2013.03.071
Gojny F H, Schulte K. Functionalisation effect on the thermo- maechanical behiviour of multi-wall carbon nanotube/epoxy composite. Composite Science Technology 64:2303–2308(2004)
Allaoui A, Bai S, Cheng H M, Cheng J B. Mechanical and electrical properties of a MWNT/epoxy composite. Composite Science Technology 62:1993–1998(2002)
Chen W X, Li F, Han G, Xia J B, Wang L Y, Tu J P, Xu Z D. Tribological behavior of carbon-nanotube-filled PTFE composites. Tribol Lett 15:275–278(2003)
Chen W X, Tu J P, Wang L Y, Gan H Y, Xu Z D, Zhang X B. Tribological application of carbon nanotubes in a metal-based composite coating and composites. Carbon 41:215–222(2003)
Khare B N, Wilhite P, Quinn R C, Chen B, Schingler R H, Tran B, Imanaka H, So C R, Bauschlicher W, Meyyappan M. Functionalization of carbon nanotubes by ammonia glow-discharge: Experiments and modeling. J Phys Chem 108:8166–8172(2004)
Rodríguez M A, Gil L, Camero S, Fréty N, Santana Y, Caro J. Effects of the dispersion time on the microstructure and wear resistance of WC/Co-CNTs HVOF sprayed coatings. Surface Coat Technol 258:38–48(2014)
Kim M T, Rhee K Y, Lee J H, Hui D, Lau A K T. Property enhancement of a carbon fiber/epoxy composite by using carbon nanotubes. Composites: Part B 42:1257–1261(2011)
Yang K, Gu M, Guo Y, Pan X, Mu G. Effects of carbon nanotube functionalization on the mechanical and thermal properties of epoxy composites. Carbon 47:1723–1737(2009)
Jia J, Chen J, Zhou H, Hu L, Chen L. Comparative investigation on the wear and transfer behaviors of carbon fiber reinforced polymer composites under dry sliding and water lubrication. Compos Sci Technol 65:1139–1147(2005)
SunL, WarrenG L, O’ReillyJ Y, EverettW N, LeeS M, DavisD, LagoudasD, SueH-J. Mechanical properties of surface-functionalized SWCNT/epoxy composites. 46:320–328(2008)10.1016/j.carbon.2007.11.051
Cha J, Jin S, Shim J H, Park C S, Ryu H J. Functionalization of carbon nanotubes for fabrication of CNT/epoxy nano- composites. Materials & Design 95:1–8(2016)
Lu X, Wong K C, Wong P C, Mitchell K A R, Cotter J, Eadie D T. Surface characterization of polytetrafluoroethylene (PTFE) transfer films during rolling-sliding tribology tests using X-ray photoelectron spectroscopy. Wear 261(10):1155–1162(2006)
Suresha B, Siddaramaiah, Kishore, Seetharamu S, Kumaran PS. Investigations on the influence of graphite filler on dry sliding wear and abrasive wear behavior of carbon fabric reinforced epoxy composites. Wear 14:1405–1414(2009)
Davim J P, Cardoso R. Effect of the reinforcement (carbon or glass fibers) on friction and wear behaviour of the PEEK against steel surface at long dry sliding. Wear 266:795–799(2009)
Rose N, le Bras M, Bourbigot S, Delobel R. Thermal oxidative degradation of epoxy resins: evaluation of their heat resistance using invariant kinetic parameters. Polymer Degradation and Stability 45:387–397(1994)
Suresha B, Ramesh B N, Subbaya K M, Ravi Kumar B N, Chand Ramohan G. Influence of graphite filler on two-body abrasive wear behaviour of carbon fabric reinforced epoxy composites. Materials and Design 31:1833–1841(2010)
Gantayat S, Prusty G, Rout D R, Swain S K. Expanded graphite as a filler for epoxy matrix composites to improve their thermal. Mechanical and Electrical Properties 30:432–437(2015)
Dong B, Yang Z, Huang Y, Li H-L. Study on tribological properties of multi-walled carbon nanotubes/epoxy resin nano-composites. Tribol Lett 20(3–4):251–254(2005)
Luo Y, Zhao Y, Cai J, Duan Y, Du S. Effect of amino- functionalization on the interfacial adhesion of multi-walled carbon nanotubes/epoxy nano-composites. Materials & Design 33:405–412(2012)
Dong B, Yang Z, Huang Y, Li H-L. Study on tribological properties of multi-walled carbon nanotubes/epoxy resin nano composites. Tribol Lett 20:251–254(2005)
Chen W X, Tu J P, Wang L Y, Gan H Y, Xu Z D, Zhang X B. Tribological application of carbon nanotubes in a metal-based composite coating and composites. Carbon 41:215–222(2003)
Chen W X, Li F, Han G, Xia J B, Wang L Y, Tu J P, Xu Z D. Tribological behavior of carbon nanotube-filled PTFE composites. Tribol Lett 15:275–278(2003)
Chen W X, Tu J P, Xu Z D, Chen W L, Zhang X B, Cheng D H. Tribological properties of Ni–P-multi-walled carbon nanotubes electroless composite coating. Mater Lett 57:1256–1260(2003)
This work was supported by the national school of engineers of Sfax, Tunisia represented by the Laboratory of material engineering and environment (LGME) and the University of South Brittany, Lorient, France, and represented by the laboratory of material engineering of Brittany (LimatB), smart plastic group.
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