Journal Home > Volume 3 , Issue 3

Using an MFT-R4000 tester at room temperature, the leaf-surface wax of two desert plants, Ammopiptanthus mongolicus (AM) and Reaumuria soongorica (RS), was extracted and evaluated for its potential as a lubricant additive in polyalphaolefin (PAO) for steel–steel contact. Gas chromatography–mass spectrometry analysis was performed to identify the composition of the AM leaf-surface wax, and scanning electron microscopy and X-ray photoelectron spectroscopy were used to investigate its friction mechanisms. The results suggest that the leaf-surface wax could successfully reduce the friction and wear of steel–steel sliding pairs compared with PAO containing molybdenum dithiocarbamate additives. AM, in particular, showed high-performance wear resistance and friction-reducing properties. Its excellent tribological properties were attributed to the wax composition of leaf-surface fatty acids, alcohol, and esters.


menu
Abstract
Full text
Outline
About this article

Leaf-surface wax of desert plants as a potential lubricant additive

Show Author's information Yanqiu XIA1( )Xiaochun XU1Xin FENG1Guoxiong CHEN2( )
School of Energy Power and Mechanical Engineering, North China Electric Power University, Beijing 102206, China
Key Laboratory of Stress Physiology and Ecology in Cold and Arid Regions, Cold and Arid Regions Environmental and Engineering Research Institute, Chinese Academy of Sciences, Lanzhou 730000, China

Abstract

Using an MFT-R4000 tester at room temperature, the leaf-surface wax of two desert plants, Ammopiptanthus mongolicus (AM) and Reaumuria soongorica (RS), was extracted and evaluated for its potential as a lubricant additive in polyalphaolefin (PAO) for steel–steel contact. Gas chromatography–mass spectrometry analysis was performed to identify the composition of the AM leaf-surface wax, and scanning electron microscopy and X-ray photoelectron spectroscopy were used to investigate its friction mechanisms. The results suggest that the leaf-surface wax could successfully reduce the friction and wear of steel–steel sliding pairs compared with PAO containing molybdenum dithiocarbamate additives. AM, in particular, showed high-performance wear resistance and friction-reducing properties. Its excellent tribological properties were attributed to the wax composition of leaf-surface fatty acids, alcohol, and esters.

Keywords: lubricant additive, friction and wear, leaf-surface wax, Ammopiptanthus mongolicus

References(20)

[1]
Choudhary R B, Pande P P. Lubrication potential of boron compounds: An overview. Lubr Sci 14: 211–22 (1965)
[2]
Yan J, Zeng X, van der Heide E, Ren T. The tribological performance and tribochemical analysis of novel borate esters as lubricant additives in rapeseed oil. Tribol Int 71: 149–157 (2014)
[3]
Li J, Li Z, Ren T, Zeng X, van der Heide E. Hydrolytic stability and tribological properties of N-containing heterocyclic borate esters as lubricant additives in rapeseed oil. Tribol Int 73: 101–110 (2014)
[4]
Zhang J, Liu W M, Xue Q J. The friction and wear behaviors of some O-containing organic compounds as additives in liquid paraffin. Wear 219: 124–127 (1998)
[5]
Martin J M, Matta C, Bouchet M D B, Forest C, Le Mogne T, Dubois T, Mazarin M. Mechanism of friction reduction of unsaturated fatty acids as additives in diesel fuels. Friction 1(3): 252–258 (2013)
[6]
Anastopoulos G, Kalligeros S, Schinas P, Zannikos F. Effect of dicarboxylic acid esters on the lubricity of aviation kerosene for use in CI engines. Friction 1(3): 271–278 (2013)
[7]
Syahrullail S, Hariz M A, Abdul Hamid M K, Abu Bakar A R. friction characteristic of mineral oil containing palm fatty acid distillate using four ball tribo-tester original. Pro Eng 68: 166–171 (2013)
[8]
Kano M, Martin J M, Yoshida K, Yoshida K, DE Barros Bouchet M I. Super-low friction of ta-C coating in presence of oleic acid. Friction 2(2): 156–163 (2014)
[9]
Grossiord C, Varlot K, Martin J M, Le Mogne T, Esnouf C, Inoue K. MoS2 single sheet lubrication by molybdenum dithiocarbamate. Tribol Int 31: 737–743 (1998)
[10]
De Barros M I, Bouchet J, Raoult I, Mogne T L, Martin J M, Kasrai M, Yamada Y. Friction reduction by metal sulfides in boundary lubrication studied by XPS and XANES analyses. Wear 254: 863–870 (2003)
[11]
Muraki M, Wada H. Influence of the alkyl group of zinc dialkyldithiophosphate on the frictional characteristics of molybdenum dialkyldithiocarbamate under sliding conditions. Tribol Int 35: 857–863 (2002)
[12]
Muraki M, Yanagit Y, Sakaguchit K. Synergistic effect on frictional characteristics under rolling-sliding conditions due to a combination of molybdenum dialkyldithiocarbamate and zinc dialkyldithiophosphate. Tribol Int 30: 69–75 (1997)
[13]
Feng X, Xia Y. Tribological properties of gray cast iron lubricated using organic compounds containing Mo and ZnDTP additives. Lubr Sci 24: 153–164 (2012)
[14]
Francoa C M, Clarkeb P J, Tateb M E, Oadesb J M. Hydrophobic properties and chemical characterisation of natural water repellent materials in Australian sands. J Hydrol 231–232: 47–58 (2000)
[15]
Cornelia P V, Nastold P, Jetter R. Homologous very-long-chain 1,3-alkanediols and 3-hydroxyaldehydes in leaf cuticular waxes of Ricinus communis L. Phytochemistry 62: 433–438 (2003)
[16]
Ji X F, Jetter R. Very long chain alkylresorcinols accumulate in the intracuticular wax of rye (Secale cereale L.) leaves near the tissue surface. Phytochemistry 69: 1197–1207 (2008)
[17]
Xu S, Jiang P, Wang Z, Wang Y. Crystal structures and chemical composition of leaf surface wax depositions on the desert moss Syntrichia caninervis. Biochem Syst Ecol 37: 723-730 (2009)
[18]
Samuels L, Kunst L, Jetter R. Sealing plant surfaces: cuticular wax formation by epidermal cells. Plant Biol 59: 683–707 (2008)
[19]
DOI
[20]
Xia Y, Wang L, Liu X, Qiao Y. Tribological properties of phosphor bronze and nanocrystalline nickel coatings under PAO + MoDTC and ionic liquid lubricated condition. Tribol Lett 31: 149–158 (2008)
Publication history
Copyright
Acknowledgements
Rights and permissions

Publication history

Received: 09 February 2015
Revised: 03 December 2015
Accepted: 17 December 2015
Published: 27 June 2015
Issue date: June 2021

Copyright

© The author(s) 2015

Acknowledgements

The authors would like to thank the financial support for this work from the National Natural Science Foundation of China (No. 51575181).

Rights and permissions

This article is published with open access at Springerlink.com

Open Access: This article is distributed under the terms of the Creative Commons Attribution License which permits any use, distribution, and reproduction in any medium, provided the original author(s) and source are credited.

Return