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In this work, a super-low friction coefficient of 0.003 was found between a silicon nitride ball and a sapphire plate lubricated by phosphoric acid solution. The wear mainly occurred in the running-in period and disappeared after superlubricity was achieved. The friction coefficient was effectively reduced from 0.3 to 0.003 at a constant speed of 0.076 m/s, accompanied by a 12-nm-thickness film. The lubrication regime was indicated to change from boundary lubrication in the running-in period to elastohydrodynamic lubrication in the superlubricity period, which is also supported by the results of the friction coefficient versus sliding speed. In addition, the experimental results showed good agreement with theoretical calculations based on the elastohydrodynamic lubrication theory, suggesting a significant hydrodynamic effect of phosphoric acid on superlubricity.


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Hydrodynamic effect on the superlubricity of phosphoric acid between ceramic and sapphire

Show Author's information Mingming DENG1Chenhui ZHANG1,2( )Jinjin LI1Liran MA1Jianbin LUO1
State Key Laboratory of Tribology, Tsinghua University, Beijing, 100084, China
Shenzhen Key Laboratory of Micro-Nano Manufacturing, Research Institute of Tsinghua University in Shenzhen, Shenzhen, 518057, China

Abstract

In this work, a super-low friction coefficient of 0.003 was found between a silicon nitride ball and a sapphire plate lubricated by phosphoric acid solution. The wear mainly occurred in the running-in period and disappeared after superlubricity was achieved. The friction coefficient was effectively reduced from 0.3 to 0.003 at a constant speed of 0.076 m/s, accompanied by a 12-nm-thickness film. The lubrication regime was indicated to change from boundary lubrication in the running-in period to elastohydrodynamic lubrication in the superlubricity period, which is also supported by the results of the friction coefficient versus sliding speed. In addition, the experimental results showed good agreement with theoretical calculations based on the elastohydrodynamic lubrication theory, suggesting a significant hydrodynamic effect of phosphoric acid on superlubricity.

Keywords: film thickness, hydrodynamic lubrication, liquid superlubricity, phosphoric acid

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Publication history

Received: 16 May 2014
Accepted: 26 May 2014
Published: 19 June 2014
Issue date: June 2014

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© The author(s) 2014

Acknowledgements

The work is financially supported by the National Key Basic Research (973) Program of China (No. 2013CB934200), and the National Natural Science Foundation of China (Nos. 51222507, 51335005, 51321092).

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