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Research Article | Open Access

Mechanism of friction reduction of unsaturated fatty acids as additives in diesel fuels

Jean Michel MARTIN1,*( )Christine MATTA1Maria-Isabel De Barros BOUCHET1Cyrielle FOREST1Thierry Le MOGNE1Thomas DUBOIS2Michael MAZARIN2
Laboratory of Tribology and System Dynamics, Ecole Centrale de Lyon, 69134 Ecully, France
TOTAL, CReS, BP22, 69360 Solaize Cedex, France
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Abstract

This paper investigates the effect of unsaturated fatty acid additives on the lubricating properties of a biodiesel, composed of a blend of fatty acid methyl esters (FAMEs) and a conventional diesel fuel. The presence of fatty acids as additives for biodiesel improves their lubricating properties at elevated temperature conditions. The formation of a protective lubricating tribochemical film on the steel contact surfaces has been evidenced. Elevated temperature conditions and possibly oxygen are needed to form this film that reduces friction and limits wear. Several analytical tools have revealed the insulating nature of the formed tribofilm and its chemical properties. Friction-induced reticulation is thought to play a major role in the growth of this insulating film.

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Friction
Pages 252-258

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Cite this article:
MARTIN JM, MATTA C, BOUCHET M-IDB, et al. Mechanism of friction reduction of unsaturated fatty acids as additives in diesel fuels. Friction, 2013, 1(3): 252-258. https://doi.org/10.1007/s40544-013-0022-2

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Received: 07 June 2013
Revised: 02 August 2013
Accepted: 05 August 2013
Published: 06 September 2013
© The author(s) 2013

This article is published with open access at Springerlink.com

Open Access: This article is distributed under the terms of the Creative Commons Attribution License which permits any use, distribution, and reproduction in any medium, provided the original author(s) and source are credited.