Ultrabroad band microwave absorption from hierarchical MoO3/TiO2/Mo2TiC2Tx hybrids via annealing treatment

Feiyue HU; Fan ZHANG; Xiaohan WANG; Yaya LI; Hailong WANG; Rui ZHANG; Hongxia LI; Bingbing FAN

doi:10.1007/s40145-022-0624-0

Journal of Advanced Ceramics 2022, 11(9): 1466-1478 https://doi.org/10.1007/s40145-022-0624-0

Research Article |

Open Access | Issue | Published: 05 September 2022

Ultrabroad band microwave absorption from hierarchical MoO₃/TiO₂/Mo₂TiC₂T_x hybrids via annealing treatment

Show Author's Information Hide Author's Information Feiyue HU^{^a}, Fan ZHANG^{^a}, Xiaohan WANG^{^a}, Yaya LI^{^a}, Hailong WANG^{^a}, Rui ZHANG^{^a^,^b}, Hongxia LI^{^c}, Bingbing FAN^{^a}(

)

aSchool of Material Science and Engineering, Zhengzhou University, Zhengzhou 450001, China

bSchool of Materials Science and Engineering, Luoyang Institute of Science and Technology, Luoyang 471023, China

cSinosteel Luoyang Institute of Refractories Research Co., Ltd., Luoyang 471039, China

Keywords:

impedance matching, dielectric loss, interfacial polarization, MoO₃/TiO₂/Mo₂TiC₂T_x composites, Mo₂TiC₂T_x MXene, electromagnetic wave absorption (EMA)

Cite this article:

HU F, ZHANG F, WANG X, et al. Ultrabroad band microwave absorption from hierarchical MoO₃/TiO₂/Mo₂TiC₂T_x hybrids via annealing treatment. Journal of Advanced Ceramics, 2022, 11(9): 1466-1478. https://doi.org/10.1007/s40145-022-0624-0

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Abstract Full text Electronic supplementary material About this article

Abstract

Two-dimensional (2D) transition metal carbide MXene-based materials hold great potentials applied for new electromagnetic wave (EMW) absorbers. However, the application of MXenes in the field of electromagnetic wave absorption (EMA) is limited by the disadvantages of poor impedance matching, single loss mechanism, and easy oxidation. In this work, MoO₃/TiO₂/Mo₂TiC₂T_x hybrids were prepared by the annealing-treated Mo₂TiC₂T_x MXene and uniform MoO₃ and TiO₂ oxides in-situ grew on Mo₂TiC₂T_x layers. At the annealing temperature of 300 ℃, the minimum reflection loss (RL_min) value of MoO₃/TiO₂/Mo₂TiC₂T_x reaches −30.76 dB (2.3 mm) at 10.18 GHz with a significantly broadening effective absorption bandwidth (EAB) of 8.6 GHz (1.8 mm). The in-situ generated oxides creating numerous defects and heterogeneous interfaces enhance dipolar and interfacial polarizations and optimize the impedance matching of Mo₂TiC₂T_x. Considering the excellent overall performance, the MoO₃/TiO₂/Mo₂TiC₂T_x hybrids can be a promising candidate for EMA.

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Ultrabroad band microwave absorption from hierarchical MoO₃/TiO₂/Mo₂TiC₂T_x hybrids via annealing treatment

Show Author's information Hide Author's Information Feiyue HU^{^a}, Fan ZHANG^{^a}, Xiaohan WANG^{^a}, Yaya LI^{^a}, Hailong WANG^{^a}, Rui ZHANG^{^a^,^b}, Hongxia LI^{^c}, Bingbing FAN^{^a}(

)

aSchool of Material Science and Engineering, Zhengzhou University, Zhengzhou 450001, China

bSchool of Materials Science and Engineering, Luoyang Institute of Science and Technology, Luoyang 471023, China

cSinosteel Luoyang Institute of Refractories Research Co., Ltd., Luoyang 471039, China

Abstract

Keywords: impedance matching, dielectric loss, interfacial polarization, MoO₃/TiO₂/Mo₂TiC₂T_x composites, Mo₂TiC₂T_x MXene, electromagnetic wave absorption (EMA)

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Publication history

Received: 05 May 2022

Revised: 10 June 2022

Accepted: 16 June 2022

Published: 05 September 2022

Issue date: September 2022

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Acknowledgements

This work was financially supported by the National Natural Science Foundation of China (Nos. U2004177 and U21A2064), Outstanding Youth Fund of Henan Province (No. 212300410081), and Support Plan for Scientific and Technological Innovation Talents in Colleges and Universities of Henan Province (No. 22HASTIT001). Bingbing FAN would like to thank The Research and Entrepreneurship Start-up Projects for Overseas Returned Talents.

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