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Research Article | Open Access

Thermal conductivity of boron carbide under fast neutron irradiation

Zhixue QUa( )Chuanjin YUaYitong WEIaXiping SUbAibing DUb
Faculty of Materials and Manufacturing, Key Laboratory of Advanced Functional Materials, Education Ministry of China, Beijing University of Technology, Beijing 100124, China
China Institute of Atomic Energy, Beijing 102413, China
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Due to the complex products and irradiation-induced defects, it is hard to understand and even predict the thermal conductivity variation of materials under fast neutron irradiation, such as the abrupt degradation of thermal conductivity of boron carbide (B4C) at the very beginning of the irradiation process. In this work, the contributions of various irradiation-induced defects in B4C primarily consisting of the substitutional defects, Frenkel defect pairs, and helium bubbles were re-evaluated separately and quantitatively in terms of the phonon scattering theory. A theoretical model with an overall consideration of the contributions of all these irradiation-induced defects was proposed without any adjustable parameters, and validated to predict the thermal conductivity variation under irradiation based on the experimental data of the unirradiated, irradiated, and annealed B4C samples. The predicted thermal conductivities by this model show a good agreement with the experimental data after irradiation. The calculation results and theoretical analysis in light of the experimental data demonstrate that the substitutional defects of boron atoms by lithium atoms, and the Frenkel defect pairs due to the collisions with the fast neutrons, rather than the helium bubbles with strain fields surrounding them, play determining roles in the abrupt degradation of thermal conductivity with burnup.


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Journal of Advanced Ceramics
Pages 482-494
Cite this article:
QU Z, YU C, WEI Y, et al. Thermal conductivity of boron carbide under fast neutron irradiation. Journal of Advanced Ceramics, 2022, 11(3): 482-494.








Web of Science






Received: 16 October 2021
Accepted: 14 January 2022
Published: 11 February 2022
© The Author(s) 2022.

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