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Research Article | Open Access

Precise control of surface oxygen vacancies in ZnO nanoparticles for extremely high acetone sensing response

Jihyun LEEa,Youngmoon CHOIb,Byoung Joon PARKcJeong Woo HANc,dHyun-Sook LEEa( )Jong Hyeok PARKb( )Wooyoung LEEa( )
Department of Materials Science and Engineering, Yonsei University, Seoul 03722, Republic of Korea
Department of Chemical and Biological Engineering, Yonsei University, Seoul 03722, Republic of Korea
Department of Chemical Engineering, Pohang University of Science and Technology, Pohang 37673, Republic of Korea
Institute for Convergence Research and Education in Advanced Technology, Yonsei University, Seoul 03722, Republic of Korea

† Jihyun Lee and Youngmoon Choi contributed equally to this work.

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Abstract

ZnO has been studied intensely for chemical sensors due to its high sensitivity and fast response. Here, we present a simple approach to precisely control oxygen vacancy contents to provide significantly enhanced acetone sensing performance of commercial ZnO nanopowders. A combination of H2O2 treatment and thermal annealing produces optimal surface defects with oxygen vacancies on the ZnO nanoparticles (NPs). The highest response of ~27,562 was achieved for 10 ppm acetone in 0.125 M H2O2 treated/annealed ZnO NPs at the optimal working temperature of 400 ℃, which is significantly higher than that of reported so far in various acetone sensors based on metal oxide semiconductors (MOSs). Furthermore, first-principles calculations indicate that pre-adsorbed O formed on the surface of H2O2 treated ZnO NPs can provide favorable adsorption energy, especially for acetone detection, due to strong bidentate bonding between carbonyl C atom of acetone molecules and pre-adsorbed O on the ZnO surface. Our study demonstrates that controlling surface oxygen vacancies by H2O2 treatment and re-annealing at optimal temperature is an effective method to improve the sensing properties of commercial MOS materials.

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Journal of Advanced Ceramics
Pages 769-783
Cite this article:
LEE J, CHOI Y, PARK BJ, et al. Precise control of surface oxygen vacancies in ZnO nanoparticles for extremely high acetone sensing response. Journal of Advanced Ceramics, 2022, 11(5): 769-783. https://doi.org/10.1007/s40145-022-0570-x

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Received: 29 September 2021
Revised: 20 December 2021
Accepted: 11 January 2022
Published: 20 April 2022
© The Author(s) 2022.

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