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Research Article | Open Access

Inactive Al3+-doped La(CoCrFeMnNiAlx)1/(5+x)O3 high-entropy perovskite oxides as high performance supercapacitor electrodes

Meng GUO, Yufeng LIU, Fengnian ZHANG, Fuhao CHENG, Chufei CHENG, Yang MIAO( ), Feng GAO, Jun YU
College of Materials Science and Engineering, Taiyuan University of Technology, Taiyuan 030024, China
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Abstract

A series of high-entropy perovskite oxides (HEPOs) La(CoCrFeMnNiAlx)1/(5+x)O3−δ (x = 0.4, 0.5, 0.6, and 0.7) have been synthesized by coprecipitation method combined with calcination process and explored as electrodes for supercapacitors. The crystal structure, microstructure, and elemental composition of HEPOs were investigated by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), and energy-dispersive X-ray spectroscopy (EDS) in detail. The electrochemical properties of HEPOs as supercapacitor electrodes were elucidated. The specific capacitances of HEPOs (x = 0.4, 0.5, 0.6, and 0.7) are 281.84, 353.65, 325.60, and 259.30 F/g at the current density of 1 A/g, respectively. After 2000 cycles, the specific capacitances of HEPOs (x = 0.4, 0.5, 0.6, and 0.7) remain 85.01%, 88.61%, 86.37%, and 91.25%, respectively. Such outstanding electrochemical properties can be attributed to the entropy-stabilized structure caused by mixed six cations in B-site and the Al3+-doping suppressing active ion aggregation during charge–discharge process. This research highlights the potential of HEPOs as electrodes for supercapacitors.

Keywords

high-entropy oxides (HEOxs)perovskite structureAl3+-dopingsupercapacitors

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Journal of Advanced Ceramics
Volume 11 Issue 5,
May 2022
Pages 742-753
DOI: 10.1007/s40145-022-0568-4
Cite this article:
GUO M, LIU Y, ZHANG F, et al. Inactive Al3+-doped La(CoCrFeMnNiAlx)1/(5+x)O3 high-entropy perovskite oxides as high performance supercapacitor electrodes. Journal of Advanced Ceramics, 2022, 11(5): 742-753. https://doi.org/10.1007/s40145-022-0568-4

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Received: 31 August 2021
Revised: 24 December 2021
Accepted: 08 January 2022
Published: 20 April 2022
© The Author(s) 2022.

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