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Research Article | Open Access

Realizing enhanced energy storage and hardness performances in 0.90NaNbO3–0.10Bi(Zn0.5Sn0.5)O3 ceramics

Xiaoyan DONGaXu LIbHongyun CHENaQinpeng DONGaJiaming WANGaXiang WANGaYue PANaXiuli CHENa( )Huanfu ZHOUa
Collaborative Innovation Center for Exploration of Hidden Nonferrous Metal Deposits and Development of New Materials in Guangxi, Key Laboratory of Nonferrous Materials and New Processing Technology, Ministry of Education, School of Materials Science and Engineering, Guilin University of Technology, Guilin 541004, China
College of Materials Science and Engineering, Sichuan University, Chengdu 610064, China
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Abstract

Ceramic dielectric capacitors have a broad scope of application in pulsed power supply devices. Relaxor behavior has manifested decent energy storage capabilities in dielectric materials due to its fast polarization response. In addition, an ultrahigh energy storage density can also be achieved in NaNbO3 (NN)-based ceramics by combining antiferroelectric and relaxor characteristics. Most of the existing reports about lead-free dielectric ceramics, nevertheless, still lack the relevant research about domain evolution and relaxor behavior. Therefore, a novel lead-free solid solution, (1−x)NaNbO3xBi(Zn0.5Sn0.5)O3 (abbreviated as xBZS, x = 0.05, 0.10, 0.15, and 0.20) was designed to analyze the domain evolution and relaxor behavior. Domain evolutions in xBZS ceramics confirmed the contribution of the relaxor behavior to their decent energy storage characteristics caused by the fast polarization rotation according to the low energy barrier of polar nanoregions (PNRs). Consequently, a high energy storage density of 3.14 J/cm3 and energy efficiency of 83.30% are simultaneously available with 0.10BZS ceramics, together with stable energy storage properties over a large temperature range (20–100 ℃) and a wide frequency range (1–200 Hz). Additionally, for practical applications, the 0.10BZS ceramics display a high discharge energy storage density (Wdis ≈ 1.05 J/cm3), fast discharge rate (t0.9 ≈ 60.60 ns), and high hardness (H ≈ 5.49 GPa). This study offers significant insights on the mechanisms of high performance lead-free ceramic energy storage materials.

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References

[1]
Wang G, Lu ZL, Li Y, et al. Electroceramics for high-energy density capacitors: Current status and future perspectives. Chem Rev 2021, 121: 61246172.
[2]
Chu B, Zhou X, Ren K, et al. A dielectric polymer with high electric energy density and fast discharge speed. Science 2006, 313: 334336.
[3]
Zhao PY, Cai ZM, Chen LL, et al. Ultra-high energy storage performance in lead-free multilayer ceramic capacitors via a multiscale optimization strategy. Energy Environ Sci 2020, 13: 48824890.
[4]
Qi H, Xie AW, Tian A, et al. Superior energy-storage capacitors with simultaneously giant energy density and efficiency using nanodomain engineered BiFeO3–BaTiO3– NaNbO3 lead-free bulk ferroelectrics. Adv Energy Mater 2019, 10: 1903338.
[5]
Han K, Luo NN, Mao SF, et al. Ultrahigh energy-storage density in A-/B-site co-doped AgNbO3 lead-free antiferroelectric ceramics: Insight into the origin of antiferroelectricity. J Mater Chem A 2019, 7: 2629326301.
[6]
Xing J, Huang Y, Xu Q, et al. Realizing high comprehensive energy storage and ultrahigh hardness in lead-free ceramics. ACS Appl Mater Interfaces 2021, 13: 2847228483.
[7]
Li X, Cheng Y, Wang F, et al. Enhancement of energy storage and hardness of (Na0.5Bi0.5)0.7Sr0.3TiO3-based relaxor ferroelectrics via introducing Ba(Mg1/3Nb2/3)O3. Chem Eng J 2022, 431: 133441.
[8]
Luo BC, Wang XH, Tian EK, et al. Enhanced energy-storage density and high efficiency of lead-free CaTiO3–BiScO3 linear dielectric ceramics. ACS Appl Mater Interfaces 2017, 9: 1996319972.
[9]
Dai Z, Xie J, Liu W, et al. Effective strategy to achieve excellent energy storage properties in lead-free BaTiO3-based bulk ceramics. ACS Appl Mater Interfaces 2020, 12: 3028930296.
[10]
Luo NN, Han K, Cabral MJ, et al. Constructing phase boundary in AgNbO3 antiferroelectrics: Pathway simultaneously achieving high energy density and efficiency. Nat Commun 2020, 11: 4824.
[11]
Yuan QB, Li G, Yao FZ, et al. Simultaneously achieved temperature-insensitive high energy density and efficiency in domain engineered BaTiO3–Bi(Mg0.5Zr0.5)O3 lead-free relaxor ferroelectrics. Nano Energy 2018, 52: 203210.
[12]
Li X, Chen XL, Sun J, et al. Novel lead-free ceramic capacitors with high energy density and fast discharge performance. Ceram Int 2020, 46: 34263432.
[13]
Zhou XF, Qi H, Yan ZN, et al. Superior thermal stability of high energy density and power density in domain-engineered Bi0.5Na0.5TiO3–NaTaO3 relaxor ferroelectrics. ACS Appl Mater Interfaces 2019, 11: 4310743115.
[14]
Qi H, Zuo RZ, Xie AW, et al. Ultrahigh energy-storage density in NaNbO3-based lead-free relaxor antiferroelectric ceramics with nanoscale domains. Adv Funct Mater 2019, 29: 1903877.
[15]
Dong XY, Li X, Chen XL, et al. High energy storage density and power density achieved simultaneously in NaNbO3-based lead-free ceramics via antiferroelectricity enhancement. J Materiomics 2021, 7: 629639.
[16]
Xie AW, Qi H, Zuo RZ. Achieving remarkable amplification of energy-storage density in two-step sintered NaNbO3–SrTiO3 antiferroelectric capacitors through dual adjustment of local heterogeneity and grain scale. ACS Appl Mater Interfaces 2020, 12: 1946719475.
[17]
Ye JM, Wang GS, Chen XF et al. Enhanced antiferroelectricity and double hysteresis loop observed in lead-free (1−x)NaNbO3xCaSnO3 ceramics. Appl Phys Lett 2019, 114: 122901.
[18]
Liu ZY, Lu JS, Mao YQ, et al. Energy storage properties of NaNbO3–CaZrO3 ceramics with coexistence of ferroelectric and antiferroelectric phases. J Eur Ceram Soc 2018, 38: 49394945.
[19]
Ye JM, Wang GS, Zhou MX, et al. Excellent comprehensive energy storage properties of novel lead-free NaNbO3-based ceramics for dielectric capacitor applications. J Mater Chem C 2019, 7: 56395645.
[20]
Luo NN, Han K, Zhuo FP, et al. Design for high energy storage density and temperature-insensitive lead-free antiferroelectric ceramics. J Mater Chem C 2019, 7: 49995008.
[21]
Chen XL, Li X, Sun J, et al. Achieving ultrahigh energy storage density and energy efficiency simultaneously in barium titanate based ceramics. Appl Phys A 2020, 126: 146.
[22]
Zhou MX, Liang RH, Zhou ZY, et al. Superior energy storage properties and excellent stability of novel NaNbO3-based lead-free ceramics with A-site vacancy obtained via a Bi2O3 substitution strategy. J Mater Chem A 2018, 6: 1789617904.
[23]
Hosogi Y, Shimodaira Y, Kato H, et al. Role of Sn2+ in the band structure of SnM2O6 and Sn2M2O7 (M = Nb and Ta) and their photocatalytic properties. Chem Mater 2008, 20: 12991307.
[24]
Hu CH, Yin XH, Wang DH, et al. First-principles studies of electronic, optical, and mechanical properties of γ-Bi2Sn2O7. Chin Phys B 2016, 25: 067801.
[25]
Xing J, Huang YL, Wu B, et al. Energy storage behavior in ErBiO3-doped (K,Na)NbO3 lead-free piezoelectric ceramics. ACS Appl Electron Mater 2020, 2: 37173727.
[26]
Yang ZT, Du HL, Jin L, et al. Realizing high comprehensive energy storage performance in lead-free bulk ceramics via designing an unmatched temperature range. J Mater Chem A 2019, 7: 2725627266.
[27]
Chao LM, Hou YD, Zheng MP, et al. High dense structure boosts stability of antiferroelectric phase of NaNbO3 polycrystalline ceramics. Appl Phys Lett 2016, 108: 212902.
[28]
Qu N, Du HL, Hao XH. A new strategy to realize high comprehensive energy storage properties in lead-free bulk ceramics. J Mater Chem C 2019, 7: 79938002.
[29]
Uchino K, Nomura S. Critical exponents of the dielectric constants in diffused-phase-transition crystals. Ferroelectrics 1982, 44: 5561.
[30]
Ji HF, Wang DW, Bao WC, et al. Ultrahigh energy density in short-range tilted NBT-based lead-free multilayer ceramic capacitors by nanodomain percolation. Energy Storage Mater 2021, 38: 113120.
[31]
Chen HY, Shi JP, Chen XL, et al. Excellent energy storage properties and stability of NaNbO3–Bi(Mg0.5Ta0.5)O3 ceramics by introducing (Bi0.5Na0.5)0.7Sr0.3TiO3. J Mater Chem A 2021, 9: 47894799.
[32]
Yang ZT, Du HL, Jin L, et al. A new family of sodium niobate-based dielectrics for electrical energy storage applications. J Eur Ceram Soc 2019, 39: 28992907.
[33]
Fan YZ, Zhou ZY, Liang RH, et al. Designing novel lead-free NaNbO3-based ceramic with superior comprehensive energy storage and discharge properties for dielectric capacitor applications via relaxor strategy. J Eur Ceram Soc 2019, 39: 47704777.
[34]
Bian JJ, Otonicar M, Spreitzer M, et al. Structural evolution, dielectric and energy storage properties of Na(Nb1−xTax)O3 ceramics prepared by spark plasma sintering. J Eur Ceram Soc 2019, 39: 23392347.
[35]
Huan Y, Wei T, Wang XZ, et al. Achieving ultrahigh energy storage efficiency in local-composition gradient-structured ferroelectric ceramics. Chem Eng J 2021, 425: 129506.
[36]
Zhou MX, Liang RH, Zhou ZY, et al. Novel BaTiO3-based lead-free ceramic capacitors featuring high energy storage density, high power density, and excellent stability. J Mater Chem C 2018, 6: 85288537.
[37]
Xie SX, Xu JG, Chen Y, et al. Indentation behavior and mechanical properties of tungsten/chromium co-doped bismuth titanate ceramics sintered at different temperatures. Materials 2018, 11: 503.
[38]
Yang ZT, Gao F, Du HL, et al. Grain size engineered lead-free ceramics with both large energy storage density and ultrahigh mechanical properties. Nano Energy 2019, 58: 768777.
[39]
Zheng MP, Hou YD, Yan XD, et al. A highly dense structure boosts energy harvesting and cycling reliabilities of a high-performance lead-free energy harvester. J Mater Chem C 2017, 5: 78627870.
[40]
Wang XY, Venkataraman LK, Tan C, et al. Fracture behavior in electrically poled alkaline bismuth- and potassium-based lead-free piezoceramics using Vickers indentation. Scripta Mater 2021, 194: 113647.
[41]
Wu LW, Wang XH, Li LT. Lead-free BaTiO3–Bi(Zn2/3Nb1/3)O3 weakly coupled relaxor ferroelectric materials for energy storage. RSC Adv 2016, 6: 1427314282.
[42]
Liu LJ, Huang YM, Su CX, et al. Space-charge relaxation and electrical conduction in K0.5Na0.5NbO3 at high temperatures. Appl Phys A 2011, 104: 10471051.
[43]
Sui JN, Fan HQ, Hu B, et al. High temperature stable dielectric properties and enhanced energy-storage performance of (1−x)(0.85Na0.5Bi0.5TiO3–0.15Ba0.8Ca0.2Ti0.8Zr0.2O3)– xK0.5Na0.5NbO3 lead-free ceramics. Ceram Int 2018, 44: 1805418059.
[44]
Gao J, Zhang YC, Zhao L, et al. Enhanced antiferroelectric phase stability in La-doped AgNbO3: Perspectives from the microstructure to energy storage properties. J Mater Chem A 2019, 7: 22252232.
[45]
Yin J, Li CY, Wu B, et al. Defect-induced superior piezoelectric response in perovskite KNbO3. J Eur Ceram Soc 2021, 41: 25062513.
Journal of Advanced Ceramics
Pages 729-741
Cite this article:
DONG X, LI X, CHEN H, et al. Realizing enhanced energy storage and hardness performances in 0.90NaNbO3–0.10Bi(Zn0.5Sn0.5)O3 ceramics. Journal of Advanced Ceramics, 2022, 11(5): 729-741. https://doi.org/10.1007/s40145-022-0566-6

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Received: 28 July 2021
Revised: 09 November 2021
Accepted: 08 January 2022
Published: 21 March 2022
© The Author(s) 2022.

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