AI Chat Paper
Note: Please note that the following content is generated by AMiner AI. SciOpen does not take any responsibility related to this content.
{{lang === 'zh_CN' ? '文章概述' : 'Summary'}}
{{lang === 'en_US' ? '中' : 'Eng'}}
Chat more with AI
Powered by AMiner. Clicking this button will take you away from SciOpen.
Home Journal of Advanced Ceramics Article
PDF (1.9 MB)
Cite
EndNote(RIS) BibTeX
Collect
Submit Manuscript AI Chat Paper
Show Outline
Outline
Show full outline
Hide outline
Outline
Show full outline
Hide outline
Research Article | Open Access

Achieving ultra-broadband electromagnetic wave absorption in high-entropy transition metal carbides (HE TMCs)

Weiming ZHANGa, Huimin XIANGa, Fu-Zhi DAIa, Biao ZHAOb, Shijiang WUc, Yanchun ZHOUa( )
Science and Technology on Advanced Functional Composite Laboratory, Aerospace Research Institute of Materials & Processing Technology, Beijing 100076, China
Henan Key Laboratory of Aeronautical Materials and Application Technology, School of Material Science and Engineering, Zhengzhou University of Aeronautics, Zhengzhou 450046, China
Zibo Firststar New Material Incorporated Co., Ltd., Zibo 255000, China
Show Author Information

Graphical Abstract

Abstract

Electronic devices pervade everyday life, which has triggered severe electromagnetic (EM) wave pollution. To face this challenge, developing EM wave absorbers with ultra-broadband absorption capacity is critically required. Currently, nano-composite construction has been widely utilized to realize impedance match and broadband absorption. However, complex experimental procedures, limited thermal stability, and interior oxidation resistance are still unneglectable issues. Therefore, it is appealing to realize ultra-broadband EM wave absorption in single-phase materials with good stability. Aiming at this target, two high-entropy transition metal carbides (HE TMCs) including (Zr,Hf,Nb,Ta)C (HE TMC-2) and (Cr,Zr,Hf,Nb,Ta)C (HE TMC-3) are designed and synthesized, of which the microwave absorption performance is investigated in comparison with previously reported (Ti,Zr,Hf,Nb,Ta)C (HE TMC-1). Due to the synergistic effects of dielectric and magnetic losses, HE TMC-2 and HE TMC-3 exhibit better impedance match and wider effective absorption bandwidth (EAB). In specific, the exclusion of Ti element in HE TMC-2 endows it optimal minimum reflection loss (RLmin) and EAB of -41.7 dB (2.11 mm, 10.52 GHz) and 3.5 GHz (at 3.0 mm), respectively. Remarkably, the incorporation of Cr element in HE TMC-3 significantly improves the impedance match, thus realizing EAB of 10.5, 9.2, and 13.9 GHz at 2, 3, and 4 mm, respectively. The significance of this study lays on realizing ultra-broadband capacity in HE TMC-3 (Cr, Zr, Hf, Nb, Ta), demonstrating the effectiveness of high-entropy component design in tailoring the impedance match.

Keywords

transition metal carbide (TMC)high-entropy ceramicselectromagnetic (EM) wave absorptiondielectric and magnetic loss couplingultra-broadband absorption

References

[1]
Golio J. The RF and Microwave Handbook. Boca Raton, USA: CRC Press, 2001.
Crossref
[2]
Jamshed MA, Héliot F, Brown TWC. A survey on electromagnetic risk assessment and evaluation mechanism for future wireless communication systems. IEEE J Electromagn RF Microw Med Biol 2020, 4: 24-36.
Crossref Google Scholar
[3]
Mishra RK, Dutta A, Mishra P, et al. Recent progress in electromagnetic absorbing materials. In Advanced Materials for Electromagnetic Shielding: Fundamentals, Properties, and Applications. Jaroszewski M, Thomas S, Rane AV, Ed. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2018: 147-166.
Crossref
[4]
Yin PF, Zhang LM, Feng X, et al. Recent progress in ferrite microwave absorbing composites. Integr Ferroelectr 2020, 211: 82-101.
Crossref Google Scholar
[5]
Neelakanta P. Handbook of Electromagnetic Materials: Monolithic and Composite Versions and Their Applications. Washington DC, USA: CRC Press, 1995.
[6]
Green M, Chen XB. Recent progress of nanomaterials for microwave absorption. J Materiomics 2019, 5: 503-541.
Crossref Google Scholar
[7]
Zeng XJ, Cheng XY, Yu RH, et al. Electromagnetic microwave absorption theory and recent achievements in microwave absorbers. Carbon 2020, 168: 606-623.
Crossref Google Scholar
[8]
Liu JL, Zhang LM, Wu HJ. Electromagnetic wave-absorbing performance of carbons, carbides, oxides, ferrites and sulfides: Review and perspective. J Phys D: Appl Phys 2021, 54: 203001.
Crossref Google Scholar
[9]
Zhang ZW, Cai ZH, Wang ZY, et al. A review on metal-organic framework-derived porous carbon-based novel microwave absorption materials. Nano-Micro Lett 2021, 13: 56.
Crossref Google Scholar
[10]
Wang C, Han XJ, Xu P, et al. The electromagnetic property of chemically reduced graphene oxide and its application as microwave absorbing material. Appl Phys Lett 2011, 98: 072906.
Crossref Google Scholar
[11]
Qi XS, Xu JL, Hu Q, et al. Metal-free carbon nanotubes: Synthesis, and enhanced intrinsic microwave absorption properties. Sci Rep 2016, 6: 28310.
Crossref Google Scholar
[12]
Meng X, Lei WJ, Yang WW, et al. Fe3O4 nanoparticles coated with ultra-thin carbon layer for polarization- controlled microwave absorption performance. J Colloid Interface Sci 2021, 600: 382-389.
Crossref Google Scholar
[13]
Yan L, Wang X, Zhao S, et al. Highly efficient microwave absorption of magnetic nanospindle-conductive polymer hybrids by molecular layer deposition. ACS Appl Mater Interfaces 2017, 9: 11116-11125.
Crossref Google Scholar
[14]
Li X, Wen CY, Yang LT, et al. MXene/FeCo films with distinct and tunable electromagnetic wave absorption by morphology control and magnetic anisotropy. Carbon 2021, 175: 509-518.
Crossref Google Scholar
[15]
Liang CY, Wang ZJ. Controllable fabricating dielectric- dielectric SiC@C core-shell nanowires for high-performance electromagnetic wave attenuation. ACS Appl Mater Interfaces 2017, 9: 40690-40696.
Crossref Google Scholar
[16]
Zhao YJ, Zhang YN, Yang CR, et al. Ultralight and flexible SiC nanoparticle-decorated carbon nanofiber mats for broad-band microwave absorption. Carbon 2021, 171: 474-483.
Crossref Google Scholar
[17]
Liu Y, Cui TT, Wu T, et al. Excellent microwave-absorbing properties of elliptical Fe3O4 nanorings made by a rapid microwave-assisted hydrothermal approach. Nanotechnology 2016, 27: 165707.
Crossref Google Scholar
[18]
Luo J, Hu Y, Xiao L, et al. Synthesis of 3D flower-like Fe3S4 microspheres and quasi-sphere Fe3S4-RGO hybrid-architectures with enhanced electromagnetic wave absorption. Nanotechnology 2019, 31: 085708.
Crossref Google Scholar
[19]
Zhang C, Wang B, Xiang J, et al. Microwave absorption properties of CoS2 nanocrystals embedded into reduced graphene oxide. ACS Appl Mater Interfaces 2017, 9: 28868-28875.
Crossref Google Scholar
[20]
Jia ZR, Lin KJ, Wu GL, et al. Recent progresses of high-temperature microwave-absorbing materials. Nano 2018, 13: 1830005.
Crossref Google Scholar
[21]
Golla BR, Mukhopadhyay A, Basu B, et al. Review on ultra-high temperature boride ceramics. Prog Mater Sci 2020, 111: 100651.
Crossref Google Scholar
[22]
Williams WS. Transition-metal carbides. Prog Solid State Chem 1971, 6: 57-118.
Crossref Google Scholar
[23]
Williams WS. Transition metal carbides, nitrides, and borides for electronic applications. JOM 1997, 49: 38-42.
Crossref Google Scholar
[24]
Williams WS. The thermal conductivity of metallic ceramics. JOM 1998, 50: 62-66.
Crossref Google Scholar
[25]
Pierson HO. Handbook of Refractory Carbides and Nitrides: Properties, Characteristics, Processing, and Applications. New Jersey, USA: Noyes Publications, 1996.
Crossref
[26]
Zhou YC, Zhao B, Chen H, et al. Electromagnetic wave absorbing properties of TMCs (TM = Ti, Zr, Hf, Nb and Ta) and high entropy (Ti0.2Zr0.2Hf0.2Nb0.2Ta0.2)C. J Mater Sci Technol 2021, 74: 105-118.
Crossref Google Scholar
[27]
Chen H, Zhao B, Zhao ZF, et al. Achieving strong microwave absorption capability and wide absorption bandwidth through a combination of high entropy rare earth silicide carbides/rare earth oxides. J Mater Sci Technol 2020, 47: 216-222.
Crossref Google Scholar
[28]
Zhang WM, Zhao B, Xiang HM, et al. One-step synthesis and electromagnetic absorption properties of high entropy rare earth hexaborides (HE REB6) and high entropy rare earth hexaborides/borates (HE REB6/HE REBO3) composite powders. J Adv Ceram 2021, 10: 62-77.
Crossref Google Scholar
[29]
Zhang WM, Zhao B, Ni N, et al. High entropy rare earth hexaborides/tetraborides (HE REB6/HE REB4) composite powders with enhanced electromagnetic wave absorption performance. J Mater Sci Technol 2021, 87: 155-166.
Crossref Google Scholar
[30]
Zhang WM, Dai FZ, Xiang HM, et al. Enabling highly efficient and broadband electromagnetic wave absorption by tuning impedance match in high-entropy transition metal diborides (HE TMB2). J Adv Ceram 2021, 10: 1299-1316.
Crossref Google Scholar
[31]
Zhao ZF, Chen H, Xiang HM, et al. High entropy defective fluorite structured rare-earth niobates and tantalates for thermal barrier applications. J Adv Ceram 2020, 9: 303-311.
Crossref Google Scholar
[32]
Sun YN, Xiang HM, Dai FZ, et al. Preparation and properties of CMAS resistant bixbyite structured high-entropy oxides RE2O3 (RE = Sm, Eu, Er, Lu, Y, and Yb): Promising environmental barrier coating materials for Al2O3f/Al2O3 composites. J Adv Ceram 2021, 10: 596-613.
Crossref Google Scholar
[33]
Zhao ZF, Xiang HM, Chen H, et al. High-entropy (Nd0.2Sm0.2Eu0.2Y0.2Yb0.2)4Al2O9 with good high temperature stability, low thermal conductivity, and anisotropic thermal expansivity. J Adv Ceram 2020, 9: 595-605.
Google Scholar
[34]
Dong Y, Ren K, Lu YH, et al. High-entropy environmental barrier coating for the ceramic matrix composites. J Eur Ceram Soc 2019, 39: 2574-2579.
Crossref Google Scholar
[35]
Wang YC, Zhang RZ, Zhang BH, et al. The role of multi-elements and interlayer on the oxidation behaviour of (Hf-Ta-Zr-Nb)C high entropy ceramics. Corros Sci 2020, 176: 109019.
Crossref Google Scholar
[36]
Xiang HM, Xing Y, Dai FZ, et al. High-entropy ceramics: Present status, challenges, and a look forward. J Adv Ceram 2021, 10: 385-441.
Crossref Google Scholar
[37]
Oyama ST. Introduction to the chemistry of transition metal carbides and nitrides. In The Chemistry of Transition Metal Carbides and Nitrides. Dordrecht, the Netherlands: Springer Netherlands, 1996: 1-27.
Crossref
[38]
Gubanov VA, Ivanovsky AL, Zhukov VP. Electronic Structure of Refractory Carbides and Nitrides. Cambridge, UK: Cambridge University Press, 1994.
Crossref
[39]
Cuppari M, Santos S. Physical properties of the NbC carbide. Metals 2016, 6: 250.
Crossref Google Scholar
[40]
Castle E, Csanádi T, Grasso S, et al. Processing and properties of high-entropy ultra-high temperature carbides. Sci Rep 2018, 8: 8609.
Crossref Google Scholar
[41]
Ye BL, Ning SS, Liu D, et al. One-step synthesis of coral-like high-entropy metal carbide powders. J Am Ceram Soc 2019, 102: 6372-6378.
Crossref Google Scholar
[42]
Feng L, Fahrenholtz WG, Hilmas GE, et al. Synthesis of single-phase high-entropy carbide powders. Scripta Mater 2019, 162: 90-93.
Crossref Google Scholar
[43]
Tilley RJD. Understanding Solids. Chichester, UK: John Wiley & Sons, Ltd., 2004.
[44]
Quan B, Shi WH, Ong SJH, et al. Defect engineering in two common types of dielectric materials for electromagnetic absorption applications. Adv Funct Mater 2019, 29: 1901236.
Crossref Google Scholar
[45]
Van Beek LKH. The Maxwell-Wagner-Sillars effect, describing apparent dielectric loss in inhomogeneous media. Physica 1960, 26: 66-68.
Crossref Google Scholar
[46]
Mabbs FE, Collison D. Electron Paramagnetic Resonance of d Transition Metal Compounds. Amsterdam, the Netherlands: Elsevier Science Publishers B.V., 1992.
Crossref
[47]
Gonzales J, Gajare S, Nguyen S, et al. Magnetically tuning the loss tangent in La(Al1-xFex)O3 using low field electron paramagnetic resonance transitions. Appl Phys Lett 2020, 117: 222901.
Crossref Google Scholar
[48]
Jian X, Tian W, Li JY, et al. High-temperature oxidation-resistant ZrN0.4B0.6/SiC nanohybrid for enhanced microwave absorption. ACS Appl Mater Interfaces 2019, 11: 15869-15880.
Crossref Google Scholar
[49]
Duan YP, Pang HF, Wen X, et al. Microwave absorption performance of FeCoNiAlCr0.9 alloy powders by adjusting the amount of process control agent. J Mater Sci Technol 2021, 77: 209-216.
Crossref Google Scholar
[50]
Duan YP, Wen X, Zhang B, et al. Optimizing the electromagnetic properties of the FeCoNiAlCrx high entropy alloy powders by composition adjustment and annealing treatment. J Magn Magn Mater 2020, 497: 165947.
Crossref Google Scholar
[51]
Zhang WD, Zhang X, Zhu Q, et al. High-efficiency and wide-bandwidth microwave absorbers based on MoS2-coated carbon fiber. J Colloid Interface Sci 2021, 586: 457-468.
Crossref Google Scholar
Journal of Advanced Ceramics
Volume 11 Issue 4,
April 2022
Pages 545-555
DOI: 10.1007/s40145-021-0554-2
Cite this article:
ZHANG W, XIANG H, DAI F-Z, et al. Achieving ultra-broadband electromagnetic wave absorption in high-entropy transition metal carbides (HE TMCs). Journal of Advanced Ceramics, 2022, 11(4): 545-555. https://doi.org/10.1007/s40145-021-0554-2

2041

Views

447

Downloads

75

Crossref

77

Web of Science

82

Scopus

0

CSCD

Altmetrics
Received: 11 August 2021
Revised: 01 November 2021
Accepted: 09 November 2021
Published: 17 March 2022
© The Author(s) 2021.

Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if changes were made.

The images or other third party material in this article are included in the article’s Creative Commons licence, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons licence and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder.

To view a copy of this licence, visit http://creativecommons.org/licenses/by/4.0/.
Return