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Research Article | Open Access

Novel 3D grid porous Li4Ti5O12 thick electrodes fabricated by 3D printing for high performance lithium-ion batteries

Changyong LIUa,bYin QIUaYanliang LIUaKun XUaNing ZHAOaChangshi LAOaJun SHENbZhangwei CHENa,b( )
Additive Manufacturing Institute, College of Mechatronics & Control Engineering, Shenzhen University, Shenzhen 518060, China
Guangdong Key Laboratory of Electromagnetic Control and Intelligent Robots, College of Mechatronics & Control Engineering, Shenzhen University, Shenzhen 518060, China
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Abstract

Three-dimensional (3D) grid porous electrodes introduce vertically aligned pores as a convenient path for the transport of lithium-ions (Li-ions), thereby reducing the total transport distance of Li-ions and improving the reaction kinetics. Although there have been other studies focusing on 3D electrodes fabricated by 3D printing, there still exists a gap between electrode design and their electrochemical performance. In this study, we try to bridge this gap through a comprehensive investigation on the effects of various electrode parameters including the electrode porosity, active material particle diameter, electrode electronic conductivity, electrode thickness, line width, and pore size on the electrochemical performance. Both numerical simulations and experimental investigations are conducted to systematically examine these effects. 3D grid porous Li4Ti5O12 (LTO) thick electrodes are fabricated by low temperature direct writing technology and the electrodes with the thickness of 1085 μm and areal mass loading of 39.44 mg·cm-2 are obtained. The electrodes display impressive electrochemical performance with the areal capacity of 5.88 mAh·cm-2@1.0 C, areal energy density of 28.95 J·cm-2@1.0 C, and areal power density of 8.04 mW·cm-2@1.0 C. This study can provide design guidelines for obtaining 3D grid porous electrodes with superior electrochemical performance.

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References

[2]
Wang S, Yang Y, Dong Y, et al. Recent progress in Ti-based nanocomposite anodes for lithium ion batteries. J Adv Ceram 2019, 8: 1-18.
[3]
Ferrari S, Loveridge M, Beattie SD, et al. Latest advances in the manufacturing of 3D rechargeable lithium microbatteries. J Power Sources 2015, 286: 25-46.
[4]
Kuang Y, Chen C, Kirsch D, et al. Thick electrode batteries: Principles, opportunities, and challenges. Adv Energy Mater 2019, 9: 1901457.
[5]
Sun H, Zhu J, Baumann D, et al. Hierarchical 3D electrodes for electrochemical energy storage. Nat Rev Mater 2019, 4: 45-60.
[6]
Arthur TS, Bates DJ, Cirigliano N, et al. Three-dimensional electrodes and battery architectures. MRS Bull 2011, 36: 523-531.
[7]
Roberts M, Johns P, Owen J, et al. 3D lithium ion batteries—From fundamentals to fabrication. J Mater Chem 2011, 21: 9876.
[8]
Inoue G, Kawase M. Numerical and experimental evaluation of the relationship between porous electrode structure and effective conductivity of ions and electrons in lithium-ion batteries. J Power Sources 2017, 342: 476-488.
[9]
Danner T, Singh M, Hein S, et al. Thick electrodes for Li-ion batteries: A model based analysis. J Power Sources 2016, 334: 191-201.
[10]
Gao H, Wu Q, Hu Y, et al. Revealing the rate-limiting Li-ion diffusion pathway in ultrathick electrodes for Li-ion batteries. J Phys Chem Lett 2018, 9: 5100-5104.
[11]
Landi BJ, Ganter MJ, Cress CD, et al. Carbon nanotubes for lithium ion batteries. Energy Environ Sci 2009, 2: 638.
[12]
Wang K, Wu Y, Luo S, et al. Hybrid super-aligned carbon nanotube/carbon black conductive networks: A strategy to improve both electrical conductivity and capacity for lithium ion batteries. J Power Sources 2013, 233: 209-215.
[13]
Liu X, Peng H, Zhang Q, et al. Hierarchical carbon nanotube/carbon black scaffolds as short- and long-range electron pathways with superior Li-ion storage performance. ACS Sustainable Chem Eng 2014, 2: 200-206.
[14]
Sander JS, Erb RM, Li L, et al. High-performance battery electrodes via magnetic templating. Nat Energy 2016, 1: 16099.
[15]
Chen C, Xu S, Kuang Y, et al. Nature-inspired tri-pathway design enabling high-performance flexible Li-O2 batteries. Adv Energy Mater 2019, 9: 1802964.
[16]
Du G, Zhou Y, Tian X, et al. High-performance 3D directional porous LiFePO4/C materials synthesized by freeze casting. Appl Surf Sci 2018, 453: 493-501.
[17]
Long J, Dunn B, Rolison D, et al. Three-dimensional battery architectures. Chem Rev 2004, 104: 4463-4492.
[18]
Ambrosi A, Pumera M. 3D-printing technologies for electrochemical applications. Chem Soc Rev 2016, 45: 2740-2755.
[19]
Fu K, Yao Y, Dai J, et al. Progress in 3D printing of carbon materials for energy-related applications. Adv Mater 2017, 29: 1603486.
[20]
Ruiz-Morales JC, Tarancón A, Canales-Vázquez J, et al. Three dimensional printing of components and functional devices for energy and environmental applications. Energy Environ Sci 2017, 10: 846-859.
[21]
Tian X, Jin J, Yuan S, et al. Emerging 3D-printed electrochemical energy storage devices: A critical review. Adv Energy Mater 2017, 7: 1700127.
[22]
Wei M, Zhang F, Wang W, et al. 3D direct writing fabrication of electrodes for electrochemical storage devices. J Power Sources 2017, 354: 134-147.
[23]
Zhakeyev A, Wang P, Zhang L, et al. Additive manufacturing: Unlocking the evolution of energy materials. Adv Sci 2017, 4: 1700187.
[24]
Zhang F, Wei M, Viswanathan VV, et al. 3D printing technologies for electrochemical energy storage. Nano Energy 2017, 40: 418-431.
[25]
Zhu C, Liu T, Qian F, et al. 3D printed functional nanomaterials for electrochemical energy storage. Nano Today 2017, 15: 107-120.
[26]
Chang P, Mei H, Zhou S, et al. 3D printed electrochemical energy storage devices. J Mater Chem A 2019, 7: 4230-4258.
[27]
Zeng L, Li P, Yao Y, et al. Recent progresses of 3D printing technologies for structural energy storage devices. Mater Today Nano 2020, 12: 100094.
[28]
Sun K, Wei TS, Ahn BY, et al. 3D printing of interdigitated Li-ion microbattery architectures. Adv Mater 2013, 25: 4539-4543.
[29]
Fu K, Wang Y, Yan C, et al. Graphene oxide-based electrode inks for 3D-printed lithium-ion batteries. Adv Mater 2016, 28: 2587-2594.
[30]
Hu J, Jiang Y, Cui S, et al. 3D-printed cathodes of LiMn1-xFexPO4 nanocrystals achieve both ultrahigh rate and high capacity for advanced lithium-ion battery. Adv Energy Mater 2016, 6: 1600856.
[31]
Kohlmeyer RR, Blake AJ, Hardin JO, et al. Composite batteries: A simple yet universal approach to 3D printable lithium-ion battery electrodes. J Mater Chem A 2016, 4: 16856-16864.
[32]
Li J, Leu MC, Panat R, et al. A hybrid three-dimensionally structured electrode for lithium-ion batteries via 3D printing. Mater Des 2017, 119: 417-424.
[33]
Wang Y, Chen C, Xie H, et al. 3D-printed all-fiber Li-ion battery toward wearable energy storage. Adv Funct Mater 2017, 27: 1703140.
[34]
Chen QM, Xu R, He ZT, et al. Printing 3D gel polymer electrolyte in lithium-ion microbattery using stereolithography. J Electrochem Soc 2017, 164: A1852-A1857.
[35]
Liu C, Cheng X, Li B, et al. Fabrication and characterization of 3D-printed highly-porous 3D LiFePO4 electrodes by low temperature direct writing process. Materials 2017, 10: 934.
[36]
Rocha VG, Rocha VG, García-Tuñón E, et al. Multimaterial 3D printing of graphene-based electrodes for electrochemical energy storage using thermoresponsive inks. ACS Appl Mater Interfaces 2017, 10: 37136-37145.
[37]
Cheng M, Jiang YZ, Yao WT, et al. Elevated-temperature 3D printing of hybrid solid-state electrolyte for Li-ion batteries. Adv Mater 2018, 30: 1800615.
[38]
Lacey SD, Kirsch DJ, Li YJ, et al. Extrusion-based 3D printing of hierarchically porous advanced battery electrodes. Adv Mater 2018, 30: 1705651.
[39]
Park SH, Kaur M, Yun D, et al. Hierarchically designed electron paths in 3D printed energy storage devices. Langmuir 2018, 34: 10897-10904.
[40]
Reyes C, Somogyi R, Niu S, et al. 3D printing of a complete lithium ion battery with fused filament fabrication. ACS Appl Energy Mater 2018, 1: 10.
[41]
Wang J, Sun Q, Gao X, et al. Toward high areal energy and power density electrode for Li-ion batteries via optimized 3D printing approach. ACS Appl Mater Interfaces 2018, 10: 39794-39801.
[42]
Wei T, Ahn B, Grotto J, et al. 3D printing of customized Li-ion batteries with thick electrodes. Adv Mater 2018, 30: 1703027.
[43]
Zhang C, Shen K, Li B, et al. Continuously 3D printed quantum dot-based electrodes for lithium storage with ultrahigh capacities. J Mater Chem A 2018, 6: 19960-19966.
[44]
Cao D, Xing Y, Tantratian K, et al. 3D printed high-performance lithium metal microbatteries enabled by nanocellulose. Adv Mater 2019, 31: 1807313.
[45]
Deiner LJ, Bezerra CAG, Howell TG, et al. Digital printing of solid-state lithium-ion batteries. Adv Eng Mater 2019, 21: 1900737.
[46]
Yu X, Liu Y, Pham H, et al. Customizable nonplanar printing of lithium-ion batteries. Adv Mater Technol 2019, 4: 1900645.
[47]
Zhou L, Ning W, Wu C, et al. 3D-printed microelectrodes with a developed conductive network and hierarchical pores toward high areal capacity for microbatteries. Adv Mater Technol 2019, 4: 1800402.
[48]
Ashby DS, Choi CS, Edwards MA, et al. High- performance solid-state lithium-ion battery with mixed 2D and 3D electrodes. ACS Appl Energy Mater 2020, 3: 8402-8409.
[49]
Bao Y, Liu Y, Kuang Y, et al. 3D-printed highly deformable electrodes for flexible lithium ion batteries. Energy Storage Mater 2020, 33: 55-61.
[50]
Gao X, Yang X, Sun Q, et al. Converting a thick electrode into vertically aligned “thin electrodes” by 3D-printing for designing thickness independent Li-S cathode. Energy Storage Mater 2020, 24: 682-688.
[51]
Zhu Y, Li J, Saleh MS, et al. Towards high-performance Li-ion batteries via optimized three-dimensional micro- lattice electrode architectures. J Power Sources 2020, 476: 228593.
[52]
Gao W, Pumera M. 3D printed nanocarbon frameworks for Li-ion battery cathodes. Adv Funct Mater 2021, 31: 2007285.
[53]
Lyu ZY, Lim GJH, Koh JJ, et al. Design and manufacture of 3D-printed batteries. Joule 2021, 5: 89-114.
[54]
Liu C, Xu F, Liu Y, et al. High mass loading ultrathick porous Li4Ti5O12 electrodes with improved areal capacity fabricated via low temperature direct writing. Electrochimica Acta 2019, 314: 81-88.
[55]
Wu X, Liang X, Zhang X, et al. Structural evolution of plasma sprayed amorphous Li4Ti5O12 electrode and ceramic/ polymer composite electrolyte during electrochemical cycle of quasi-solid-state lithium battery. J Adv Ceram 2021, 10: 347-354.
[56]
Sotomayor ME, de la Torre-Gamarra C, Bucheli W, et al. Additive-free Li4Ti5O12 thick electrodes for Li-ion batteries with high electrochemical performance. J Mater Chem A 2018, 6: 5952-5961.
Journal of Advanced Ceramics
Pages 295-307
Cite this article:
LIU C, QIU Y, LIU Y, et al. Novel 3D grid porous Li4Ti5O12 thick electrodes fabricated by 3D printing for high performance lithium-ion batteries. Journal of Advanced Ceramics, 2022, 11(2): 295-307. https://doi.org/10.1007/s40145-021-0533-7

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Received: 05 May 2021
Revised: 04 September 2021
Accepted: 04 September 2021
Published: 11 January 2022
© The Author(s) 2021.

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