AI Chat Paper
Note: Please note that the following content is generated by AMiner AI. SciOpen does not take any responsibility related to this content.
{{lang === 'zh_CN' ? '文章概述' : 'Summary'}}
{{lang === 'en_US' ? '中' : 'Eng'}}
Chat more with AI
Powered by AMiner. Clicking this button will take you away from SciOpen.
Home Journal of Advanced Ceramics Article
PDF (4 MB)
Cite
EndNote(RIS) BibTeX
Collect
Submit Manuscript AI Chat Paper
Show Outline
Outline
Show full outline
Hide outline
Outline
Show full outline
Hide outline
Research Article | Open Access

Defect engineering of BCZT-based piezoelectric ceramics with high piezoelectric properties

Xinjian WANG1, Yu HUAN1( ), Yixuan ZHU1, Peng ZHANG1, Wenlong YANG1, Peng LI2, Tao WEI1, Longtu LI3, Xiaohui WANG3
School of Material Science and Engineering, University of Jinan, Jinan 250022, China
School of Materials Science and Engineering, Liaocheng University, Liaocheng 252000, China
State Key Laboratory of New Ceramics and Fine Processing, School of Materials Science and Engineering, Tsinghua University, Beijing 100084, China
Show Author Information

Abstract

The intrinsic conduction mechanism and optimal sintering atmosphere of (Ba0.85Ca0.15)(Zr0.1Ti0.9)O3 (BCZT) ceramics were regulated by Mn-doping element in this work. By Hall and impedance analysis, the undoped BCZT ceramics exhibit a typical n-type conduction mechanism, and the electron concentration decreases with the increasing oxygen partial pressure. Therefore, the undoped ceramics exhibit best electrical properties (piezoelectrical constant d33 = 585 pC·N-1, electro-mechanical coupling factor kp = 56%) in O2. A handful of Mn-doping element would transfer the conduction mechanism from n-type into p-type. And the hole concentration reduces with the decreasing oxygen partial pressure for Mn-doped BCZT ceramics. Therefore, the Mn-doped ceramics sintered in N2 have the highest insulation resistance and best piezoelectric properties (d33 = 505 pC·N-1, kp = 50%). The experimental results demonstrate that the Mn-doping element can effectively adjust the intrinsic conduction mechanism and then predict the optimal atmosphere.

Keywords

BCZT ceramicsMn-dopingdifferent sintering atmospherep/n-type conduction mechanismdefect engineering

Electronic Supplementary Material

Download File(s)
s40145-021-0526-6_ESM.pdf (404 KB)

References

[1]
Tressler J, Alkoy S, Newnham R. Piezoelectric sensors and sensor materials. J Electroceram 1998, 2: 257-272.
Crossref Google Scholar
[2]
Hao JG, Li W, Zhai JW, et al. Progress in high-strain perovskite piezoelectric ceramics. Mater Sci Eng: R: Rep 2019, 135: 1-57.
Crossref Google Scholar
[3]
Gao X, Wu J, Yu Y, et al. Giant piezoelectric coefficients in relaxor piezoelectric ceramic PNN-PZT for vibration energy harvesting. Adv Funct Mater 2018, 28: 1706895.
Crossref Google Scholar
[4]
Jamie RL, Graeme EB, Pedro JJA, et al. Nanomaterials in the environment: Behavior, fate, bioavailability, and effects—An updated review. Environ Toxicol Chem 2018, 37: 2029-2063.
Crossref Google Scholar
[5]
Gao JH, Xue DZ, Liu WF, et al. Recent progress on BaTiO3-based piezoelectric ceramics for actuator applications. Actuators 2017, 6: 24.
Crossref Google Scholar
[6]
Alkathy MS, James Raju KC. Structural, dielectric, electromechanical, piezoelectric, elastic and ferroelectric properties of lanthanum and sodium co-substituted Barium titanate ceramics. J Alloys Compd 2018, 737: 464-476.
Crossref Google Scholar
[7]
Li TY, Lou XJ, Ke XQ, et al. Giant strain with low hysteresis in A-site-deficient (Bi0.5Na0.5)TiO3-based lead-free piezoceramics. Acta Mater 2017, 128: 337-344.
Crossref Google Scholar
[8]
Yin J, Zhao CL, Zhang YX, et al. Ultrahigh strain in site engineering-independent Bi0.5Na0.5TiO3-based relaxor- ferroelectrics. Acta Mater 2018, 147: 70-77.
Crossref Google Scholar
[9]
Wang K, Yao FZ, Koruza J, et al. Electromechanical properties of CaZrO3 modified (K,Na)NbO3-based lead-free piezoceramics under uniaxial stress conditions. J Am Ceram Soc 2017, 100: 2116-2122.
Crossref Google Scholar
[10]
Li P, Chen XQ, Wang FF, et al. Microscopic insight into electric fatigue resistance and thermally stable piezoelectric properties of (K,Na)NbO3-based ceramics. ACS Appl Mater Interfaces 2018, 10: 28772-28779.
Crossref Google Scholar
[11]
Malič B, Koruza J, Hreščak J, et al. Sintering of lead-free piezoelectric sodium potassium niobate ceramics. Materials: Basel 2015, 8: 8117-8146.
Crossref Google Scholar
[12]
Castkova K, Maca K, Cihlar J, et al. Chemical synthesis, sintering and piezoelectric properties of Ba0.85Ca0.15Zr0.1Ti0.9O3 lead-free ceramics. J Am Ceram Soc 2015, 98: 2373-2380.
Crossref Google Scholar
[13]
Li SB, Wang CB, Li L, et al. Effect of annealing temperature on structural and electrical properties of BCZT ceramics prepared by plasma activated sintering. J Alloys Compd 2018, 730: 182-190.
Crossref Google Scholar
[14]
Coondoo I, Panwar N, Alikin D, et al. A comparative study of structural and electrical properties in lead-free BCZT ceramics: Influence of the synthesis method. Acta Mater 2018, 155: 331-342.
Crossref Google Scholar
[15]
Liu Y, Chang Y, Li F, et al. Exceptionally high piezoelectric coefficient and low strain hysteresis in grain-oriented (Ba, Ca)(Ti,Zr)O3 through integrating crystallographic texture and domain engineering. ACS Appl Mater Interfaces 2017, 9: 29863-29871.
Crossref Google Scholar
[16]
Bai WF, Chen DQ, Li P, et al. Enhanced electromechanical properties in <001>-textured (Ba0.85Ca0.15)(Zr0.1Ti0.9)O3 lead-free piezoceramics. Ceram Int 2016, 42: 3429-3436.
Crossref
[17]
Liu W, Ren X. Large piezoelectric effect in Pb-free ceramics. Phys Rev Lett 2009, 103: 257602.
Crossref Google Scholar
[18]
Gao RL, Chu XC, Huan Y, et al. Ceramic-electrode inter- diffusion of (K,Na)NbO3-based multilayer ceramics with Ag0.7Pd0.3 electrode. J Eur Ceram Soc 2015, 35: 389-392.
Crossref Google Scholar
[19]
Zhang QW, Cai W, Zhou C, et al. Electric fatigue of BCZT ceramics sintered in different atmospheres. Appl Phys A 2019, 125: 759.
Crossref Google Scholar
[20]
Cai W, Zhang QW, Zhou C, et al. Effects of oxygen partial pressure on the electrical properties and phase transitions in (Ba,Ca)(Ti,Zr)O3 ceramics. J Mater Sci 2020, 55: 9972-9992.
Crossref Google Scholar
[21]
Zhang SW, Zhang HL, Zhang BP, et al. Dielectric and piezoelectric properties of (Ba0.95Ca0.05)(Ti0.88Zr0.12)O3 ceramics sintered in a protective atmosphere. J Eur Ceram Soc 2009, 29: 3235-3242.
Crossref Google Scholar
[22]
Zhang Y, Sun HJ, Chen W. Influence of cobalt and sintering temperature on structure and electrical properties of BaZr0.05Ti0.95O3 ceramics. Ceram Int 2015, 41: 8520-8532.
Crossref Google Scholar
[23]
Zhang Y, Sun HJ, Chen W, et al. Modification of the structure and electrical properties of Ba0.95Ca0.05Zr0.1Ti0.9O3 ceramics by the doping of Mn ions. J Mater Sci: Mater Electron 2015, 26: 10034-10043.
Crossref Google Scholar
[24]
Yan XD, Zheng MP, Gao X, et al. Giant current performance in lead-free piezoelectrics stem from local structural heterogeneity. Acta Mater 2020, 187: 29-40.
Crossref Google Scholar
[25]
Yao ZH, Luo Q, Xu CB, et al. Titanium deficiency in tetragonal-structured (Ba,Ca)(Zr,Ti)O3 piezoelectric ceramics. J Alloys Compd 2017, 712: 406-411.
Crossref Google Scholar
[26]
Wang H, Yuan H, Hu Q, et al. Exploring the high-performance (1-x)BaTiO3-xCaZrO3 piezoceramics with multiphase coexistence (R-O-T) from internal lattice distortion and domain features. J Alloys Compd 2021, 853: 157167.
Crossref Google Scholar
[27]
Dobal PS, Katiyar RS. Studies on ferroelectric perovskites and Bi-layered compounds using micro-Raman spectroscopy. J Raman Spectrosc 2002, 33: 405-423.
Crossref Google Scholar
[28]
Janbua W, Bongkarn T, Kolodiazhnyi T, et al. High piezoelectric response and polymorphic phase region in the lead-free piezoelectric BaTiO3-CaTiO3-BaSnO3 ternary system. RSC Adv 2017, 7: 30166-30176.
Crossref Google Scholar
[29]
Perry CH, Hall DB. Temperature dependence of the Raman spectrum of BaTiO3. Phys Rev Lett 1965, 15: 700-702.
Crossref Google Scholar
[30]
Zhang YM, Deng HM, Si SF, et al. Band gap narrowing and magnetic properties of transition-metal-doped Ba0.85Ca0.15Ti0.9Zr0.1O3 lead-free ceramics. J Am Ceram Soc 2020, 103: 2491-2498.
Crossref Google Scholar
[31]
Tian YS, Cao LJ, Qin PP, et al. Piezoelectric and thermophysical performances of La3+ and Ir4+ co-doped Ba0.95Ca0.05Ti0.94Zr0.06O3 ceramics. Ceram Int 2019, 45: 12825-12831.
Crossref Google Scholar
[32]
Chen XL, He F, Wang YL, et al. Significant effects of powder preparation processes on the physical properties of Bi0.5Na0.5TiO3-0.06BaTiO3 ceramic. J Mater Sci: Mater Electron 2014, 25: 5309-5315.
Crossref Google Scholar
[33]
Bae SH, Kahya O, Sharma BK, et al. Graphene-P(VDF-TrFE) multilayer film for flexible applications. ACS Nano 2013, 7: 3130-3138.
Crossref Google Scholar
[34]
Wang ZX, Huan Y, Feng Y, et al. Design of p-type NKN-based piezoelectric ceramics sintered in low oxygen partial pressure by defect engineering. J Am Ceram Soc 2020, 103: 3667-3675.
Crossref Google Scholar
[35]
Li M, Pietrowski MJ, De Souza RA, et al. A family of oxide ion conductors based on the ferroelectric perovskite Na0.5Bi0.5TiO3. Nat Mater 2014, 13: 31-35.
Crossref Google Scholar
[36]
Donnelly NJ, Randall CA. Mixed conduction and chemical diffusion in a Pb(Zr0.53,Ti0.47)O3 buried capacitor structure. Appl Phys Lett 2010, 96: 052906.
Crossref Google Scholar
[37]
Wang XP, Zheng T, Wu JG, et al. Characteristics of giant piezoelectricity around the rhombohedral-tetragonal phase boundary in (K,Na)NbO3-based ceramics with different additives. J Mater Chem A 2015, 3: 15951-15961.
Crossref Google Scholar
Journal of Advanced Ceramics
Volume 11 Issue 1,
January 2022
Pages 184-195
DOI: 10.1007/s40145-021-0526-6
Cite this article:
WANG X, HUAN Y, ZHU Y, et al. Defect engineering of BCZT-based piezoelectric ceramics with high piezoelectric properties. Journal of Advanced Ceramics, 2022, 11(1): 184-195. https://doi.org/10.1007/s40145-021-0526-6

1380

Views

189

Downloads

43

Crossref

47

Web of Science

48

Scopus

4

CSCD

Altmetrics
Received: 11 June 2021
Revised: 25 July 2021
Accepted: 09 August 2021
Published: 24 December 2021
© The Author(s) 2021.

Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if changes were made.

The images or other third party material in this article are included in the article’s Creative Commons licence, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons licence and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder.

To view a copy of this licence, visit http://creativecommons.org/licenses/by/4.0/.
Return