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The novel dental ceramics can be fabricated at lower temperatures when sol-gel derived lithium disilicate glass ceramics (LDGC) was used as an additive for yttria stabilized tetragonal zirconia polycrystalline (Y-TZP) ceramics. The effect of LDGC on the sintering, mechanical, and translucent properties of Y-TZP ceramics was investigated in the present study. The results showed that the LDGC additive effectively improved the densification of Y-TZP at 1100 ℃, which was much lower than the sintering temperature for pure Y-TZP. When sintered at 1100 ℃, the Y-TZP with 1 wt% LDGC reached a relative density of 95.45%, and prossessed a flexural strength of 482.4 MPa and a fracture toughness of 5.94 MPa·m1/2. Moreover, its translucency was also improved. While, the addition of LDGC could result in an escape of yttrium atoms from the grain lattice of zirconia, which induced the tetragonal-monoclinic transformation of zirconia and abnormal growth of monoclinic grains. The escaped yttrium atoms diffused into the intergranular glass phase. The results indicated that the novel Y-TZP-LDGC ceramics has a great potential to be used for all-ceramic restorations.


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Optimized sintering and mechanical properties of Y-TZP ceramics for dental restorations by adding lithium disilicate glass ceramics

Show Author's information Ke LIa,bJiancun RAOc( )Congqin NINGa,b,d( )
State Key Laboratory of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China
Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing 100049, China
AIM Lab, Maryland NanoCenter, University of Maryland, College Park, MD 20742, USA
The Education Ministry Key Lab of Resource Chemistry and Shanghai Key Laboratory of Rare Earth Functional Materials, Shanghai Normal University, Shanghai 200234, China

Abstract

The novel dental ceramics can be fabricated at lower temperatures when sol-gel derived lithium disilicate glass ceramics (LDGC) was used as an additive for yttria stabilized tetragonal zirconia polycrystalline (Y-TZP) ceramics. The effect of LDGC on the sintering, mechanical, and translucent properties of Y-TZP ceramics was investigated in the present study. The results showed that the LDGC additive effectively improved the densification of Y-TZP at 1100 ℃, which was much lower than the sintering temperature for pure Y-TZP. When sintered at 1100 ℃, the Y-TZP with 1 wt% LDGC reached a relative density of 95.45%, and prossessed a flexural strength of 482.4 MPa and a fracture toughness of 5.94 MPa·m1/2. Moreover, its translucency was also improved. While, the addition of LDGC could result in an escape of yttrium atoms from the grain lattice of zirconia, which induced the tetragonal-monoclinic transformation of zirconia and abnormal growth of monoclinic grains. The escaped yttrium atoms diffused into the intergranular glass phase. The results indicated that the novel Y-TZP-LDGC ceramics has a great potential to be used for all-ceramic restorations.

Keywords: sintering, mechanical properties, dental restoration, yttria stabilized tetragonal zirconia polycrystalline (Y-TZP), lithium disilicate glass ceramics (LDGC)

References(44)

[1]
Raigrodski AJ. Contemporary materials and technologies for all-ceramic fixed partial dentures: A review of the literature. J Prosthet Dent 2004, 92: 557-562.
[2]
Guazzato M, Albakry M, Ringer SP, et al. Strength, fracture toughness and microstructure of a selection of all-ceramic materials. Part II. Zirconia-based dental ceramics. Dent Mater 2004, 20: 449-456.
[3]
Conejo J, Nueesch R, Vonderheide M, et al. Clinical performance of all-ceramic dental restorations. Curr Oral Heal Rep 2017, 4: 112-123.
[4]
Kelly J, Benetti P. Ceramic materials in dentistry: Historical evolution and current practice. Aust Dent J 2011, 56: 84-96.
[5]
Elsaka SE, Elnaghy AM. Mechanical properties of zirconia reinforced lithium silicate glass-ceramic. Dent Mater 2016, 32: 908-914.
[6]
Gautam C, Joyner J, Gautam A, et al. Zirconia based dental ceramics: Structure, mechanical properties, biocompatibility and applications. Dalton Trans 2016, 45: 19194-19215.
[7]
Denry I, Kelly JR. State of the art of zirconia for dental applications. Dent Mater 2008, 24: 299-307.
[8]
Zhang F, Inokoshi M, Batuk M, et al. Strength, toughness and aging stability of highly-translucent Y-TZP ceramics for dental restorations. Dent Mater 2016, 32: e327-e337.
[9]
Zhu DB, Song YJ, Liang JS, et al. Progress of toughness in dental zirconia ceramics. J Inorg Mater 2018, 33: 363.
[10]
Piconi C, Maccauro G. Zirconia as a ceramic biomaterial. Biomaterials 1999, 20: 1-25.
[11]
Miranda RBDP, Miranda WG Jr, Lazar DRR Jr, et al. Effect of titania content and biomimetic coating on the mechanical properties of the Y-TZP/TiO2 composite. Dent Mater 2018, 34: 238-245.
[12]
Garvie RC, Hannink RH, Pascoe RT. Ceramic steel? Nature 1975, 258: 703-704.
[13]
Sun YH, Zhang YF, Guo JK. Microstructure and bending strength of 3Y-TZP ceramics by liquid-phase sintering with CAS addition. Ceram Int 2003, 29: 229-232.
[14]
Hannink RHJ, Kelly PM, Muddle BC. Transformation toughening in zirconia-containing ceramics. J Am Ceram Soc 2000, 83: 461-487.
[15]
Ho WF, Hsu HC, Peng YF, et al. Microstructure and mechanical properties of dental 3Y-TZP ceramics by using CaO-P2O5 glass as additive. Ceram Int 2011, 37: 1169-1174.
[16]
Soubelet CG, Albano MP, Conconi MS. Sintering, microstructure and hardness of Y-TZP-64S bioglass ceramics. Ceram Int 2018, 44: 4868-4874.
[17]
Soubelet CG, Albano MP. Mechanical properties and aging behaviour of Y-TZP with 64S bioglass additions for dental restorations. Adv Appl Ceram 2019, 118: 329-339.
[18]
De Paula Miranda RB, Borges R, Marchi J, et al. Microstructure and flexural strength of the Y:TZP/BG composite. Int J Appl Ceram Technol 2019, 16: 1979-1988.
[19]
Bellucci D, Sola A, Cannillo V. Bioactive glass/ZrO2 composites for orthopaedic applications. Biomed Mater 2013, 9: 015005.
[20]
Shi JL, Lu ZL, Guo JK. Model analysis of boundary residual stress and its effect on toughness in thin boundary layered yttria-stabilized tetragonal zirconia polycrystalline ceramics. J Mater Res 2000, 15: 727-732.
[21]
Bai Y, Peng L, Zhu QS. The preparation of the lithium disilicate glass-ceramic with high translucency. J Non Cryst Solids 2017, 457: 129-134.
[22]
Deng BH, Harris JT, Luo J. Atomic picture of crack propagation in Li2O-2SiO2 glass-ceramics revealed by molecular dynamics simulations. J Am Ceram Soc 2020, 103: 4304-4312.
[23]
Daguano JKMB, Milesi MTB, Rodas ACD, et al. In vitro biocompatibility of new bioactive lithia-silica glass- ceramics. Mater Sci Eng: C 2019, 94: 117-125.
[24]
Hoppe A, Güldal NS, Boccaccini AR. A review of the biological response to ionic dissolution products from bioactive glasses and glass-ceramics. Biomaterials 2011, 32: 2757-2774.
[25]
Guazzato M, Albakry M, Ringer SP, et al. Strength, fracture toughness and microstructure of a selection of all-ceramic materials. Part I. Pressable and alumina glass-infiltrated ceramics. Dent Mater 2004, 20: 441-448.
[26]
Li J, Cui BC, Lin YH, et al. High strength and toughness in chromatic polymer-infiltrated zirconia ceramics. Dent Mater 2016, 32: 1555-1563.
[27]
Garvie RC, Nicholson PS. Phase analysis in zirconia systems. J Am Ceram Soc 1972, 55: 303-305.
[28]
Toraya H, Yoshimura M, Somiya S. Calibration curve for quantitative analysis of the monoclinic-tetragonal ZrO2 system by X-ray diffraction. J Am Ceram Soc 1984, 67: C119-C121.
[29]
Swain MV. Unstable cracking (chipping) of veneering porcelain on all-ceramic dental crowns and fixed partial dentures. Acta Biomater 2009, 5: 1668-1677.
[30]
Habibe AF, Maeda LD, Souza RC, et al. Effect of bioglass additions on the sintering of Y-TZP bioceramics. Mater Sci Eng: C 2009, 29: 1959-1964.
[31]
Santos C, Souza RC, Habibe AF, et al. Mechanical properties of Y-TPZ ceramics obtained by liquid phase sintering using bioglass as additive. Mater Sci Eng: A 2008, 478: 257-263.
[32]
German RM, Suri P, Park SJ. Review: liquid phase sintering. J Mater Sci 2009, 44: 1-39.
[33]
Liu JW, Zhou XB, Tatarko P, et al. Fabrication, microstructure, and properties of SiC/Al4SiC4 multiphase ceramics via an in situ formed liquid phase sintering. J Adv Ceram 2020, 9: 193-203.
[34]
Tekeli S, Gürü M, Saǧlam OE. Densification and grain- growth behavior of various amounts of SiO2 doped 8YSCZ/SiO2 composites. Mater Manuf Process 2007, 22: 710-714.
[35]
Bicalho LA, Baptista CARP, Souza RC, et al. Fatigue and subcritical crack growth in ZrO2-bioglass ceramics. Ceram Int 2013, 39: 2405-2414.
[36]
Drożdż E, Wyrwa J, Schneider K, et al. Electrical properties of silica-doped 3 mol% yttria-stabilized tetragonal zirconia. J Mater Sci 2017, 52: 674-685.
[37]
Stábile MF, Soubelet CG, Albano MP, et al. Effect of 64S bioglass addition on sintering kinetic, flexural strength and osteoblast cell response of yttria-partially stabilized zirconia ceramics. Int J Appl Ceram Technol 2019, 16: 517-530.
[38]
Sun ZQ, Li MS, Zhou YC. Recent progress on synthesis, multi-scale structure, and properties of Y-Si-O oxides. Int Mater Rev 2014, 59: 357-383.
[39]
Haritha AH, Rao RR. Sol-gel synthesis and phase evolution studies of yttrium silicates. Ceram Int 2019, 45: 24957-24964.
[40]
Ma QS, Cai LH. Fabrication and oxidation resistance of mullite/yttrium silicate multilayer coatings on C/SiC composites. J Adv Ceram 2017, 6: 360-367.
[41]
Sun ZQ, Zhou YC, Li MS. Effect of LiYO2 on the synthesis and pressureless sintering of Y2SiO5. J Mater Res 2008, 23: 732-736.
[42]
Shi JL, Ruan ML, Yen TS. Crystallite growth in yttria- doped superfine zirconia powders and their compacts: A comparison between Y-TZP and YSZ. Ceram Int 1996, 22: 137-142.
[43]
Camposilvan E, Leone R, Gremillard L, et al. Aging resistance, mechanical properties and translucency of different yttria-stabilized zirconia ceramics for monolithic dental crown applications. Dent Mater 2018, 34: 879-890.
[44]
Zhang F, van Meerbeek B, Vleugels J. Importance of tetragonal phase in high-translucent partially stabilized zirconia for dental restorations. Dent Mater 2020, 36: 491-500.
Publication history
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Publication history

Received: 06 January 2021
Revised: 07 June 2021
Accepted: 11 June 2021
Published: 18 September 2021
Issue date: December 2021

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© The Author(s) 2021

Acknowledgements

This research was supported by the Shanghai Committee of Science and Technology, China (No. 17441904100).

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