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Research Article | Open Access

Pomegranate-type Si/C anode with SiC taped, well-dispersed tiny Si particles for lithium-ion batteries

Pengfei WUa,b,Benyang SHIa,Huibin TUaChangqing GUOaAnhua LIUa,b( )Guan YANc( )Zhaoju YUa( )
Key Laboratory of High-Performance Ceramic Fibers of Ministry of Education, College of Materials, Xiamen University, Xiamen 361005, China
Shenzhen Research Institute of Xiamen University, Shenzhen 518000, China
College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China

† Pengfei Wu and Benyang Shi contributed equally to this work.

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Abstract

Severe volume expansion and inherently poor lithium ion transmission are two major problems of silicon anodes. To address these issues, we proposed a pomegranate-type Si/C composite anode with highly dispersed tiny silicon particles as the core assisted by small amount of SiC. Skillfully exploiting the high heat from magnesiothermic reduction, SiC can assist the good dispersion of silicon and provide good interface compatibility and chemical stability. The silicon anchored to the carbon shell provides multipoint contact mode, that together with the carbon shell frame, significantly promoting the transfer of dual charge. Besides, the pomegranate-type microcluster structure also improves the tap density of the electrode, reduces the direct contact area between active material and electrolyte, and enhances the electrochemical performance.

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Journal of Advanced Ceramics
Pages 1129-1139
Cite this article:
WU P, SHI B, TU H, et al. Pomegranate-type Si/C anode with SiC taped, well-dispersed tiny Si particles for lithium-ion batteries. Journal of Advanced Ceramics, 2021, 10(5): 1129-1139. https://doi.org/10.1007/s40145-021-0498-6

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Received: 25 January 2021
Revised: 19 April 2021
Accepted: 09 May 2021
Published: 13 July 2021
© The Author(s) 2021

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