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Research Article | Open Access

Design and preparation of an ultra-high temperature ceramic by in-situ introduction of Zr2[Al(Si)]4C5 into ZrB2-SiC: Investigation on the mechanical properties and oxidation behavior

Lei YUa( ), Hui LIUa,b, Yaohui FUa, Weijiang HUa, Zhefei WANGa,c( ), Quan LIUa, Bo WEIa, Jian YANGd, Tai QIUd
School of Materials Engineering, Changshu Institute of Technology, Changshu 215500, China
School of Petrochemical Engineering, Changzhou University, Changzhou 213164, China
School of Materials Science and Engineering, Nanyang Technological University, Singapore 639798, Singapore
College of Materials Science and Engineering, Nanjing Tech University, Nanjing 210009, China
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Abstract

Novel ZrB2-matrix composites were designed and prepared by in-situ introducing SiC and Zr2[Al(Si)]4C5 simultaneously for the first time. The obtained composites were dense and showed good mechanical properties, especially the strength and toughness, 706 MPa and 7.33 MPa·m1/2, respectively, coupled with high hardness of 21.3 GPa, and stiffness of 452 GPa. SiC and Zr2[Al(Si)]4C5 constituted a reinforcing system with synergistic effects including grain refinement, grain pull-out as well as crack branching, bridging, and deflection. Besides, the oxidation results of the composites showed that the oxidation kinetics followed the parabolic law at 1600 ℃, and the oxidation rate constants increased with the increase of Zr2[Al(Si)]4C5 content. The formation and evolution model of the oxidation structure was also investigated, and the oxide scale of the composite exhibited a three-layer structure.

Keywords

ZrB2-matrix compositesultra-high temperature ceramics (UHTCs)mechanical propertiesstrengthening and toughening mechanismoxidation behavior

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Journal of Advanced Ceramics
Volume 10 Issue 5,
October 2021
Pages 1082-1094
DOI: 10.1007/s40145-021-0493-y
Cite this article:
YU L, LIU H, FU Y, et al. Design and preparation of an ultra-high temperature ceramic by in-situ introduction of Zr2[Al(Si)]4C5 into ZrB2-SiC: Investigation on the mechanical properties and oxidation behavior. Journal of Advanced Ceramics, 2021, 10(5): 1082-1094. https://doi.org/10.1007/s40145-021-0493-y

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Received: 22 February 2021
Revised: 26 April 2021
Accepted: 04 May 2021
Published: 16 September 2021
© The Author(s) 2021

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