AI Chat Paper
Note: Please note that the following content is generated by AMiner AI. SciOpen does not take any responsibility related to this content.
{{lang === 'zh_CN' ? '文章概述' : 'Summary'}}
{{lang === 'en_US' ? '中' : 'Eng'}}
Chat more with AI
Powered by AMiner. Clicking this button will take you away from SciOpen.
Home Journal of Advanced Ceramics Article
PDF (12.6 MB)
Cite
EndNote(RIS) BibTeX
Collect
Submit Manuscript AI Chat Paper
Show Outline
Outline
Show full outline
Hide outline
Outline
Show full outline
Hide outline
Research Article | Open Access

Novel hierarchical structure of MoS2/TiO2/Ti3C2Tx composites for dramatically enhanced electromagnetic absorbing properties

Heng DUa,b,†, Qipeng ZHANGa,†, Biao ZHAOc, Frank MARKENd, Qiancheng GAOc, Hongxia LUa, Li GUANc, Hailong WANGc, Gang SHAOc, Hongliang XUc, Rui ZHANGa,e, Bingbing FANa( )
School of Materials Science and Engineering, Zhengzhou University, Zhengzhou 450001, China
Key Laboratory of Functional Molecular Solids, Ministry of Education, Anhui Normal University, Wuhu 241000, China
Henan Key Laboratory of Aeronautical Materials and Application Technology, Zhengzhou University of Aeronautics, Zhengzhou 450046, China
Department of Chemistry, University of Bath, Claverton Down, Bath BA2 7AY, UK
School of Materials Science and Engineering, Luoyang Institute of Science and Technology, Luoyang 471023, China

† Heng Du and Qipeng Zhang contributed equally to this work.

Show Author Information

Abstract

In order to prevent the microwave leakage and mutual interference, more and more microwave absorbing devices are added into the design of electronic products to ensure its routine operation. In this work, we have successfully prepared MoS2/TiO2/Ti3C2Tx hierarchical composites by one-pot hydrothermal method and focused on the relationship between structures and electromagnetic absorbing properties. Supported by comprehensive characterizations, MoS2 nanosheets were proved to be anchored on the surface and interlayer of Ti3C2Tx through a hydrothermal process. Additionally, TiO2 nanoparticles were obtained in situ. Due to these hierarchical structures, the MoS2/TiO2/Ti3C2Tx composites showed greatly enhanced microwave absorbing performance. The MoS2/TiO2/Ti3C2Tx composites exhibit a maximum reflection loss value of -33.5 dB at 10.24 GHz and the effective absorption bandwidth covers 3.1 GHz (13.9-17 GHz) at the thickness of 1.0 mm, implying the features of wide frequency and light weight. This work in the hierarchical structure of MoS2/TiO2/Ti3C2Tx composites opens a promising door to the exploration of constructing extraordinary electromagnetic wave absorbents.

Keywords

MoS2/TiO2/Ti3C2Tx hierarchical hybridsmicrowave absorbing propertiesdielectric loss

References

[1]
Zhang F, Du H, Shang SY, et al. Constructing γ-MnO2 hollow spheres with tunable microwave absorption properties. Adv Powder Technol 2020, 31: 4642-4647.
Crossref Google Scholar
[2]
Xue W, Yang G, Bi S, et al. Construction of caterpillar-like hierarchically structured Co/MnO/CNTs derived from MnO2/ZIF-8@ZIF-67 for electromagnetic wave absorption. Carbon 2021, 173: 521-527.
Crossref Google Scholar
[3]
Tang M, Zhang JY, Bi S, et al. Ultrathin topological insulator absorber: Unique dielectric behavior of Bi2Te3 nanosheets based on conducting surface states. ACS Appl Mater Interfaces 2019, 11: 33285-33291.
Crossref Google Scholar
[4]
Qin F, Brosseau C. Comment on “The electromagnetic property of chemically reduced graphene oxide and its application as microwave absorbing material” [Appl. Phys. Lett. 98, 072906 (2011)]. Appl Phys Lett 2012, 100: 046101.
Crossref Google Scholar
[5]
Zhang XJ, Li S, Wang SW, et al. Self-supported construction of three-dimensional MoS2 hierarchical nanospheres with tunable high-performance microwave absorption in broadband. J Phys Chem C 2016, 120: 22019-22027.
Crossref Google Scholar
[6]
Liu ZC, Pan F, Deng BW, et al. Self-assembled MoS2/3D worm-like expanded graphite hybrids for high-efficiency microwave absorption. Carbon 2021, 174: 59-69.
Crossref Google Scholar
[7]
Yao YQ, Zhao J, Yang XH, et al. Recent advance in electromagnetic shielding of MXenes. Chin Chem Lett 2021, 32: 620-634.
Crossref Google Scholar
[8]
Deng BW, Xiang Z, Xiong J, et al. Sandwich-like Fe&TiO2@C nanocomposites derived from MXene/Fe-MOFs hybrids for electromagnetic absorption. Nano-Micro Lett 2020, 12: 1-16.
Crossref Google Scholar
[9]
Naguib M, Kurtoglu M, Presser V, et al. Two-dimensional nanocrystals produced by exfoliation of Ti3AlC2. Adv Mater 2011, 23: 4248-4253.
Crossref Google Scholar
[10]
Jiang XT, Kuklin AV, Baev A, et al. Two-dimensional MXenes: From morphological to optical, electric, and magnetic properties and applications. Phys Rep 2020, 848: 1-58.
Crossref Google Scholar
[11]
Wang Z, Cheng Z, Fang CQ, et al. Recent advances in MXenes composites for electromagnetic interference shielding and microwave absorption. Compos A: Appl Sci Manuf 2020, 136: 105956.
Crossref Google Scholar
[12]
Qing YC, Zhou WC, Luo F, et al. Titanium carbide (MXene) nanosheets as promising microwave absorbers. Ceram Int 2016, 42: 16412-16416.
Crossref Google Scholar
[13]
Fan BB, Li N, Dai BZ, et al. Investigation of adjacent spacing dependent microwave absorption properties of lamellar structural Ti3C2Tx MXenes. Adv Powder Technol 2020, 31: 808-815.
Crossref Google Scholar
[14]
Cui GZ, Sun XD, Zhang GY, et al. Electromagnetic absorption performance of two-dimensional MXene Ti3C2Tx exfoliated by HCl+LiF etchant with diverse etching times. Mater Lett 2019, 252: 8-10.
Crossref Google Scholar
[15]
Cui GZ, Zheng X, Lv X, et al. Synthesis and microwave absorption of Ti3C2Tx MXene with diverse reactant concentration, reaction time, and reaction temperature. Ceram Int 2019, 45: 23600-23610.
Crossref Google Scholar
[16]
Zhang JY, Xue W, Chen XY. Ti3C2Tx MXenes as thin broadband absorbers. Nanotechnology 2020, 31: 275301.
Crossref Google Scholar
[17]
Qian Y, Wei HW, Dong JD, et al. Fabrication of urchin-like ZnO-MXene nanocomposites for high-performance electromagnetic absorption. Ceram Int 2017, 43: 10757-10762.
Crossref Google Scholar
[18]
Li XL, Yin XW, Xu HL, et al. Ultralight MXene-coated, interconnected SiCnws three-dimensional lamellar foams for efficient microwave absorption in the X-band. ACS Appl Mater Interfaces 2018, 10: 34524-34533.
Crossref Google Scholar
[19]
Wang HY, Ma HB. The electromagnetic and microwave absorbing properties of MoS2 modified Ti3C2Tx nanocomposites. J Mater Sci: Mater Electron 2019, 30: 15250-15256.
Crossref Google Scholar
[20]
Fan BB, Shang SY, Dai BZ, et al. 2D-layered Ti3C2/TiO2 hybrids derived from Ti3C2 MXenes for enhanced electromagnetic wave absorption. Ceram Int 2020, 46: 17085-17092.
Crossref Google Scholar
[21]
Zhang WD, Zhang X, Wu HJ, et al. Impact of morphology and dielectric property on the microwave absorbing performance of MoS2-based materials. J Alloys Compd 2018, 751: 34-42.
Crossref Google Scholar
[22]
Cui YH, Yang K, Wang JQ, et al. Preparation of pleated RGO/MXene/Fe3O4 microsphere and its absorption properties for electromagnetic wave. Carbon 2021, 172: 1-14.
Crossref Google Scholar
[23]
Shahzad F, Alhabeb M, Hatter CB, et al. Electromagnetic interference shielding with 2D transition metal carbides (MXenes). Science 2016, 353: 1137-1140.
Crossref Google Scholar
[24]
Ning MQ, Lu MM, Li JB, et al. Two-dimensional nanosheets of MoS2: A promising material with high dielectric properties and microwave absorption performance. Nanoscale 2015, 7: 15734-15740.
Crossref Google Scholar
[25]
Liu N, Guo YL, Yang XY, et al. Microwave-assisted reactant-protecting strategy toward efficient MoS2 electrocatalysts in hydrogen evolution reaction. ACS Appl Mater Interfaces 2015, 7: 23741-23749.
Crossref Google Scholar
[26]
Li JH, Rui BL, Wei WX, et al. Nanosheets assembled layered MoS2/MXene as high performance anode materials for potassium ion batteries. J Power Sources 2020, 449: 227481.
Crossref Google Scholar
[27]
Zhang K, Ye MQ, Han AJ, et al. Preparation, characterization and microwave absorbing properties of MoS2 and MoS2 -reduced graphene oxide (RGO) composites. J Solid State Chem 2019, 277: 68-76.
Crossref Google Scholar
[28]
My Tran N, Thanh Hoai Ta Q, Noh JS. Unusual synthesis of safflower-shaped TiO2/Ti3C2 heterostructures initiated from two-dimensional Ti3C2 MXene. Appl Surf Sci 2021, 538: 148023.
Crossref Google Scholar
[29]
Dai BZ, Zhao B, Xie X, et al. Novel two-dimensional Ti3C2Tx MXenes/nano-carbon sphere hybrids for high- performance microwave absorption. J Mater Chem C 2018, 6: 5690-5697.
Crossref Google Scholar
[30]
Wang Y, Dou H, Wang J, et al. Three-dimensional porous MXene/layered double hydroxide composite for high performance supercapacitors. J Power Sources 2016, 327: 221-228.
Crossref Google Scholar
[31]
Zheng M, Guo RS, Liu ZC, et al. MoS2 intercalated p-Ti3C2 anode materials with sandwich-like three dimensional conductive networks for lithium-ion batteries. J Alloys Compd 2018, 735: 1262-1270.
Crossref Google Scholar
[32]
Hu L, Sun YY, Gong SJ, et al. Experimental and theoretical investigation on MoS2/MXene heterostructure as an efficient electrocatalyst for hydrogen evolution in both acidic and alkaline media. New J Chem 2020, 44: 7902-7911.
Crossref Google Scholar
[33]
Mao ML, Mei L, Guo D, et al. High electrochemical performance based on the TiO2 nanobelt@few-layered MoS2 structure for lithium-ion batteries. Nanoscale 2014, 6: 12350-12353.
Crossref Google Scholar
[34]
Ferrari AC. Raman spectroscopy of graphene and graphite: Disorder, electron-phonon coupling, doping and nonadiabatic effects. Solid State Commun 2007, 143: 47-57.
Crossref Google Scholar
[35]
Ding X, Huang Y, Li SP, et al. FeNi3 nanoalloy decorated on 3D architecture composite of reduced graphene oxide/ molybdenum disulfide giving excellent electromagnetic wave absorption properties. J Alloys Compd 2016, 689: 208-217.
Crossref Google Scholar
[36]
Liu QH, Cao Q, Bi H, et al. CoNi@SiO2@TiO2 and CoNi@Air@TiO2 microspheres with strong wideband microwave absorption. Adv Mater 2016, 28: 486-490.
Crossref Google Scholar
[37]
Zhao GL, Lv H, Zhou Y, et al. Self-assembled sandwich-like MXene-derived nanocomposites for enhanced electromagnetic wave absorption. ACS Appl Mater Interfaces 2018, 10: 42925-42932.
Crossref Google Scholar
[38]
Liao Q, He M, Zhou YM, et al. Rational construction of Ti3C2Tx/Co-MOF-derived laminated Co/TiO2-C hybrids for enhanced electromagnetic wave absorption. Langmuir 2018, 34: 15854-15863.
Crossref Google Scholar
[39]
Liu PJ, Yao ZJ, Ng VMH, et al. Novel multilayer-like structure of Ti3C2Tx/CNZF composites for low-frequency electromagnetic absorption. Mater Lett 2019, 34: 214-217.
Crossref Google Scholar
[40]
Han M, Yin X, Wu H, et al. Ti3C2 MXenes with modified surface for high-performance electromagnetic absorption and shielding in the X-band. ACS Appl Mater Interfaces 2016, 8: 21011-21019.
Crossref Google Scholar
Journal of Advanced Ceramics
Volume 10 Issue 5,
October 2021
Pages 1042-1051
DOI: 10.1007/s40145-021-0487-9
Cite this article:
DU H, ZHANG Q, ZHAO B, et al. Novel hierarchical structure of MoS2/TiO2/Ti3C2Tx composites for dramatically enhanced electromagnetic absorbing properties. Journal of Advanced Ceramics, 2021, 10(5): 1042-1051. https://doi.org/10.1007/s40145-021-0487-9

1600

Views

183

Downloads

117

Crossref

116

Web of Science

117

Scopus

16

CSCD

Altmetrics
Received: 26 January 2021
Revised: 17 April 2021
Accepted: 17 April 2021
Published: 16 September 2021
© The Author(s) 2021

This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if changes were made.

The images or other third party material in this article are included in the article’s Creative Commons licence, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons licence and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder.

To view a copy of this licence, visit http://creativecommons.org/licenses/by/4.0/.
Return