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Journal of Advanced Ceramics 2021, 10(5): 1001-1010 https://doi.org/10.1007/s40145-021-0483-0
Research Article | Open Access | Issue | Published: 20 September 2021

Resistive switching and optical properties of strontium ferrate titanate thin film prepared via chemical solution deposition

Show Author's Information Jun LI,  Xingui TANG( ),  Qiuxiang LIU,  Yanping JIANG,  Zhenxun TANG
School of Physics and Optoelectric Engineering, Guangdong University of Technology, Guangzhou 510006, China
Keywords:
oxygen vacancy, first principles, thin films, resistive switching, SrTiO3
Cite this article:
LI J, TANG X, LIU Q, et al. Resistive switching and optical properties of strontium ferrate titanate thin film prepared via chemical solution deposition. Journal of Advanced Ceramics, 2021, 10(5): 1001-1010. https://doi.org/10.1007/s40145-021-0483-0
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Abstract Full text Electronic supplementary material About this article

The polycrystalline strontium ferrate titanate (SrFe0.1Ti0.9O3, SFTO) thin films have been successfully prepared by chemical solution method. By analyzing the current-voltage (I-V) characteristics, we discuss the conduction mechanism of SFTO. It is found that the number of oxygen vacancy defects is increased by Fe ion doping, making SFTO be with better resistive switching property. Fe ion doping can also enhance the absorption of strontium titanate to be exposed to visible light, which is associated with the change of energy band. The band gap width (2.84 eV) of SFTO films is figured out, which is less than that of pure strontium titanate. Due to more oxygen vacancy defects caused by Fe ion doping, the band gap width of strontium titanate was reduced slightly. The defect types of SFTO thin films can be determined by electron paramagnetic resonance spectroscopy. In addition, we analyzed the energy band and state density of SFTO by first-principles calculation based on density functional theory, and found that Fe ion doping can reduce the band gap width of strontium titanate with micro-regulation on the band structure. A chemical state of SFTO was analyzed by X-ray photo electron spectroscopy. At the same time, the structure and morphology of SFTO were characterized by X-ray diffraction and scanning electron microscope. This study deepens further understanding of the influence of Fe ion doping on the structure and properties of strontium ferrate titanate, which is expected to be a functional thin film material for memristor devices.


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Electronic supplementary material
About this article

Resistive switching and optical properties of strontium ferrate titanate thin film prepared via chemical solution deposition

Show Author's information Jun LI, Xingui TANG( ), Qiuxiang LIU, Yanping JIANG, Zhenxun TANG
School of Physics and Optoelectric Engineering, Guangdong University of Technology, Guangzhou 510006, China

Abstract

The polycrystalline strontium ferrate titanate (SrFe0.1Ti0.9O3, SFTO) thin films have been successfully prepared by chemical solution method. By analyzing the current-voltage (I-V) characteristics, we discuss the conduction mechanism of SFTO. It is found that the number of oxygen vacancy defects is increased by Fe ion doping, making SFTO be with better resistive switching property. Fe ion doping can also enhance the absorption of strontium titanate to be exposed to visible light, which is associated with the change of energy band. The band gap width (2.84 eV) of SFTO films is figured out, which is less than that of pure strontium titanate. Due to more oxygen vacancy defects caused by Fe ion doping, the band gap width of strontium titanate was reduced slightly. The defect types of SFTO thin films can be determined by electron paramagnetic resonance spectroscopy. In addition, we analyzed the energy band and state density of SFTO by first-principles calculation based on density functional theory, and found that Fe ion doping can reduce the band gap width of strontium titanate with micro-regulation on the band structure. A chemical state of SFTO was analyzed by X-ray photo electron spectroscopy. At the same time, the structure and morphology of SFTO were characterized by X-ray diffraction and scanning electron microscope. This study deepens further understanding of the influence of Fe ion doping on the structure and properties of strontium ferrate titanate, which is expected to be a functional thin film material for memristor devices.

Keywords: oxygen vacancy, first principles, thin films, resistive switching, SrTiO3

References(38)

[1]
Cho S, Jang JW, Zhang WR, et al. Single-crystalline thin films for studying intrinsic properties of BiFeO3-SrTiO3 solid solution photoelectrodes in solar energy conversion. Chem Mater 2015, 27: 6635-6641.
DOI Google Scholar
[2]
Janousch M, Meijer GI, Staub U, et al. Role of oxygen vacancies in Cr-doped SrTiO3 for resistance-change memory. Adv Mater 2007, 19: 2232-2235.
DOI Google Scholar
[3]
Menesklou W, Schreiner HJ, Härdtl KH, et al. High temperature oxygen sensors based on doped SrTiO3. Sens Actuat B: Chem 1999, 59: 184-189.
DOI Google Scholar
[4]
Kawasaki S, Nakatsuji K, Yoshinobu J, et al. Epitaxial Rh-doped SrTiO3 thin film photocathode for water splitting under visible light irradiation. Appl Phys Lett 2012, 101: 033910.
DOI Google Scholar
[5]
Wang L, Merkle R, Mastrikov YA, et al. Oxygen exchange kinetics on solid oxide fuel cell cathode materials—General trends and their mechanistic interpretation. J Mater Res 2012, 27: 2000-2008.
DOI Google Scholar
[6]
Alexandrov VE, Maier J, Evarestov RA. Ab initio study of SrFexTi1-xO3: Jahn-Teller distortion and electronic structure. Phys Rev B 2008, 77: 075111.
DOI Google Scholar
[7]
Higuchi T, Tsukamoto T, Sata N, et al. Electronic structure of p-type SrTiO3 by photoemission spectroscopy. Phys Rev B 1998, 57: 6978-6983.
DOI Google Scholar
[8]
Sarin N, Mishra M, Gupta G, et al. Deciphering the role of oxygen vacancies on structural, electrical, and magnetic properties of Fe-substituted strontium titanate. Phys Status Solidi B 2018, 255: 1700683.
DOI Google Scholar
[9]
Berney RL, Cowan DL. Photochromism of three photosensitive Fe centers in SrTiO3. Phys Rev B 1981, 23: 37-50.
DOI Google Scholar
[10]
Merkle R, Maier J. Oxygen incorporation into Fe-doped SrTiO3: Mechanistic interpretation of the surface reaction. Phys Chem Chem Phys 2002, 4: 4140-4148.
DOI Google Scholar
[11]
Rothschild A, Litzelman SJ, Tuller HL, et al. Temperature- independent resistive oxygen sensors based on SrTi1-xFexO3-δ solid solutions. Sens Actuat B: Chem 2005, 108: 223-230.
DOI Google Scholar
[12]
Evarestov R, Blokhin E, Gryaznov D, et al. Jahn-Teller effect in the phonon properties of defective SrTiO3 from first principles. Phys Rev B 2012, 85: 174303.
DOI Google Scholar
[13]
Ang C, Yu Z, Jing Z, et al. Dielectric spectra and electrical conduction in Fe-doped SrTiO3. Phys Rev B 2000, 61: 3922-3926.
DOI Google Scholar
[14]
Muenstermann R, Menke T, Dittmann R, et al. Coexistence of filamentary and homogeneous resistive switching in Fe-doped SrTiO3 thin-film memristive devices. Adv Mater 2010, 22: 4819-4822.
DOI Google Scholar
[15]
Rothschild A, Menesklou W, Tuller HL, et al. Electronic structure, defect chemistry, and transport properties of SrTi1-xFexO3-y solid solutions. Chem Mater 2006, 18: 3651-3659.
DOI Google Scholar
[16]
Steinsvik S, Bugge R, Gjønnes J, et al. The defect structufe OF SrTi1-xFexO3-y (x = 0-0.8) investigated by electrical conductivity measurements and electron energy loss spectroscopy (EELS). J Phys Chem Solids 1997, 58: 969-976.
DOI Google Scholar
[17]
Vračar M, Kuzmin A, Merkle R, et al. Jahn-Teller distortion around Fe4+ in Sr(FexTi1-x)O3-δ from X-ray absorption spectroscopy, X-ray diffraction, and vibrational spectroscopy. Phys Rev B 2007, 76: 174107.
DOI Google Scholar
[18]
Rodewald S, Fleig J, Maier J. Microcontact impedance spectroscopy at single grain boundaries in Fe-doped SrTiO3 polycrystals. J Am Ceram Soc 2001, 84: 521-530.
DOI Google Scholar
[19]
Sundell PG, Björketun ME, Wahnström G. Thermodynamics of doping and vacancy formation in BaZrO3 perovskite oxide from density functional calculations. Phys Rev B 2006, 73: 104112.
DOI Google Scholar
[20]
Johnson KD, Dravid VP. Static and dynamic electron holography of electrically active grain boundaries in SrTiO3. Interface Sci 2000, 8: 189-198.
DOI Google Scholar
[21]
Wang YG, Tang XG, Liu QX, et al. Ferroelectric and ferromagnetic properties of SrTi0.9Fe0.1O3-δ thin films. Solid State Commun 2015, 202: 24-27.
DOI Google Scholar
[22]
Baker JN, Bowes PC, Long DM, et al. Defect mechanisms of coloration in Fe-doped SrTiO3 from first principles. Appl Phys Lett 2017, 110: 122903.
DOI Google Scholar
[23]
Neaton JB, Ederer C, Waghmare UV, et al. First-principles study of spontaneous polarization in multiferroic BiFeO3. Phys Rev B 2005, 71: 014113.
DOI Google Scholar
[24]
Hosokura T, Iwaji N, Nakagawa T, et al. (100)-oriented SrTiO3/BaTiO3 artificial superlattices fabricated by chemical solution deposition. Cryst Growth Des 2011, 11: 4253-4256.
DOI Google Scholar
[25]
Carter E, Carley AF, Murphy DM. Evidence for O2- radical stabilization at surface oxygen vacancies on polycrystalline TiO2. J Phys Chem C 2007, 111: 10630-10638.
DOI Google Scholar
[26]
Caretti I, Keulemans M, Verbruggen SW, et al. Light-induced processes in plasmonic gold/TiO2 photocatalysts studied by electron paramagnetic resonance. Top Catal 2015, 58: 776-782.
DOI Google Scholar
[27]
Huang MH, Xia JY, Xi YM, et al. Study on photochromism in SrTiO3:Fe ceramic powder. J Eur Ceram Soc 1997, 17: 1761-1765.
DOI Google Scholar
[28]
Ehre D, Cohen H, Lyahovitskaya V, et al. X-ray photoelectron spectroscopy of amorphous and quasiamorphous phases of BaTiO3 and SrTiO3. Phys Rev B 2008, 77: 184106.
DOI Google Scholar
[29]
Yamashita T, Hayes P. Analysis of XPS spectra of Fe2+ and Fe3+ ions in oxide materials. Appl Surf Sci 2008, 254: 2441-2449.
DOI Google Scholar
[30]
Perry NH, Kim N, Ertekin E, et al. Origins and control of optical absorption in a nondilute oxide solid solution: Sr(Ti, Fe)O3-x perovskite case study. Chem Mater 2019, 31: 1030-1041.
DOI Google Scholar
[31]
Cooper D, Baeumer C, Bernier N, et al. Anomalous resistance hysteresis in oxide ReRAM: Oxygen evolution and reincorporation revealed by in situ TEM. Adv Mater 2017, 29: 1700212.
DOI Google Scholar
[32]
Merino NA, Barbero BP, Eloy P, et al. La1-xCaxCoO3 perovskite-type oxides: Identification of the surface oxygen species by XPS. Appl Surf Sci 2006, 253: 1489-1493.
DOI Google Scholar
[33]
Ghaffari M, Liu T, Huang H, et al. Investigation of local structure effect and X-ray absorption characteristics (EXAFS) of Fe (Ti) K-edge on photocatalyst properties of SrTi(1-x)FexO(3-δ). Mater Chem Phys 2012, 136: 347-357.
DOI Google Scholar
[34]
Rana A, Lu HD, Bogle K, et al. Scaling behavior of resistive switching in epitaxial bismuth ferrite heterostructures. Adv Funct Mater 2014, 24: 3962-3969.
DOI Google Scholar
[35]
Ghaffari M, Shannon M, Hui H, et al. Preparation, surface state and band structure studies of SrTi(1-x)Fe(x)O(3-δ) (x = 0-1) perovskite-type nano structure by X-ray and ultraviolet photoelectron spectroscopy. Surf Sci 2012, 606: 670-677.
DOI Google Scholar
[36]
Sahner K, Schönauer D, Moos R, et al. Effect of electrodes and zeolite cover layer on hydrocarbon sensing with p-type perovskite SrTi0.8Fe0.2O3-δ thick and thin films. J Mater Sci 2006, 41: 5828-5835.
DOI Google Scholar
[37]
Bocquet, Fujimori, Mizokawa, et al. Electronic structure of SrFe4+O3 and related Fe perovskite oxides. Phys Rev B Condens Matter 1992, 45: 1561-1570.
DOI Google Scholar
[38]
Du HC, Jia CL, Mayer J, et al. Atomic structure of antiphase nanodomains in Fe-doped SrTiO3 films. Adv Funct Mater 2015, 25: 6369-6373.
DOI Google Scholar
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Publication history

Received: 17 September 2020
Revised: 10 April 2021
Accepted: 12 April 2021
Published: 20 September 2021
Issue date: October 2021

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© The Author(s) 2021

Acknowledgements

This work was supported by the National Natural Science Foundation of China (Grant No. 11574057), the Guangdong Basic and Applied Basic Research Foundation (Grant No. 2021A1515012607), and the Science and Technology Program of Guangdong Province of China (Grant No. 2017A010104022).

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