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Research Article | Open Access

High-thermally conductive AlN-based microwave attenuating composite ceramics with spherical graphite as attenuating agent

Xia FANGa,bLei JIANGa,bLimei PANa,bShuang YINa,bTai QIUa,bJian YANGa,b( )
Jiangsu Collaborative Innovation Center for Advanced Inorganic Function Composites, Nanjing 211816, China
College of Materials Science and Engineering, Nanjing Tech University, Nanjing 211816, China
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Abstract

High-thermally conductive AlN-based microwave attenuating composite ceramics with spherical graphite (SG) as the attenuating agent were fabricated through hot-pressing sintering. The SG maintains its three-dimensional (3D) morphology within the sintered bodies, which considerably impedes the sintering of the composites to some extent but slightly influences on the growth of AlN grains. The addition of SG reduces the strength of the composites, but provides a moderate toughening effect at the optimal addition amount (3.8 MPa·m1/2 at 4 wt% SG). Benefiting from the low anisotropy, high thermal conductivity, and the 3D morphology of SG, the composites exhibit a relatively higher thermal conductivity (76.82 W·m-1·K-1 at 10 wt% SG) compared with composites added with non-spherical attenuating agent. The dielectric constant and loss (8.2-12.4 GHz) increase remarkably as the amount of SG added increases up to 8 wt%, revealing that the incorporation of SG improves the dielectric property of the composite. The composite with 7 wt% SG exhibits the best absorption performance with a minimum reflection loss of -13.9 dB at 12.4 GHz and an effective absorbing bandwidth of 0.87 GHz. The excellent overall properties of the SG/AlN microwave attenuating composites render them as a promising material for various applications. Moreover, SG has a great potential as an attenuating agent for microwave attenuating composites due to its strong attenuation upon integration, high thermal conductivity, and low anisotropy.

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Journal of Advanced Ceramics
Pages 301-319
Cite this article:
FANG X, JIANG L, PAN L, et al. High-thermally conductive AlN-based microwave attenuating composite ceramics with spherical graphite as attenuating agent. Journal of Advanced Ceramics, 2021, 10(2): 301-319. https://doi.org/10.1007/s40145-020-0441-2

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Received: 21 August 2020
Revised: 24 November 2020
Accepted: 27 November 2020
Published: 01 March 2021
© The Author(s) 2020

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