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Journal of Advanced Ceramics 2021, 10(1): 187-193 https://doi.org/10.1007/s40145-020-0431-4
Rapid Communication | Open Access | Issue | Published: 18 January 2021

Formation of hierarchical Si3N4 foams by protein-based gelcasting and chemical vapor infiltration

Show Author's Information Junsheng LI,  Qiuping YU,  Duan LI( ),  Liang ZENG,  Shitao GAO
Science and Technology on Advanced Ceramic Fibers and Composites Laboratory, College of Aerospace Science and Engineering, National University of Defense Technology, Changsha 410073, China
Keywords:
ceramics, sintering, porosity, mechanical properties, permeability
Cite this article:
LI J, YU Q, LI D, et al. Formation of hierarchical Si3N4 foams by protein-based gelcasting and chemical vapor infiltration. Journal of Advanced Ceramics, 2021, 10(1): 187-193. https://doi.org/10.1007/s40145-020-0431-4
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Abstract Full text About this article

Silicon nitride foams with a hierarchical porous structure was formed by the combination of protein-based gelcasting, chemical vapor infiltration, and in-situ growth of silicon nitride nanowires. The porosity of the foams can be controlled at 76.3-83.8 vol% with an open porosity of 70.2-82.8 vol%. The pore size distribution was presented in three levels: < 2 μm (voids among grains and cross overlapping of silicon nitride nanowires (SNNWs)), 10-50 μm (cell windows), and >100 μm (cells). The resulted compressive strength of the porous bodies at room temperature can achieve up to 18.0±1.0 MPa (porosity = 76.3 vol%) while the corresponding retention rate at 800 ℃ was 58.3%. Gas permeability value was measured to be 5.16 (cm3·cm)/(cm2·s·kPa). The good strength, high permeability together with the pore structure in multiple scales enabled the foam materials for microparticle infiltration applications.


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About this article

Formation of hierarchical Si3N4 foams by protein-based gelcasting and chemical vapor infiltration

Show Author's information Junsheng LI, Qiuping YU, Duan LI( ), Liang ZENG, Shitao GAO
Science and Technology on Advanced Ceramic Fibers and Composites Laboratory, College of Aerospace Science and Engineering, National University of Defense Technology, Changsha 410073, China

Abstract

Silicon nitride foams with a hierarchical porous structure was formed by the combination of protein-based gelcasting, chemical vapor infiltration, and in-situ growth of silicon nitride nanowires. The porosity of the foams can be controlled at 76.3-83.8 vol% with an open porosity of 70.2-82.8 vol%. The pore size distribution was presented in three levels: < 2 μm (voids among grains and cross overlapping of silicon nitride nanowires (SNNWs)), 10-50 μm (cell windows), and >100 μm (cells). The resulted compressive strength of the porous bodies at room temperature can achieve up to 18.0±1.0 MPa (porosity = 76.3 vol%) while the corresponding retention rate at 800 ℃ was 58.3%. Gas permeability value was measured to be 5.16 (cm3·cm)/(cm2·s·kPa). The good strength, high permeability together with the pore structure in multiple scales enabled the foam materials for microparticle infiltration applications.

Keywords: ceramics, sintering, porosity, mechanical properties, permeability

References(27)

[1]
F Riley. Silicon nitride and related materials. J Am Ceram Soc 2000, 83: 245-265.
DOI Google Scholar
[2]
EG de Moraes, D Li, P Colombo, et al. Silicon nitride foams from emulsions sintered by rapid intense thermal radiation. J Eur Ceram Soc 2015, 35: 3263-3272.
DOI Google Scholar
[3]
ZL Cheng, F Ye, YS Liu, et al. Mechanical and dielectric properties of porous and wave-transparent Si3N4-Si3N4 composite ceramics fabricated by 3D printing combined with chemical vapor infiltration. J Adv Ceram 2019, 8: 399-407.
DOI Google Scholar
[4]
JJ Liu, B Ren, YL Wang, et al. Hierarchical porous ceramics with 3D reticular architecture and efficient flow-through filtration towards high-temperature particulate matter capture. Chem Eng J 2019, 362: 504-512.
DOI Google Scholar
[5]
ZX Cuo, HD Liu, F Zhao, et al. Highly porous fibrous mullite ceramic membrane with interconnected pores for high performance dust removal. Ceram Int 2018, 44: 11778-11782.
DOI Google Scholar
[6]
D Li, E Guzi de Moraes, P Guo, et al. Rapid sintering of silicon nitride foams decorated with one-dimensional nanostructures by intense thermal radiation. Sci Technol Adv Mater 2014, 15: 045003.
DOI Google Scholar
[7]
AR Studart, UT Gonzenbach, E Tervoort, et al. Processing routes to macroporous ceramics: A review. J Am Ceram Soc 2006, 89: 1771-1789.
DOI Google Scholar
[8]
T Ohji, M Fukushima. Macro-porous ceramics: Processing and properties. Int Mater Rev 2012, 57: 115-131.
DOI Google Scholar
[9]
XQ Li, DX Yao, KH Zuo, et al. Microstructure and gas permeation performance of porous silicon nitride ceramics with unidirectionally aligned channels. J Am Ceram Soc 2020, 103: 6565-6574.
DOI Google Scholar
[10]
JM Wu, XY Zhang, J Xu, et al. Preparation of porous Si3N4 ceramics via tailoring solid loading of Si3N4 slurry and Si3N4 poly-hollow microsphere content. J Adv Ceram 2015, 4: 260-266.
DOI Google Scholar
[11]
L Han, L Huang, FL Li, et al. Low-temperature preparation of Si3N4/SiC porous ceramics via foam-gelcasting and microwave-assisted catalytic nitridation. Ceram Int 2018, 44: 11088-11093.
DOI Google Scholar
[12]
L Han, XG Deng, FL Li, et al. Preparation of high strength porous mullite ceramics via combined foam-gelcasting and microwave heating. Ceram Int 2018, 44: 14728-14733.
DOI Google Scholar
[13]
L Han, JK Wang, FL Li, et al. Low-temperature preparation of Si3N4 whiskers bonded/reinforced SiC porous ceramics via foam-gelcasting combined with catalytic nitridation. J Eur Ceram Soc 2018, 38: 1210-1218.
DOI Google Scholar
[14]
P Jamshidi, NN Lu, G Liu, et al. Netshape centrifugal gel-casting of high-temperature sialon ceramics. Ceram Int 2018, 44: 3440-3447.
DOI Google Scholar
[15]
O Lyckfeldt, J Brandt, S Lesca. Protein forming—A novel shaping technique for ceramics. J Eur Ceram Soc 2000, 20: 2551-2559.
DOI Google Scholar
[16]
CH Wang, YS Liu, MX Zhao, et al. Three-dimensional graphene/SiBCN composites for high-performance electromagnetic interference shielding. Ceram Int 2018, 44: 22830-22839.
DOI Google Scholar
[17]
Y Pan, YS Liu, MX Zhao, et al. Effects of oxidation temperature on microstructure and EMI shielding performance of layered SiC/PyC porous ceramics. J Eur Ceram Soc 2019, 39: 4527-4534.
DOI Google Scholar
[18]
J Wang, LY Cao, YS Liu, et al. Fabrication of improved flexural strength C/SiC composites via LA-CVI method using optimized spacing of mass transfer channels. J Eur Ceram Soc 2020, 40: 2828-2833.
DOI Google Scholar
[19]
F Chen, Y Li, W Liu, et al. Synthesis of α silicon nitride single-crystalline nanowires by nitriding cryomilled nanocrystalline silicon powder. Scripta Mater 2009, 60: 737-740.
DOI Google Scholar
[20]
YY Zheng, D Li, B Li, et al. Effect of SNNWS content on the microstructure and properties of SNNWS/Si-C-N ceramic composites via PIP. Ceram Int 2018, 44: 5102-5108.
DOI Google Scholar
[21]
JL Yu, JL Yang, S Li, et al. Preparation of Si3N4 foam ceramics with nest-like cell structure by particle-stabilized foams. J Am Ceram Soc 2012, 95: 1229-1233.
DOI Google Scholar
[22]
B Ren, JJ Liu, WL Huo, et al. Facile fabrication of nanofibrous network reinforced hierarchical structured porous Si3N4-based ceramics based on Si-Si3N4 binary particle-stabilized foams. Ceram Int 2019, 45: 1984-1990.
DOI Google Scholar
[23]
MN Rahaman. Sintering of Ceramics. Boca Raton: CRC Press/Taylor & Francis, 2007.
[24]
SS Balabanov, DA Permin, EY Rostokina, et al. Sinterability of nanopowders of terbia solid solutions with scandia, yttria, and Lutetia. J Adv Ceram 2018, 7: 362-369.
DOI Google Scholar
[25]
LH Wu, CW Li, H Li, et al. Preparation and characteristics of porous anorthite ceramics with high porosity and high-temperature strength. Int J Appl Ceram Technol 2020, 17: 963-973.
DOI Google Scholar
[26]
XG Deng, SL Ran, L Han, et al. Foam-gelcasting preparation of high-strength self-reinforced porous mullite ceramics. J Eur Ceram Soc 2017, 37: 4059-4066.
DOI Google Scholar
[27]
D Li, QP Yu, JS Li, et al. Manufacture of Si3N4-SiCN composite bulks with hierarchical pore structure. J Eur Ceram Soc 2021, 41: 284-289.
DOI Google Scholar
Publication history
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Publication history

Received: 03 September 2020
Revised: 03 October 2020
Accepted: 26 October 2020
Published: 18 January 2021
Issue date: February 2021

Copyright

© The Author(s) 2020

Acknowledgements

We acknowledged the financial support from the Natural Science Foundation of Hunan Province (Grant No. 2017JJ3353) and the National Natural Science Foundation of China (Grant No.51702361).

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