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Research Article | Open Access

Enhanced dielectric, ferroelectric, and optical properties in rare earth elements doped PMN-PT thin films

Shun ZHOUaDabin LINa( )Yongming SUaLin ZHANGb( )Weiguo LIUa
Thin Film and Optical Manufacturing Technology, Key Laboratory of Ministry of Education, Xi’an Technological University, Xi’an 710032, China
Electronic Materials Research Laboratory, Key Laboratory of the Ministry of Education & International Center for Dielectric Research, School of Electronic Science and Engineering, Faculty of Electronic and Information Engineering, Xi’an Jiaotong University, Xi’an 710049, China
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Abstract

Rare earth (RE = La3+, Sm3+, Pr3+) ion doped Pb(Mg1/3Nb2/3)O3-PbTiO3 (RE-PMN-PT) ferroelectric thin films with compositions near the morphotropic phase boundary were grown on the Pt/TiO2/SiO2/Si(100) substrate using sol-gel/spin coating method. The phase structure, electrical properties, and photoluminescence performance of thin films were investigated systematically. The highly (100)-preferred orientation was obtained in pure perovskite Sm-PMN-0.30PT thin films with an average grain size of 131 nm. After 2.5% Sm3+ doping, the PMN-0.30PT thin films exhibited a triple enhancement of dielectric permittivity with a maximum value of 3500 at 1 kHz, a low dielectric loss of 1.3%, and high remanent polarization of 17.5 μC/cm2 at room temperature. In visible light and near-infrared band, the transmittance rate increased with PT content and showed the highest value of 85% in 2.5%Sm-PMN-0.31PT. In addition, the films presented strong red-orange emission at 599 nm, which was sensitively in temperature range of 248-273 K corresponding to the rhombohedral to monoclinic phase transition temperature.

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Journal of Advanced Ceramics
Pages 98-107
Cite this article:
ZHOU S, LIN D, SU Y, et al. Enhanced dielectric, ferroelectric, and optical properties in rare earth elements doped PMN-PT thin films. Journal of Advanced Ceramics, 2021, 10(1): 98-107. https://doi.org/10.1007/s40145-020-0423-4

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Received: 07 April 2020
Revised: 15 September 2020
Accepted: 15 September 2020
Published: 05 November 2020
© The Author(s) 2020

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