Journal Home > Volume 10 , Issue 1

Rare earth (RE = La3+, Sm3+, Pr3+) ion doped Pb(Mg1/3Nb2/3)O3-PbTiO3 (RE-PMN-PT) ferroelectric thin films with compositions near the morphotropic phase boundary were grown on the Pt/TiO2/SiO2/Si(100) substrate using sol-gel/spin coating method. The phase structure, electrical properties, and photoluminescence performance of thin films were investigated systematically. The highly (100)-preferred orientation was obtained in pure perovskite Sm-PMN-0.30PT thin films with an average grain size of 131 nm. After 2.5% Sm3+ doping, the PMN-0.30PT thin films exhibited a triple enhancement of dielectric permittivity with a maximum value of 3500 at 1 kHz, a low dielectric loss of 1.3%, and high remanent polarization of 17.5 μC/cm2 at room temperature. In visible light and near-infrared band, the transmittance rate increased with PT content and showed the highest value of 85% in 2.5%Sm-PMN-0.31PT. In addition, the films presented strong red-orange emission at 599 nm, which was sensitively in temperature range of 248-273 K corresponding to the rhombohedral to monoclinic phase transition temperature.


menu
Abstract
Full text
Outline
About this article

Enhanced dielectric, ferroelectric, and optical properties in rare earth elements doped PMN-PT thin films

Show Author's information Shun ZHOUaDabin LINa( )Yongming SUaLin ZHANGb( )Weiguo LIUa
Thin Film and Optical Manufacturing Technology, Key Laboratory of Ministry of Education, Xi’an Technological University, Xi’an 710032, China
Electronic Materials Research Laboratory, Key Laboratory of the Ministry of Education & International Center for Dielectric Research, School of Electronic Science and Engineering, Faculty of Electronic and Information Engineering, Xi’an Jiaotong University, Xi’an 710049, China

Abstract

Rare earth (RE = La3+, Sm3+, Pr3+) ion doped Pb(Mg1/3Nb2/3)O3-PbTiO3 (RE-PMN-PT) ferroelectric thin films with compositions near the morphotropic phase boundary were grown on the Pt/TiO2/SiO2/Si(100) substrate using sol-gel/spin coating method. The phase structure, electrical properties, and photoluminescence performance of thin films were investigated systematically. The highly (100)-preferred orientation was obtained in pure perovskite Sm-PMN-0.30PT thin films with an average grain size of 131 nm. After 2.5% Sm3+ doping, the PMN-0.30PT thin films exhibited a triple enhancement of dielectric permittivity with a maximum value of 3500 at 1 kHz, a low dielectric loss of 1.3%, and high remanent polarization of 17.5 μC/cm2 at room temperature. In visible light and near-infrared band, the transmittance rate increased with PT content and showed the highest value of 85% in 2.5%Sm-PMN-0.31PT. In addition, the films presented strong red-orange emission at 599 nm, which was sensitively in temperature range of 248-273 K corresponding to the rhombohedral to monoclinic phase transition temperature.

Keywords: PMN-PT, rare earth doping, dielectric, ferroelectric, photoluminescence

References(48)

[1]
F Li, D Lin, Z Chen, et al. Ultrahigh piezoelectricity in ferroelectric ceramics by design. Nat Mater 2018, 17: 349-354.
[2]
SH Baek, J Park, DM Kim, et al. Giant piezoelectricity on Si for hyperactive MEMS. Science 2011, 334: 958-961.
[3]
SH Baek, MS Rzchowski, VA Aksyuk. Giant piezoelectricity in PMN-PT thin films: Beyond PZT. MRS Bull 2012, 37: 1022-1029.
[4]
TE Beechem, MD Goldflam, MB Sinclair, et al. Tunable infrared devices via ferroelectric domain reconfiguration. Adv Opt Mater 2018, 6: 1800862.
[5]
XQ Chen, Q Wang, X Wu, et al. Piezoelectric/ photoluminescence effect in one-dimensional lead-free nanofibers. Scripta Mater 2018, 145: 81-84.
[6]
ZY Feng, DQ Shi, R Zeng, et al. Large electrocaloric effect of highly (100)-oriented 0.68PbMg1/3Nb2/3O3-0.32PbTiO3 thin films with a Pb(Zr0.3Ti0.7)O3/PbOx buffer layer. Thin Solid Films 2011, 519: 5433-5436.
[7]
Z Lv, YL Qin, YC Zhang, et al. Efficient upconversion photoluminescence in transparent Pr3+/Yb3+ co-doped 0.75Pb(Mg1/3Nb2/3)O3-0.25PbTiO3 ferroelectric ceramics. Ceram Int 2019, 45: 10924-10929.
[8]
FF Wang, D Liu, ZB Chen, et al. In situ reversible tuning of photoluminescence of an epitaxial thin film via piezoelectric strain induced by a Pb(Mg1/3Nb2/3)O3-PbTiO3 single crystal. J Mater Chem C 2017, 5: 9115-9120.
[9]
X Wu, J Lin, P Chen, et al. Ho3+-doped (K,Na)NbO3-based multifunctional transparent ceramics with superior optical temperature sensing performance. J Am Ceram Soc 2019, 102: 1249-1258.
[10]
P Du, LH Luo, WP Li, et al. Upconversion emission in Er-doped and Er/Yb-codoped ferroelectric Na0.5Bi0.5TiO3 and its temperature sensing application. J Appl Phys 2014, 116: 014102.
[11]
ZL Wang. Piezopotential gated nanowire devices: Piezotronics and piezo-phototronics. Nano Today 2010, 5: 540-552.
[12]
AG Paulish, PS Zagubisalo, VN Barakov, et al. Piezo-optical transducer for high sensitive strain gauges. IEEE Sensor J 2018, 18: 8318-8328.
[13]
M McDonald. 39.3: Manufacture of flat panel displays using piezoelectric drop-on-demand ink jet. SID Symposium Digest 2003, 34: 1186-1189.
[14]
M Tabib-Azar, A Garcia-Valenzuela. Sensing means and sensor shells: A new method of comparative study of piezoelectric, piezoresistive, electrostatic, magnetic, and optical sensors. Sensor Actuat A: Phys 1995, 48: 87-100.
[15]
SJ Zhang, F Li. High performance ferroelectric relaxor-PbTiO3 single crystals: Status and perspective. J Appl Phys 2012, 111: 031301.
[16]
F Li, S Zhang, D Damjanovic, et al. Local structural heterogeneity and electromechanical responses of ferroelectrics: Learning from relaxor ferroelectrics. Adv Funct Mater 2018, 28: 1801504.
[17]
Y Li, Y Tang, J Chen, et al. Enhanced pyroelectric properties and thermal stability of Mn-doped 0.29Pb(In1/2Nb1/2)O3-0.29Pb(Mg1/3Nb2/3)O3-0.42PbTiO3 single crystals. Appl Phys Lett 2018, 112: 172901.
[18]
SY Li, EW Sun, LG Tang, et al. Temperature dependence of full matrix material constants of [001]c poled 0.71Pb(Mg1/3Nb2/3)O3-0.29PbTiO3 single crystal. J Appl Phys 2018, 123: 164102.
[19]
ZZ Song, YC Zhang, CJ Lu, et al. Fabrication and ferroelectric/dielectric properties of La-doped PMN-PT ceramics with high optical transmittance. Ceram Int 2017, 43: 3720-3725.
[20]
ZH Wei, YL Huang, T Tsuboi, et al. Optical characteristics of Er3+-doped PMN-PT transparent ceramics. Ceram Int 2012, 38: 3397-3402.
[21]
Z Wei, T Tsuboi, Y Nakai. The synthesis of Er3+-doped PMN-PT transparent ceramic and its infrared luminescence. Mater Lett 2012, 68: 57-59.
[22]
JT Zeng, ZH Wei, YL Huang, et al. NIR to visible up-conversion luminescence of Er3+-doped PMN-PT transparent ceramics. J Am Ceram Soc 2012, 95: 2573-2578.
[23]
C Cai, D Zhang, W Liu, et al. Synthesis, giant dielectric, and pyroelectric response of [001]-oriented Pr3+ doped Pb(Mg1/3Nb2/3)O3-PbTiO3 ferroelectric nano-films grown on Si substrates. Materials 2018, 11: 2392.
[24]
TC Goel, P Kumar, AR James, et al. Processing and dielectric properties of sol-gel derived PMN-PT (68:32) thin films. J Electroceram 2004, 13: 503-507.
[25]
GR Li, W Ruan, JT Zeng, et al. The effect of domain structures on the transparency of PMN-PT transparent ceramics. Opt Mater 2013, 35: 722-726.
[26]
JY Pan, TL Men, XY Xu, et al. Domain growth dynamics in PMN-PT ferroelectric thin films. J Mater Sci 2019, 54: 10600-10608.
[27]
J Wang, KH Wong, HLW Chan, et al. Composition control and electrical properties of PMN-PT thin films around the morphotropic boundary. Appl Phys A 2004, 79: 551-556.
[28]
WL Ji, XY He, X Zeng, et al. Effects of PMN/PT ratio on optical and electro-optic properties of PLMNT transparent ceramics. Ceram Int 2015, 41: 10387-10393.
[29]
W Ruan, GR Li, JT Zeng, et al. Large electro-optic effect in La-doped 0.75Pb(Mg1/3Nb2/3)O3-0.25PbTiO3 transparent ceramic by two-stage sintering. J Am Ceram Soc 2010, 93: 2128-2131.
[30]
R Keech, S Shetty, K Wang, et al. Management of lead content for growth of {001}-oriented lead magnesium niobate-lead titanate thin films. J Am Ceram Soc 2016, 99: 1144-1146.
[31]
KH Brosnan, GL Messing, RJ Meyer, et al. Texture measurements in <001> fiber-oriented PMN-PT. J Am Ceram Soc 2006, 89: 1965-1971.
DOI
[32]
FK Lotgering. Topotactical reactions with ferrimagnetic oxides having hexagonal crystal structures—II. J Inorg Nucl Chem 1960, 16: 100-108.
[33]
F Li, MJ Cabral, B Xu, et al. Giant piezoelectricity of Sm-doped Pb(Mg1/3Nb2/3)O3-PbTiO3 single crystals. Science 2019, 364: 264-268.
[34]
NJ Donnelly, CA Randall. Impedance spectroscopy of PZT ceramics-measuring diffusion coefficients, mixed conduction, and Pb loss. IEEE Trans Ultrason, Ferroelect, Freq Contr 2012, 59: 1883-1887.
[35]
S Pandya, J Wilbur, J Kim, et al. Pyroelectric energy conversion with large energy and power density in relaxor ferroelectric thin films. Nat Mater 2018, 17: 432-438.
[36]
KH Hardtl, D Hennings. Distribution of A-site and B-site vacancies in (Pb, La)(Ti, Zr)O3 ceramics. J Am Ceram Soc 1972, 55: 230-231.
[37]
WL Zhu, I Fujii, W Ren, et al. Domain wall motion in A and B site donor-doped Pb(Zr0.52Ti0.48)O3 films. J Am Ceram Soc 2012, 95: 2906-2913.
[38]
H Zhou, GH Wu, N Qin, et al. Improved electrical properties and strong red emission of Pr3+-doped xK0.5Bi0.5TiO3-(1-x) Na0.5Bi0.5TiO3 lead-free ferroelectric thin films. J Am Ceram Soc 2012, 95: 483-486.
[39]
H Zhou, GH Wu, N Qin, et al. Dual enhancement of photoluminescence and ferroelectric polarization in Pr3+/La3+-codoped bismuth titanate thin films. J Am Ceram Soc 2010, 93: 2109-2112.
[40]
WH Huang, S He, AZ Hao, et al. Structural phase transition, electrical and photoluminescent properties of Pr3+-doped (1-x)Na0.5Bi0.5TiO3-xSrTiO3 lead-free ferroelectric thin films. J Eur Ceram Soc 2018, 38: 2328-2334.
[41]
LY Li, V Castaing, D Rytz, et al. Tunable trap depth for persistent luminescence by cationic substitution in Pr3+:K1-xNaxNbO3 perovskites. J Am Ceram Soc 2019, 102: 2629-2639.
[42]
N Bassiri-Gharb, I Fujii, E Hong, et al. Domain wall contributions to the properties of piezoelectric thin films. J Electroceram 2007, 19: 49-67.
[43]
R Keech, S Shetty, MA Kuroda, et al. Lateral scaling of Pb(Mg1/3Nb2/3)O3-PbTiO3 thin films for piezoelectric logic applications. J Appl Phys 2014, 115: 234106.
[44]
T Kyômen, R Sakamoto, N Sakamoto, et al. Photoluminescence properties of Pr-doped (Ca, Sr, Ba)TiO3. Chem Mater 2005, 17: 3200-3204.
[45]
XR Du, WH Huang, SK Thatikonda, et al. Improved ferroelectric and dielectric properties of Sm, La co-doped Bi4Ti3O12 multifunctional thin films with orange-red emission. J Mater Sci: Mater Electron 2019, 30: 13158-13166.
[46]
GH Haertling. PLZT electrooptic materials and applications— A review. Ferroelectrics 1987, 75: 25-55.
[47]
ZM Ma, YC Zhang, CJ Lu, et al. Synthesis and properties of La-doped PMN-PT transparent ferroelectric ceramics. J Mater Sci: Mater Electron 2018, 29: 6985-6990.
[48]
DB Lin, ZR Li, SJ Zhang, et al. Electric-field and temperature induced phase transitions in Pb(Mg1/3Nb2/3)O3-0.3PbTiO3 single crystals. J Appl Phys 2010, 108: 034112.
Publication history
Copyright
Acknowledgements
Rights and permissions

Publication history

Received: 07 April 2020
Revised: 15 September 2020
Accepted: 15 September 2020
Published: 05 November 2020
Issue date: February 2021

Copyright

© The Author(s) 2020

Acknowledgements

We appreciate the funding from the National Natural Science Foundation of China (Nos. 51502232 and 51972263), National Basic Research Project (No. JCKY2016208A002), and Advanced Manufacturing Project (No. 41423020111).

Rights and permissions

This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if changes were made.

The images or other third party material in this article are included in the article’s Creative Commons licence, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons licence and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder.

To view a copy of this licence, visit http://creativecommons.org/licenses/by/4.0/.

Return