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Research Article | Open Access

Effect of starting materials and sintering temperature on microstructure and optical properties of Y2O3:Yb3+ 5 at% transparent ceramics

R. P. YAVETSKIYa( )A. E. BALABANOVaS. V. PARKHOMENKOaO. S. KRYZHANOVSKAaA. G. DOROSHENKOaP. V. MATEYCHENKOaA. V. TOLMACHEVaJiang LIbNan JIANGbL. GHEORGHEcM. ENCULESCUd
Institute for Single Crystals of NAS of Ukraine, 60 Nauky Ave., Kharkiv 61072, Ukraine
Key Laboratory of Transparent Opto-functional Inorganic Materials, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 201899, China
National Institute for Laser, Plasma and Radiation Physics, Laboratory of Solid-State Quantum Electronics, Magurele 077125, Ilfov, Romania
National Institute of Materials Physics, Magurele 077125, Ilfov, Romania
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Abstract

Y2O3:Yb3+ 5 at% ceramics have been synthesized by the reactive sintering method using different commercial yttria powders (Alfa-Micro, Alfa-Nano, and ITO-V) as raw materials. It has been shown that all Y2O3 starting powders consist from agglomerates up to 5-7 μm in size which are formed from 25-60 nm primary particles. High-energy ball milling allows to significantly decreasing the median particle size D50 below 500 nm regardless of the commercial powders used. Sintering experiments indicate that powder mixtures fabricated from Alfa-Nano yttria powders have the highest sintering activity, while (Y0.86La0.09Yb0.05)2O3 ceramics sintered at 1750 ℃ for 10 h are characterized by the highest transmittance of about 45%. Y2O3:Yb3+ ceramics have been obtained by the reactive sintering at 1750-1825 ℃ using Alfa-Nano Y2O3 powders and La2O3+ZrO2 as a complex sintering aid. The effects of the sintering temperature on densification processes, microstructure, and optical properties of Y2O3:Yb3+ 5 at% ceramics have been studied. It has been shown that Zr4+ ions decrease the grain growth of Y2O3:Yb3+ ceramics for sintering temperatures 1750-1775 ℃. Further increasing the sintering temperature was accompanied by a sharp increase of the average grain size of ceramics referred to changes of structure and chemical composition of grain boundaries, as well as their mobility. It has been determined that the optimal sintering temperature to produce high-dense yttria ceramics with transmittance of 79%-83% and average grain size of 8 μm is 1800 ℃. Finally, laser emission at ~1030.7 nm with a slope efficiency of 10% was obtained with the most transparent Y2O3:Yb3+ 5 аt% ceramics sintered.

References

[1]
J Kong, J Lu, K Takaichi, et al. Diode-pumped Yb:Y2O3 ceramic laser. Appl Phys Lett 2003, 82: 2556-2558.
[2]
A Shirakawa, K Takaichi, H Yagi, et al. Diode-pumped mode-locked Yb3+:Y2O3 ceramic laser. Opt Express 2003, 11: 2911-2916.
[3]
K Takaichi, H Yagi, JR Lu, et al. Highly efficient continuous-wave operation at 1030 and 1075 nm wavelengths of LD-pumped Yb3+:Y2O3 ceramic lasers. Appl Phys Lett 2004, 84: 317-319.
[4]
M Tokurakawa, A Shirakawa, KI Ueda, et al. Continuous wave and mode-locked Yb3+:Y2O3 ceramic thin disk laser. Opt Express 2012, 20: 10847-10852.
[5]
VV Petrov, EV Pestryakov, VA Petrov, et al. The design of Yb:Y2O3 ceramic diode-pumped multipass amplifier operating at cryogenic temperatures. Laser Phys 2014, 24: 074014.
[6]
W Kim, G Villalobos, C Baker, et al. Ceramic windows and gain media for high-energy lasers. Opt Eng 2013, 52: 021003.
[7]
J Wang, J Ma, J Zhang, et al. Yb:Y2O3 transparent ceramics processed with hot isostatic pressing. Opt Mater 2017, 71: 117-120.
[8]
XY Huang, X Zhang, ZW Hu, et al. Fabrication of Y2O3 transparent ceramics by hot isostatic pressing from precipitated nanopowders. Opt Mater 2019, 92: 359-365.
[9]
J Wang, DL Yin, J Ma, et al. Pump laser induced photodarkening in ZrO2-doped Yb:Y2O3 laser ceramics. J Eur Ceram Soc 2019, 39: 635-640.
[10]
H Furuse, S Nakasawa, H Yoshida, et al. Transparent ultrafine Yb3+:Y2O3 laser ceramics fabricated by spark plasma sintering. J Am Ceram Soc 2018, 101: 694-702.
[11]
SS Balabanov, YV Bykov, SV Egorov, et al. Yb:(YLa)2O3 laser ceramics produced by microwave sintering. Quantum Electron 2013, 43: 396-400.
[12]
M Ivanov, Y Kopylov, V Kravchenko, et al. Highly transparent ytterbium doped yttrium lanthanum oxide ceramics. J Rare Earths 2014, 32: 254-258.
[13]
G Stanciu, L Gheorghe, F Voicu, et al. Highly transparent Yb:Y2O3 ceramics obtained by solid-state reaction and combined sintering procedures. Ceram Int 2019, 45: 3217-3222.
[14]
OS Kryzhanovska, VN Baumer, SV Parkhomenko, et al. Formation peculiarities and optical properties of highly-doped (Y0.86La0.09Yb0.05)2O3 transparent ceramics. Ceram Int 2019, 45: 16002-16007.
[15]
SS Li, XW Zhu, J Li, et al. Fabrication of 5 at.% Yb:(La0.1Y0.9)2O3 transparent ceramics by chemical precipitation and vacuum sintering. Opt Mater 2017, 71: 56-61.
[16]
SS Balabanov, YV Bykov, SV Egorov, et al. Transparent Yb:(YLa)2O3 ceramics produced by self-propagating high-temperature synthesis and microwave sintering. Opt Mater 2013, 35: 727-730.
[17]
DA Permin, SV Kurashkin, AV Novikova, et al. Synthesis and luminescence properties of Yb-doped Y2O3, Sc2O3 and Lu2O3 solid solutions nanopowders. Opt Mater 2018, 77: 240-245.
[18]
M Ivanov, Y Kopylov, V Kravchenko, et al. Sintering and optical quality of highly transparent Yb-doped yttrium lanthanum oxide ceramics. Phys Status Solidi C 2013, 10: 940-944.
[19]
XJ Mao, XK Li, MH Feng, et al. Cracks in transparent La-doped yttria ceramics and the formation mechanism. J Eur Ceram Soc 2015, 35: 3137-3143.
[20]
QH Yang, SZ Lu, B Zhang, et al. Preparation and laser performance of Nd-doped yttrium lanthanum oxide transparent ceramic. Opt Mater 2011, 33: 692-694.
[21]
Q Yi, SM Zhou, H Teng, et al. Structural and optical properties of Tm:Y2O3 transparent ceramic with La2O3, ZrO2 as composite sintering aid. J Eur Ceram Soc 2012, 32: 381-388.
[22]
LL Zhu, YJ Park, L Gan, et al. Fabrication and characterization of highly transparent Er:Y2O3 ceramics with ZrO2 and La2O3 additives. Ceram Int 2017, 43: 13127-13132.
[23]
Y Hu, M Shahid, W Pan. Tunable ultraviolet/visible to near-infrared down-conversion luminescence in the Er3+, Yb3+ co-doped (Y0.88La0.09Zr0.03)2O3 transparent ceramics. Opt Mater 2017, 72: 40-44.
[24]
P Deshmukh, S Satapathy, A Ahlawat, et al. (Yb0.01Zr0.02La0.01Y0.96)2O3 transparent ceramic: Fabrication, structural and optical characterization for IR emission. J Mater Sci: Mater Electron 2017, 28: 11020-11028.
[25]
KJ Ning, J Wang, DW Luo, et al. Fabrication and characterization of highly transparent Yb3+:Y2O3 ceramics. Opt Mater 2015, 50: 21-24.
[26]
LL Zhu, YJ Park, L Gan, et al. Effects of ZrO2-La2O3 co-addition on the microstructural and optical properties of transparent Y2O3 ceramics. Ceram Int 2017, 43: 8525-8530.
[27]
PL Chen, IW Chen. Grain boundary mobility in Y2O3: Defect mechanism and dopant effects. J Am Ceram Soc 1996, 79: 1801-1809.
[28]
AP Patel, CR Stanek, MR Levy, et al. Defect volumes of BO2 doped Y2O3 (B = Ti, Zr, Hf and Ce). Nucl Instrum Methods Phys Res, Sect B 2010, 268: 3111-3113.
[29]
NA Dulina, VN Baumer, MI Danylenko, et al. Effects of phase and chemical composition of precursor on structural and morphological properties of (Lu0.95Eu0.05)2O3 nanopowders. Ceram Int 2013, 39: 2397-2404.
[30]
VN Abramov, AI Kunznetsov. Fundamental absorption of Y2O3 and YAlO3. Sov Phys Solid State 1978, 20: 399-402.
[31]
A Ikesue, YL Aung. Synthesis of Yb:YAG ceramics without sintering additives and their performance. J Am Ceram Soc 2017, 100: 26-30.
[32]
IL Snetkov, VV Balashov. Thermo-optical properties of Ho:Y2O3 ceramics. Opt Mater 2020, 100: 109617.
[33]
RWG Wyckoff. Crystal Structures, Vol. 1, 2nd edn. New York: John Wiley Interscience Publishers, 1963.
[34]
PR Cantwell, M Tang, SJ Dillon, et al. Grain boundary complexions. Acta Mater 2014, 62: 1-48.
[35]
SA Bojarski, SL Ma, W Lenthe, et al. Changes in the grain boundary character and energy distributions resulting from a complexion transition in Ca-doped yttria. Metall Mater Trans A 2012, 43: 3532-3538.
[36]
PR Cantwell, SL Ma, SA Bojarski, et al. Expanding time-temperature-transformation (TTT) diagrams to interfaces: A new approach for grain boundary engineering. Acta Mater 2016, 106: 78-86.
[37]
IL Snetkov, IB Mukhin, SS Balabanov, et al. Efficient lasing in Yb:(YLa)2O3 ceramics. Quantum Electron 2015, 45: 95-97.
Journal of Advanced Ceramics
Pages 49-61
Cite this article:
YAVETSKIY RP, BALABANOV AE, PARKHOMENKO SV, et al. Effect of starting materials and sintering temperature on microstructure and optical properties of Y2O3:Yb3+ 5 at% transparent ceramics. Journal of Advanced Ceramics, 2021, 10(1): 49-61. https://doi.org/10.1007/s40145-020-0416-3

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Received: 30 April 2020
Revised: 06 August 2020
Accepted: 25 August 2020
Published: 21 September 2020
© The Author(s) 2020

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