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Journal of Advanced Ceramics 2021, 10(1): 49-61 https://doi.org/10.1007/s40145-020-0416-3
Research Article | Open Access | Issue | Published: 21 September 2020

Effect of starting materials and sintering temperature on microstructure and optical properties of Y2O3:Yb3+ 5 at% transparent ceramics

Show Author's Information R. P. YAVETSKIYa( ),  A. E. BALABANOVa,  S. V. PARKHOMENKOa,  O. S. KRYZHANOVSKAa,  A. G. DOROSHENKOa,  P. V. MATEYCHENKOa,  A. V. TOLMACHEVa,  Jiang LIb,  Nan JIANGb,  L. GHEORGHEc,  M. ENCULESCUd
Institute for Single Crystals of NAS of Ukraine, 60 Nauky Ave., Kharkiv 61072, Ukraine
Key Laboratory of Transparent Opto-functional Inorganic Materials, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 201899, China
National Institute for Laser, Plasma and Radiation Physics, Laboratory of Solid-State Quantum Electronics, Magurele 077125, Ilfov, Romania
National Institute of Materials Physics, Magurele 077125, Ilfov, Romania
Keywords:
microstructure, reactive sintering, transparent ceramics, grain growth, lasing
Cite this article:
YAVETSKIY RP, BALABANOV AE, PARKHOMENKO SV, et al. Effect of starting materials and sintering temperature on microstructure and optical properties of Y2O3:Yb3+ 5 at% transparent ceramics. Journal of Advanced Ceramics, 2021, 10(1): 49-61. https://doi.org/10.1007/s40145-020-0416-3
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Abstract Full text About this article

Y2O3:Yb3+ 5 at% ceramics have been synthesized by the reactive sintering method using different commercial yttria powders (Alfa-Micro, Alfa-Nano, and ITO-V) as raw materials. It has been shown that all Y2O3 starting powders consist from agglomerates up to 5-7 μm in size which are formed from 25-60 nm primary particles. High-energy ball milling allows to significantly decreasing the median particle size D50 below 500 nm regardless of the commercial powders used. Sintering experiments indicate that powder mixtures fabricated from Alfa-Nano yttria powders have the highest sintering activity, while (Y0.86La0.09Yb0.05)2O3 ceramics sintered at 1750 ℃ for 10 h are characterized by the highest transmittance of about 45%. Y2O3:Yb3+ ceramics have been obtained by the reactive sintering at 1750-1825 ℃ using Alfa-Nano Y2O3 powders and La2O3+ZrO2 as a complex sintering aid. The effects of the sintering temperature on densification processes, microstructure, and optical properties of Y2O3:Yb3+ 5 at% ceramics have been studied. It has been shown that Zr4+ ions decrease the grain growth of Y2O3:Yb3+ ceramics for sintering temperatures 1750-1775 ℃. Further increasing the sintering temperature was accompanied by a sharp increase of the average grain size of ceramics referred to changes of structure and chemical composition of grain boundaries, as well as their mobility. It has been determined that the optimal sintering temperature to produce high-dense yttria ceramics with transmittance of 79%-83% and average grain size of 8 μm is 1800 ℃. Finally, laser emission at ~1030.7 nm with a slope efficiency of 10% was obtained with the most transparent Y2O3:Yb3+ 5 аt% ceramics sintered.


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Effect of starting materials and sintering temperature on microstructure and optical properties of Y2O3:Yb3+ 5 at% transparent ceramics

Show Author's information R. P. YAVETSKIYa( ), A. E. BALABANOVa, S. V. PARKHOMENKOa, O. S. KRYZHANOVSKAa, A. G. DOROSHENKOa, P. V. MATEYCHENKOa, A. V. TOLMACHEVa, Jiang LIb, Nan JIANGb, L. GHEORGHEc, M. ENCULESCUd
Institute for Single Crystals of NAS of Ukraine, 60 Nauky Ave., Kharkiv 61072, Ukraine
Key Laboratory of Transparent Opto-functional Inorganic Materials, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 201899, China
National Institute for Laser, Plasma and Radiation Physics, Laboratory of Solid-State Quantum Electronics, Magurele 077125, Ilfov, Romania
National Institute of Materials Physics, Magurele 077125, Ilfov, Romania

Abstract

Y2O3:Yb3+ 5 at% ceramics have been synthesized by the reactive sintering method using different commercial yttria powders (Alfa-Micro, Alfa-Nano, and ITO-V) as raw materials. It has been shown that all Y2O3 starting powders consist from agglomerates up to 5-7 μm in size which are formed from 25-60 nm primary particles. High-energy ball milling allows to significantly decreasing the median particle size D50 below 500 nm regardless of the commercial powders used. Sintering experiments indicate that powder mixtures fabricated from Alfa-Nano yttria powders have the highest sintering activity, while (Y0.86La0.09Yb0.05)2O3 ceramics sintered at 1750 ℃ for 10 h are characterized by the highest transmittance of about 45%. Y2O3:Yb3+ ceramics have been obtained by the reactive sintering at 1750-1825 ℃ using Alfa-Nano Y2O3 powders and La2O3+ZrO2 as a complex sintering aid. The effects of the sintering temperature on densification processes, microstructure, and optical properties of Y2O3:Yb3+ 5 at% ceramics have been studied. It has been shown that Zr4+ ions decrease the grain growth of Y2O3:Yb3+ ceramics for sintering temperatures 1750-1775 ℃. Further increasing the sintering temperature was accompanied by a sharp increase of the average grain size of ceramics referred to changes of structure and chemical composition of grain boundaries, as well as their mobility. It has been determined that the optimal sintering temperature to produce high-dense yttria ceramics with transmittance of 79%-83% and average grain size of 8 μm is 1800 ℃. Finally, laser emission at ~1030.7 nm with a slope efficiency of 10% was obtained with the most transparent Y2O3:Yb3+ 5 аt% ceramics sintered.

Keywords: microstructure, reactive sintering, transparent ceramics, grain growth, lasing

References(37)

[1]
J Kong, J Lu, K Takaichi, et al. Diode-pumped Yb:Y2O3 ceramic laser. Appl Phys Lett 2003, 82: 2556-2558.
DOI Google Scholar
[2]
A Shirakawa, K Takaichi, H Yagi, et al. Diode-pumped mode-locked Yb3+:Y2O3 ceramic laser. Opt Express 2003, 11: 2911-2916.
DOI Google Scholar
[3]
K Takaichi, H Yagi, JR Lu, et al. Highly efficient continuous-wave operation at 1030 and 1075 nm wavelengths of LD-pumped Yb3+:Y2O3 ceramic lasers. Appl Phys Lett 2004, 84: 317-319.
DOI Google Scholar
[4]
M Tokurakawa, A Shirakawa, KI Ueda, et al. Continuous wave and mode-locked Yb3+:Y2O3 ceramic thin disk laser. Opt Express 2012, 20: 10847-10852.
DOI Google Scholar
[5]
VV Petrov, EV Pestryakov, VA Petrov, et al. The design of Yb:Y2O3 ceramic diode-pumped multipass amplifier operating at cryogenic temperatures. Laser Phys 2014, 24: 074014.
DOI Google Scholar
[6]
W Kim, G Villalobos, C Baker, et al. Ceramic windows and gain media for high-energy lasers. Opt Eng 2013, 52: 021003.
DOI Google Scholar
[7]
J Wang, J Ma, J Zhang, et al. Yb:Y2O3 transparent ceramics processed with hot isostatic pressing. Opt Mater 2017, 71: 117-120.
DOI Google Scholar
[8]
XY Huang, X Zhang, ZW Hu, et al. Fabrication of Y2O3 transparent ceramics by hot isostatic pressing from precipitated nanopowders. Opt Mater 2019, 92: 359-365.
DOI Google Scholar
[9]
J Wang, DL Yin, J Ma, et al. Pump laser induced photodarkening in ZrO2-doped Yb:Y2O3 laser ceramics. J Eur Ceram Soc 2019, 39: 635-640.
DOI Google Scholar
[10]
H Furuse, S Nakasawa, H Yoshida, et al. Transparent ultrafine Yb3+:Y2O3 laser ceramics fabricated by spark plasma sintering. J Am Ceram Soc 2018, 101: 694-702.
DOI Google Scholar
[11]
SS Balabanov, YV Bykov, SV Egorov, et al. Yb:(YLa)2O3 laser ceramics produced by microwave sintering. Quantum Electron 2013, 43: 396-400.
Google Scholar
[12]
M Ivanov, Y Kopylov, V Kravchenko, et al. Highly transparent ytterbium doped yttrium lanthanum oxide ceramics. J Rare Earths 2014, 32: 254-258.
Google Scholar
[13]
G Stanciu, L Gheorghe, F Voicu, et al. Highly transparent Yb:Y2O3 ceramics obtained by solid-state reaction and combined sintering procedures. Ceram Int 2019, 45: 3217-3222.
Google Scholar
[14]
OS Kryzhanovska, VN Baumer, SV Parkhomenko, et al. Formation peculiarities and optical properties of highly-doped (Y0.86La0.09Yb0.05)2O3 transparent ceramics. Ceram Int 2019, 45: 16002-16007.
Google Scholar
[15]
SS Li, XW Zhu, J Li, et al. Fabrication of 5 at.% Yb:(La0.1Y0.9)2O3 transparent ceramics by chemical precipitation and vacuum sintering. Opt Mater 2017, 71: 56-61.
Google Scholar
[16]
SS Balabanov, YV Bykov, SV Egorov, et al. Transparent Yb:(YLa)2O3 ceramics produced by self-propagating high-temperature synthesis and microwave sintering. Opt Mater 2013, 35: 727-730.
Google Scholar
[17]
DA Permin, SV Kurashkin, AV Novikova, et al. Synthesis and luminescence properties of Yb-doped Y2O3, Sc2O3 and Lu2O3 solid solutions nanopowders. Opt Mater 2018, 77: 240-245.
Google Scholar
[18]
M Ivanov, Y Kopylov, V Kravchenko, et al. Sintering and optical quality of highly transparent Yb-doped yttrium lanthanum oxide ceramics. Phys Status Solidi C 2013, 10: 940-944.
Google Scholar
[19]
XJ Mao, XK Li, MH Feng, et al. Cracks in transparent La-doped yttria ceramics and the formation mechanism. J Eur Ceram Soc 2015, 35: 3137-3143.
Google Scholar
[20]
QH Yang, SZ Lu, B Zhang, et al. Preparation and laser performance of Nd-doped yttrium lanthanum oxide transparent ceramic. Opt Mater 2011, 33: 692-694.
Google Scholar
[21]
Q Yi, SM Zhou, H Teng, et al. Structural and optical properties of Tm:Y2O3 transparent ceramic with La2O3, ZrO2 as composite sintering aid. J Eur Ceram Soc 2012, 32: 381-388.
DOI Google Scholar
[22]
LL Zhu, YJ Park, L Gan, et al. Fabrication and characterization of highly transparent Er:Y2O3 ceramics with ZrO2 and La2O3 additives. Ceram Int 2017, 43: 13127-13132.
DOI Google Scholar
[23]
Y Hu, M Shahid, W Pan. Tunable ultraviolet/visible to near-infrared down-conversion luminescence in the Er3+, Yb3+ co-doped (Y0.88La0.09Zr0.03)2O3 transparent ceramics. Opt Mater 2017, 72: 40-44.
DOI Google Scholar
[24]
P Deshmukh, S Satapathy, A Ahlawat, et al. (Yb0.01Zr0.02La0.01Y0.96)2O3 transparent ceramic: Fabrication, structural and optical characterization for IR emission. J Mater Sci: Mater Electron 2017, 28: 11020-11028.
DOI Google Scholar
[25]
KJ Ning, J Wang, DW Luo, et al. Fabrication and characterization of highly transparent Yb3+:Y2O3 ceramics. Opt Mater 2015, 50: 21-24.
DOI Google Scholar
[26]
LL Zhu, YJ Park, L Gan, et al. Effects of ZrO2-La2O3 co-addition on the microstructural and optical properties of transparent Y2O3 ceramics. Ceram Int 2017, 43: 8525-8530.
DOI Google Scholar
[27]
PL Chen, IW Chen. Grain boundary mobility in Y2O3: Defect mechanism and dopant effects. J Am Ceram Soc 1996, 79: 1801-1809.
DOI Google Scholar
[28]
AP Patel, CR Stanek, MR Levy, et al. Defect volumes of BO2 doped Y2O3 (B = Ti, Zr, Hf and Ce). Nucl Instrum Methods Phys Res, Sect B 2010, 268: 3111-3113.
DOI Google Scholar
[29]
NA Dulina, VN Baumer, MI Danylenko, et al. Effects of phase and chemical composition of precursor on structural and morphological properties of (Lu0.95Eu0.05)2O3 nanopowders. Ceram Int 2013, 39: 2397-2404.
DOI Google Scholar
[30]
VN Abramov, AI Kunznetsov. Fundamental absorption of Y2O3 and YAlO3. Sov Phys Solid State 1978, 20: 399-402.
Google Scholar
[31]
A Ikesue, YL Aung. Synthesis of Yb:YAG ceramics without sintering additives and their performance. J Am Ceram Soc 2017, 100: 26-30.
DOI Google Scholar
[32]
IL Snetkov, VV Balashov. Thermo-optical properties of Ho:Y2O3 ceramics. Opt Mater 2020, 100: 109617.
DOI Google Scholar
[33]
RWG Wyckoff. Crystal Structures, Vol. 1, 2nd edn. New York: John Wiley Interscience Publishers, 1963.
[34]
PR Cantwell, M Tang, SJ Dillon, et al. Grain boundary complexions. Acta Mater 2014, 62: 1-48.
DOI Google Scholar
[35]
SA Bojarski, SL Ma, W Lenthe, et al. Changes in the grain boundary character and energy distributions resulting from a complexion transition in Ca-doped yttria. Metall Mater Trans A 2012, 43: 3532-3538.
DOI Google Scholar
[36]
PR Cantwell, SL Ma, SA Bojarski, et al. Expanding time-temperature-transformation (TTT) diagrams to interfaces: A new approach for grain boundary engineering. Acta Mater 2016, 106: 78-86.
DOI Google Scholar
[37]
IL Snetkov, IB Mukhin, SS Balabanov, et al. Efficient lasing in Yb:(YLa)2O3 ceramics. Quantum Electron 2015, 45: 95-97.
DOI Google Scholar
Publication history
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Publication history

Received: 30 April 2020
Revised: 06 August 2020
Accepted: 25 August 2020
Published: 21 September 2020
Issue date: February 2021

Copyright

© The Author(s) 2020

Acknowledgements

This work was supported by the National Academy of Sciences of Ukraine by the budget programs "Support for the development of priority areas of scientific research" (KPKVK 6541230). The authors are grateful to Dr. Vyacheslav Baumer from the "SSI Institute for Single Crystals" of NAS of Ukraine, Kharkiv, Ukraine, Dr. Andrei Kuncser from the National Institute of Materials Physics, Bucharest, Romania, and to Dr. Nicolaie Pavel and Dr. Gabriela Croitoru from the National Institute for Laser, Plasma and Radiation Physics, Magurele, Romania, for their help in the characterization of the ceramic samples and the fruitful discussions of the experimental results.

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