Journal Home > Volume 9 , Issue 5
Journal of Advanced Ceramics 2020, 9(5): 641-646 https://doi.org/10.1007/s40145-020-0398-1
Rapid Communication | Open Access | Issue | Published: 25 September 2020

Effect of octahedron tilt on the structure and magnetic properties of bismuth ferrite

Show Author's Information Yang HONG,  Jun LI( ),  Han BAI,  Zhenjia SONG,  Ming WANG,  Zhongxiang ZHOU( )
School of Physics, Harbin Institute of Technology, Harbin 150001, China
Keywords:
magnetism, bismuth ferrite (BiFeO3), octahedron tilt, Raman spectrum, electromagnetic characteristics
Cite this article:
HONG Y, LI J, BAI H, et al. Effect of octahedron tilt on the structure and magnetic properties of bismuth ferrite. Journal of Advanced Ceramics, 2020, 9(5): 641-646. https://doi.org/10.1007/s40145-020-0398-1
Download citation
EndNote(RIS)
BibTeX

557

Views

29

Downloads

Citations

24

Crossref

N/A

WoS

25

Scopus

1

CSCD

Abstract Full text About this article

Multiferroic BiFeO3-based ceramics were synthesized using the rapid liquid-phase sintering method. The rare-earth ion (Sm3+, Gd3+, Y3+) doping causes structural distortion without changing the intrinsic rhombohedral perovskite structure. Raman analysis shows that the effect of doping on E modes is greater than A1 modes, and the microstructure of FeO6 octahedron can be regulated by ion doping. A-site trivalent ion doped ceramics exhibit improved magnetism compared with pure BiFeO3 ceramic, which originated from the suppressed spiral spin structure of Fe ions. The tilt of FeO6 octahedron as a typical structure instability causes the anomalous change of the imaginary part of permittivity at high frequency, and doped ceramics exhibit natural resonance around 16-17 GHz.


menu
Abstract
Full text
Outline
About this article

Effect of octahedron tilt on the structure and magnetic properties of bismuth ferrite

Show Author's information Yang HONG, Jun LI( ), Han BAI, Zhenjia SONG, Ming WANG, Zhongxiang ZHOU( )
School of Physics, Harbin Institute of Technology, Harbin 150001, China

Abstract

Multiferroic BiFeO3-based ceramics were synthesized using the rapid liquid-phase sintering method. The rare-earth ion (Sm3+, Gd3+, Y3+) doping causes structural distortion without changing the intrinsic rhombohedral perovskite structure. Raman analysis shows that the effect of doping on E modes is greater than A1 modes, and the microstructure of FeO6 octahedron can be regulated by ion doping. A-site trivalent ion doped ceramics exhibit improved magnetism compared with pure BiFeO3 ceramic, which originated from the suppressed spiral spin structure of Fe ions. The tilt of FeO6 octahedron as a typical structure instability causes the anomalous change of the imaginary part of permittivity at high frequency, and doped ceramics exhibit natural resonance around 16-17 GHz.

Keywords: magnetism, bismuth ferrite (BiFeO3), octahedron tilt, Raman spectrum, electromagnetic characteristics

References(26)

[1]
ZH Chen, ZL Luo, CW Huang, et al. Low-symmetry monoclinic phases and polarization rotation path mediated by epitaxial strain in multiferroic BiFeO3 thin films. Adv Funct Mater 2011, 21: 133-138.
DOI Google Scholar
[2]
JG Wu, Z Fan, DQ Xiao, et al. Multiferroic bismuth ferrite-based materials for multifunctional applications: Ceramic bulks, thin films and nanostructures. Prog Mater Sci 2016, 84: 335-402.
DOI Google Scholar
[3]
SS Wang, Z Wu, J Chen, et al. Lead-free sodium niobate nanowires with strong piezo-catalysis for dye wastewater degradation. Ceram Int 2019, 45: 11703-11708.
DOI Google Scholar
[4]
H Pan, F Li, Y Liu, et al. Ultrahigh-energy density lead-free dielectric films via polymorphic nanodomain design. Science 2019, 365: 578-582.
DOI Google Scholar
[5]
M Ismail, Z Wu, LH Zhang, et al. High-efficient synergy of piezocatalysis and photocatalysis in bismuth oxychloride nanomaterial for dye decomposition. Chemosphere 2019, 228: 212-218.
DOI Google Scholar
[6]
JP Ma, J Ren, YM Jia, et al. High efficiency bi-harvesting light/vibration energy using piezoelectric zinc oxide nanorods for dye decomposition. Nano Energy 2019, 62: 376-383.
DOI Google Scholar
[7]
Y Hong, J Li, H Bai, et al. Role of finite-size effect in BiFeO3 nanoparticles to enhance ferromagnetism and microwave absorption. Appl Phys Lett 2020, 116: 013103.
DOI Google Scholar
[8]
MM Shirolkar, XL Dong, JN Li, et al. Observation of nanotwinning and room temperature ferromagnetism in sub-5 nm BiFeO3 nanoparticles: A combined experimental and theoretical study. Phys Chem Chem Phys 2016, 18: 25409-25420.
DOI Google Scholar
[9]
F Kubel, H Schmid. Structure of a ferroelectric and ferroelastic monodomain crystal of the perovskite BiFeO3. Acta Crystallogr Sect B 1990, 46: 698-702.
DOI Google Scholar
[10]
J Wang. Epitaxial BiFeO3 multiferroic thin film heterostructures. Science 2003, 299: 1719-1722.
DOI Google Scholar
[11]
I Sosnowska, M Azuma, R Przeniosło, et al. Crystal and magnetic structure in Co-substituted BiFeO3. Inorg Chem 2013, 52: 13269-13277.
DOI Google Scholar
[12]
O Delaire, MB Stone, J Ma, et al. Anharmonic phonons and magnons in BiFeO3. Phys Rev B 2012, 85: 064405.
DOI Google Scholar
[13]
I Sosnowska, M Loewenhaupt, WIF David, et al. Searching for the magnetic spiral arrangement in Bi0.7La0.3FeO3. Mater Sci Forum 1993, 133-136: 683-686.
DOI Google Scholar
[14]
CS Tu, PY Chen, CS Chen, et al. Tailoring microstructure and photovoltaic effect in multiferroic Nd-substituted BiFeO3 ceramics by processing atmosphere modification. J Eur Ceram Soc 2018, 38: 1389-1398.
DOI Google Scholar
[15]
S Pattanayak, RNP Choudhary, PR Das, et al. Effect of Dy-substitution on structural, electrical and magnetic properties of multiferroic BiFeO3 ceramics. Ceram Int 2014, 40: 7983-7991.
DOI Google Scholar
[16]
N Wang, Y Li, FL Wang, et al. Structure, magnetic and ferroelectric properties of Sm and Sc doped BiFeO3 polycrystalline ceramics. J Alloys Compd 2019, 789: 894-903.
DOI Google Scholar
[17]
XL Xu, LB Xiao, YM Jia, et al. Pyro-catalytic hydrogen evolution by Ba0.7Sr0.3TiO3 nanoparticles: Harvesting cold-hot alternation energy near room-temperature. Energy Environ Sci 2018, 11: 2198-2207.
DOI Google Scholar
[18]
AK Jena, S Satapathy, J Mohanty. Magnetic properties and oxygen migration induced resistive switching effect in Y substituted multiferroic bismuth ferrite. Phys Chem Chem Phys 2019, 21: 15854-15860.
DOI Google Scholar
[19]
CH Yang, D Kan, I Takeuchi, et al. Doping BiFeO3: Approaches and enhanced functionality. Phys Chem Chem Phys 2012, 14: 15953-15962.
DOI Google Scholar
[20]
J Wei, CF Wu, TT Yang, et al. Temperature-driven multiferroic phase transitions and structural instability evolution in lanthanum-substituted bismuth ferrite. J Phys Chem C 2019, 123: 4457-4468.
DOI Google Scholar
[21]
G Catalan, JF Scott. Physics and applications of bismuth ferrite. Adv Mater 2009, 21: 2463-2485.
DOI Google Scholar
[22]
RC Lennox, MC Price, W Jamieson, et al. Strain driven structural phase transformations in dysprosium doped BiFeO3 ceramics. J Mater Chem C 2014, 2: 3345-3360.
DOI Google Scholar
[23]
DP Dutta, BP Mandal, MD Mukadam, et al. Improved magnetic and ferroelectric properties of Sc and Ti codoped multiferroic nano BiFeO3 prepared via sonochemical synthesis. Dalton Trans 2014, 43: 7838.
DOI Google Scholar
[24]
P Sharma, S Satapathy, D Varshney, et al. Effect of sintering temperature on structure and multiferroic properties of Bi0.825Sm0.175FeO3 ceramics. Mater Chem Phys 2015, 162: 469-476.
DOI Google Scholar
[25]
X Liu, LS Wang, YT Ma, et al. Enhanced microwave absorption properties by tuning cation deficiency of perovskite oxides of two-dimensional LaFeO3/C composite in X-band. ACS Appl Mater Interfaces 2017, 9: 7601-7610.
DOI Google Scholar
[26]
J Yuan, ZL Hou, HJ Yang, et al. High dielectric loss and microwave absorption behavior of multiferroic BiFeO3 ceramic. Ceram Int 2013, 39: 7241-7246.
DOI Google Scholar
Publication history
Copyright
Acknowledgements
Rights and permissions

Publication history

Received: 22 April 2020
Revised: 31 May 2020
Accepted: 18 June 2020
Published: 25 September 2020
Issue date: October 2020

Copyright

© The author(s) 2020

Acknowledgements

This study was supported by the National Natural Science Foundation of China (51502054), the Postdoctoral Science Foundation of China (2014M551236), and the Postdoctoral Science Foundation of Heilongjiang Province (LBH-Z14083).

Rights and permissions

This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if changes were made.

The images or other third party material in this article are included in the article’s Creative Commons licence, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons licence and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder.

To view a copy of this licence, visit http://creativecommons. org/licenses/by/4.0/.

Return