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Nano-magnetic ferrites with composition Mg1-xZnxFe2O4 (x = 0.3, 0.4, 0.5, 0.6, and 0.7) have been prepared by coprecipitation method. X-ray diffraction (XRD) studies showed that the lattice parameter was found to increase from 8.402 to 8.424 Å with Zn2+ ion content from 0.3 to 0.7. Fourier transform infrared (FTIR) spectra revealed two prominent peaks corresponding to tetrahedral and octahedral at around 560 and 430 cm-1 respectively that confirmed the spinel phase of the samples. Transmission electron microscopy (TEM) images showed that the particle size was noted to increase from 18 to 24 nm with an increase in Zn content from x = 0.3 to 0.7. The magnetic properties were studied by vibrating sample magnetometer (VSM) and electron paramagnetic resonance (EPR) which ascertained the superparamagnetic behavior of the samples and contribution of superexchange interactions. The maximum magnetization was found to vary from 23.80 to 32.78 emu/g that increased till x = 0.5 and decreased thereafter. Further, X-ray photoelectron spectroscopy (XPS) was employed to investigate the chemical composition and substantiate their oxidation states.


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Zn2+ substituted superparamagnetic MgFe2O4 spinel-ferrites: Investigations on structural and spin-interactions

Show Author's information Lakshita PHOR( )Surjeet CHAHALVinod KUMAR( )
Department of Physics, Deenbandhu Chhotu Ram University of Science and Technology, Murthal 131039, Haryana, India

Abstract

Nano-magnetic ferrites with composition Mg1-xZnxFe2O4 (x = 0.3, 0.4, 0.5, 0.6, and 0.7) have been prepared by coprecipitation method. X-ray diffraction (XRD) studies showed that the lattice parameter was found to increase from 8.402 to 8.424 Å with Zn2+ ion content from 0.3 to 0.7. Fourier transform infrared (FTIR) spectra revealed two prominent peaks corresponding to tetrahedral and octahedral at around 560 and 430 cm-1 respectively that confirmed the spinel phase of the samples. Transmission electron microscopy (TEM) images showed that the particle size was noted to increase from 18 to 24 nm with an increase in Zn content from x = 0.3 to 0.7. The magnetic properties were studied by vibrating sample magnetometer (VSM) and electron paramagnetic resonance (EPR) which ascertained the superparamagnetic behavior of the samples and contribution of superexchange interactions. The maximum magnetization was found to vary from 23.80 to 32.78 emu/g that increased till x = 0.5 and decreased thereafter. Further, X-ray photoelectron spectroscopy (XPS) was employed to investigate the chemical composition and substantiate their oxidation states.

Keywords:

nanoparticles (NPs), nanospinel ferrites, structural properties, magnetism, coprecipitation method
Received: 28 March 2020 Revised: 27 May 2020 Accepted: 10 June 2020 Published: 12 September 2020 Issue date: October 2020
References(54)
[1]
SB Singh, C Srinivas, BV Tirupanyam, et al. Structural, thermal and magnetic studies of MgxZn1−xFe2O4 nanoferrites: Study of exchange interactions on magnetic anisotropy. Ceram Int 2016, 42: 19179-19186.
[2]
C Srinivas, BV Tirupanyam, SS Meena, et al. Structural and magnetic characterization of co-precipitated NixZn1-xFe2O4 ferrite nanoparticles. J Magn Magn Mater 2016, 407: 135-141.
[3]
S Rahman, K Nadeem, M Anis-Ur-rehman, et al. Structural and magnetic properties of ZnMg-ferrite nanoparticles prepared using the co-precipitation method. Ceram Int 2013, 39: 5235-5239.
[4]
S Ghatak, M Sinha, AK Meikap, et al. Electrical transport behavior of nonstoichiometric magnesium-zinc ferrite. Mater Res Bull 2010, 45: 954-960.
[5]
M Niaz Akhtar, N Yahya, A Sattar, et al. Investigations of structural and magnetic properties of nanostructured Ni0.5+xZn0.5-xFe2O4 Magnetic feeders for CSEM application. Int J Appl Ceram Technol 2015, 12: 625-637.
[6]
S Chahal, S Gaba, A Kumar, et al. Effect of Mg2+ substitution on structural and magnetic properties of nano zinc ferrite. AIP Conf Proc 2018, 2006: 030014.
[7]
MD Shultz, S Calvin, PP Fatouros, et al. Enhanced ferrite nanoparticles as MRI contrast agents. J Magn Magn Mater 2007, 311: 464-468.
[8]
V Šepelák, I Bergmann, D Menzel, et al. Magnetization enhancement in nanosized MgFe2O4 prepared by mechanosynthesis. J Magn Magn Mater 2007, 316: e764-e767.
[9]
R Ghosh, L Pradhan, YP Devi, et al. Induction heating studies of Fe3O4 magnetic nanoparticles capped with oleic acid and polyethylene glycol for hyperthermia. J Mater Chem 2011, 21: 13388.
[10]
NV Jadhav, AI Prasad, A Kumar, et al. Synthesis of oleic acid functionalized Fe3O4 magnetic nanoparticles and studying their interaction with tumor cells for potential hyperthermia applications. Colloids Surfaces B: Biointerfaces 2013, 108: 158-168.
[11]
P Masina, T Moyo, HMI Abdallah. Synthesis, structural and magnetic properties of ZnxMg1-xFe2O4 nanoferrites. J Magn Magn Mater 2015, 381: 41-49.
[12]
HY Liu, AM Li, XX Ding, et al. Magnetic induction heating properties of Mg1-xZnxFe2O4 ferrites synthesized by co-precipitation method. Solid State Sci 2019, 93: 101-108.
[13]
PY Reyes-Rodríguez, DA Cortés-Hernández, JC Escobedo-Bocardo, et al. Structural and magnetic properties of Mg-Zn ferrites (Mg1-xZnxFe2O4) prepared by sol-gel method. J Magn Magn Mater 2017, 427: 268-271.
[14]
V Kassabova-Zhetcheva, L Pavlova, B Samuneva, et al. Characterization of superparamagnetic MgxZn1-xFe2O4 powders. Open Chem 2007, 5: 107-117.
[15]
SS Khot, NS Shinde, BP Ladgaonkar, et al. Magnetic and structural properties of magnesium zinc ferrites synthesized at different temperature. Adv Appl Sci Res 2011, 2: 460-471.
[16]
S Rahman, K Nadeem, M Anis-Ur-rehman, et al. Structural and magnetic properties of ZnMg-ferrite nanoparticles prepared using the co-precipitation method. Ceram Int 2013, 39: 5235-5239.
[17]
C Choodamani, GP Nagabhushana, S Ashoka, et al. Structural and magnetic studies of Mg(1-x)ZnxFe2O4 nanoparticles prepared by a solution combustion method. J Alloys Compd 2013, 578: 103-109.
[18]
L Phor, V Kumar. Self-cooling by ferrofluid in magnetic field. SN Appl Sci 2019, 1: 1696.
[19]
KA Mohammed, AD Al-Rawas, AM Gismelseed, et al. Infrared and structural studies of Mg1-xZnxFe2O4 ferrites. Physica B 2012, 407: 795-804.
[20]
N Kumari, V Kumar, SK Singh. Effect of Cr3+ substitution on properties of nano-ZnFe2O4. J Alloys Compd 2015, 622: 628-634.
[21]
IH Gul, AZ Abbasi, F Amin, et al. Structural, magnetic and electrical properties of Co1−xZnxFe2O4 synthesized by co-precipitation method. J Magn Magn Mater 2007, 311: 494-499.
[22]
A Globus, H Pascard, V Cagan. Distance between magnetic ions and fundamental properties in ferrites. J Phys Colloques 1977, 38: C1-163-C1-168.
[23]
SA Mazen, MH Abdallah, BA Sabrah, et al. The effect of titanium on some physical properties of CuFe2O4. Phys Stat Sol (a) 1992, 134: 263-271.
[24]
HM Zaki, SH Al-Heniti, TA Elmosalami. Structural, magnetic and dielectric studies of copper substituted nano-crystalline spinel magnesium zinc ferrite. J Alloys Compd 2015, 633: 104-114.
[25]
P Thakur, R Sharma, M Kumar, et al. Superparamagnetic La doped Mn-Zn nano ferrites: Dependence on dopant content and crystallite size. Mater Res Express 2016, 3: 075001.
[26]
BF Levine. D-electron effects on bond susceptibilities and ionicities. Phys Rev B 1973, 7: 2591.
[27]
L Phor, V Kumar. Structural, magnetic and dielectric properties of lanthanum substituted Mn0.5Zn0.5Fe2O4. Ceram Int 2019, 45: 22972-22980.
[28]
VK Lakhani, TK Pathak, NH Vasoya, et al. Structural parameters and X-ray Debye temperature determination study on copper-ferrite-aluminates. Solid State Sci 2011, 13: 539-547.
[29]
L Phor, V Kumar. Structural, thermomagnetic, and dielectric properties of Mn0.5Zn0.5GdxFe2-xO4 (x = 0, 0.025, 0.050, 0.075, and 0.1). J Adv Ceram 2020, 9: 243-254.
[30]
RD Waldron. Infrared spectra of ferrites. Phys Rev 1955, 99: 1727.
[31]
MC Chhantbar,, UN Trivedi, PV Tanna, et al. Infrared spectral studies of Zn-substituted CuFeCrO4 spinel ferrite system. Indian J Phys 2004, 78A: 321-326.
[32]
HM Zaki, HA Dawoud. Far-infrared spectra for copper- zinc mixed ferrites. Phys B: Condens Matter 2010, 405: 4476-4479.
[33]
KB Modi, UN Trivedi, PU Sharma, et al. Study of elastic properties of fine particle-copper zinc ferrites through infrared spectroscopy. Indian J Pure Ap Phy 2006, 44: 165-168.
[34]
S Chahal, N Rani, A Kumar, et al. UV-irradiated photocatalytic performance of yttrium doped ceria for hazardous Rose Bengal dye. Appl Surf Sci 2019, 493: 87-93.
[35]
P Priyadharsini, A Pradeep, PS Rao, et al. Structural, spectroscopic and magnetic study of nanocrystalline Ni-Zn ferrites. Mater Chem Phys 2009, 116: 207-213.
[36]
L Phor, V Kumar. Self-cooling device based on thermomagnetic effect of MnxZn1-xFe2O4 (x = 0.3, 0.4, 0.5, 0.6, 0.7)/ferrofluid. J Mater Sci: Mater Electron 2019, 30: 9322-9333.
[37]
R Tholkappiyan, K Vishista. Combustion synthesis of Mg-Er ferrite nanoparticles: Cation distribution and structural, optical, and magnetic properties. Mater Sci Semicond Process 2015, 40: 631-642.
[38]
N Kumari, V Kumar, S Khasa, et al. Chemical synthesis and magnetic investigations on Cr3+ substituted Zn-ferrite superparamagnetic nano-particles. Ceram Int 2015, 41: 1907-1911.
[39]
SA Mazen, SF Mansour, HM Zaki. Some physical and magnetic properties of Mg-Zn ferrite. Cryst Res Technol 2003, 38: 471-478.
[40]
TJ Shinde, AB Gadkari, PN Vasambekar. Magnetic properties and cation distribution study of nanocrystalline Ni-Zn ferrites. J Magn Magn Mater 2013, 333: 152-155.
[41]
EC Stoner, EP Wohlfarth. A mechanism of magnetic hystersis in hetrogeneous alloys. Philos T R Soc A 240, 1948, 240: 599-642.
[42]
BK Bammannavar, LR Nair, RB Pujar, BK Chougule. Preparation, characterization and physical properties of Mg-Zn ferrites. Indian J Eng Mater Sci 2007, 14: 381-385.
[43]
V Kumar, A Rana, MS Yadav, et al. Size-induced effect on nano-crystalline CoFe2O4. J Magn Magn Mater 2008, 320: 1729-1734.
[44]
S Thota, SC Kashyap, SK Sharma, et al. Micro Raman, Mossbauer and magnetic studies of manganese substituted zinc ferrite nanoparticles: Role of Mn. J Phys Chem Solids 2016, 91: 136-144.
[45]
H Montiel, G Alvarez, M Gutiérrez, et al. Microwave absorption in Ni-Zn ferrites through the Curie transition. J Alloys Compd 2004, 369: 141-143.
[46]
P Chu, DL Mills, R Arias. Exchange/dipole collective spin-wave modes of ferromagnetic nanosphere arrays. Phys Rev B 2006, 73: 094405.
[47]
E Schlömann. Ferromagnetic resonance in polycrystalline ferrites with large anisotropy—I. J Phys Chem Solids 1958, 6: 257-266.
[48]
E Schlömann, JR Zeender. Ferromagnetic resonance in polycrystalline nickel ferrite aluminate. J Appl Phys 1958, 29: 341-343.
[49]
C Srivastava, M Patni. Ferromagnetic relaxation processes in polycrystalline magnetic insulators. J Magn Reson 1969 1974, 15: 359-366.
[50]
T Yamashita, P Hayes. Analysis of XPS spectra of Fe2+ and Fe3+ ions in oxide materials. Appl Surf Sci 2008, 254: 2441-2449.
[51]
ZK Yan, JM Gao, Y Li, et al. Hydrothermal synthesis and structure evolution of metal-doped magnesium ferrite from saprolite laterite. RSC Adv 2015, 5: 92778-92787.
[52]
J Liu, M Zeng, RH Yu. Surfactant-free synthesis of octahedral ZnO/ZnFe2O4 heterostructure with ultrahigh and selective adsorption capacity of malachite green. Sci Rep 2016, 6: 25074.
[53]
N Guijarro, P Bornoz, M Prévot, et al. Evaluating spinel ferrites MFe2O4 (M = Cu, Mg, Zn) as photoanodes for solar water oxidation: Prospects and limitations. Sustainable Energy Fuels 2018, 2: 103-117.
[54]
R Dom, AS Chary, R Subasri, et al. Solar hydrogen generation from spinel ZnFe2O4 photocatalyst: Effect of synthesis methods. Int J Energy Res 2015, 39: 1378-1390.
Publication history
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Publication history

Received: 28 March 2020
Revised: 27 May 2020
Accepted: 10 June 2020
Published: 12 September 2020
Issue date: October 2020

Copyright

© The author(s) 2020

Acknowledgements

We are thankful to Thapar Institute of Engineering & Technology for providing a vibrating sample magnetometer facility.

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