AI Chat Paper
Note: Please note that the following content is generated by AMiner AI. SciOpen does not take any responsibility related to this content.
{{lang === 'zh_CN' ? '文章概述' : 'Summary'}}
{{lang === 'en_US' ? '中' : 'Eng'}}
Chat more with AI
View PDF
Collect
Submit Manuscript AI Chat Paper
Show Outline
Outline
Show full outline
Hide outline
Outline
Show full outline
Hide outline
Research Article | Open Access

Creep deformation behavior during densification of ZrB2-SiBCN ceramics with ZrO2 additive

Bo FENGZhenhang WANGYunhao FANJinghua GUYue ZHANG( )
Key Laboratory of Aerospace Materials and Performance (Ministry of Education), School of Materials Science and Engineering, Beihang University, Beijing 100191, China
Show Author Information

Abstract

ZrB2-SiBCN ceramics with ZrO2 additive are hot-pressed under a constant applied pressure. The densification behavior of the composites is studied in a view of creep deformation by means of the Bernard-Granger and Guizard model. With determination of the stress exponent (n) and the apparent activation energy (Qd), the specific deformation mechanisms controlling densification are supposed. Within lower temperature ranges of 1300-1400 ℃, the operative mechanism is considered to be grain boundary sliding accommodated by atom diffusion of the polymer-derived SiBCN (n = 1, Qd = 123±5 kJ/mol) and by viscous flow of the amorphous SiBCN (n = 2, Qd = 249±5 kJ/mol). At higher temperatures, the controlling mechanism transforms to lattice or intra-granular diffusion creep (n = 3-5) due to gradual consumption of the amorphous phase. It is suggested that diffusion of oxygen ions inside ZrO2 into the amorphous SiBCN decreases the viscosity, modifies the fluidity, and contributes to the grain boundary mobility.

References

[1]
SQ Guo. Densification of ZrB2-based composites and their mechanical and physical properties: A review. J Eur Ceram Soc 2009, 29: 995-1011.
[2]
WG Fahrenholtz, GE Hilmas, IG Talmy, et al. Refractory diborides of zirconium and hafnium. J Am Ceram Soc 2007, 90: 1347-1364.
[3]
AL Chamberlain, WG Fahrenholtz, GE Hilmas. Pressureless sintering of zirconium diboride. J Am Ceram Soc 2006, 89: 450-456.
[4]
F Monteverde, A Bellosi, L Scatteia. Processing and properties of ultra-high temperature ceramics for space applications. Mat Sci Eng A 2008, 485: 415-421.
[5]
RV Krishnarao, VV Bhanuprasad, G Madhusudhan Reddy. ZrB2-SiC based composites for thermal protection by reaction sintering of ZrO2+B4C+Si. J Adv Ceram 2017, 6: 320-329.
[6]
F Monteverde, A Bellosi, S Guicciardi. Processing and properties of zirconium diboride-based composites. J Eur Ceram Soc 2002, 22: 279-288.
[7]
Z Ahmadi, B Nayebi, M Shahedi Asl, et al. Sintering behavior of ZrB2-SiC composites doped with Si3N4: A fractographical approach. Ceram Int 2017, 43: 9699-9708.
[8]
MS Asl, B Nayebi, Z Ahmadi, et al. Effects of carbon additives on the properties of ZrB2-based composites: A review. Ceram Int 2018, 44: 7334-7348.
[9]
ZF Zhang, JJ Sha, YF Zu, et al. Fabrication and mechanical properties of self-toughening ZrB2-SiC composites from in situ reaction. J Adv Ceram 2019, 8: 527-536.
[10]
B Feng, Y Zhang, BY Li, et al. Medium-temperature sintering efficiency of ZrB2 ceramics using polymer- derived SiBCN as a sintering aid. J Am Ceram Soc 2019, 102: 855-866.
[11]
P Colombo, G Mera, R Riedel, et al. Polymer-derived ceramics: 40 years of research and innovation in advanced ceramics. J Am Ceram Soc 2010, 93: 1805-1837.
[12]
C Stabler, E Ionescu, M Graczyk-Zajac, et al. Silicon oxycarbide glasses and glass-ceramics: “All-Rounder” materials for advanced structural and functional applications. J Am Ceram Soc 2018, 101: 4817-4856.
[13]
R Riedel, LM Ruswisch, LN An, et al. Amorphous silicoboron carbonitride ceramic with very high viscosity at temperatures above 1500°C. J Am Ceram Soc 1998, 81: 3341-3344.
[14]
LN An, R Riedel, C Konetschny, et al. Newtonian viscosity of amorphous silicon carbonitride at high temperature. J Am Ceram Soc 1998, 81: 1349-1352.
[15]
NV Ravi Kumar, R Mager, Y Cai, et al. High temperature deformation behaviour of crystallized Si-B-C-N ceramics obtained from a boron modified poly(vinyl)silazane polymeric precursor. Scripta Mater 2004, 51: 65-69.
[16]
NV Ravi Kumar, S Prinz, Y Cai, et al. Crystallization and creep behavior of Si-B-C-N ceramics. Acta Mater 2005, 53: 4567-4578.
[17]
C Stabler, F Roth, M Narisawa, et al. High-temperature creep behavior of a SiOC glass ceramic free of segregated carbon. J Eur Ceram Soc 2016, 36: 3747-3753.
[18]
PF Zhang, B Yang, Z Lu, et al. Effect of AlN and ZrO2 on the microstructure and property of the 2Si-B-3C-N ceramic. Ceram Int 2018, 44: 3406-3411.
[19]
E Ionescu, C Linck, C Fasel, et al. Polymer-derived SiOC/ZrO2 ceramic nanocomposites with excellent high- temperature stability. J Am Ceram Soc 2010, 93: 241-250.
[20]
G Bernard-Granger, A Addad, G Fantozzi, et al. Spark plasma sintering of a commercially available granulated zirconia powder: Comparison with hot-pressing. Acta Mater 2010, 58: 3390-3399.
[21]
JY Zhang, H Zhan, ZY Fu, et al. In-situ synthesis and sintering of mullite glass composites by SPS. J Adv Ceram 2014, 3: 165-170.
[22]
G Bernard-Granger, C Guizard. Spark plasma sintering of a commercially available granulated zirconia powder: I. Sintering path and hypotheses about the mechanism(s) controlling densification. Acta Mater 2007, 55: 3493-3504.
[23]
RL Coble. Diffusion models for hot pressing with surface energy and pressure effects as driving forces. J Appl Phys 1970, 41: 4798-4807.
[24]
SK Kashyap, R Mitra. Densification behavior involving creep during spark plasma sintering of ZrB2-SiC based ultra-high temperature ceramic composites. Ceram Int 2020, 46: 5028-5036.
[25]
A Mukherjee, JE Bird, JE Dorn. Experimental correlations for high-temperature creep. Lawrence Berkeley National Laboratory. 1968, LBNL Report #: UCRL-18526.
[26]
AS Helle, KE Easterling, MF Ashby. Hot-isostatic pressing diagrams: New developments. Acta Metall 1985, 33: 2163-2174.
[27]
DCC Lam, FF Lange, AG Evans. Mechanical properties of partially dense alumina produced from powder compacts. J Am Ceram Soc 1994, 77: 2113-2117.
[28]
N Chawake, NTBN Koundinya, AK Srivastav, et al. On correlation between densification kinetics during spark plasma sintering and compressive creep of B2 aluminides. Scripta Mater 2015, 107: 63-66.
[29]
L Ramond, G Bernard-Granger, A Addad, et al. Sintering of a quasi-crystalline powder using spark plasma sintering and hot-pressing. Acta Mater 2010, 58: 5120-5128.
[30]
GH Liu, RD Li, TC Yuan, et al. Spark plasma sintering of pure TiCN: Densification mechanism, grain growth and mechanical properties. Int J Refract Met Hard Mater 2017, 66: 68-75.
[31]
ZB Zhang, F Zeng, JJ Han, et al. Synthesis and characterization of a new liquid polymer precursor for Si-B-C-N ceramics. J Mater Sci 2011, 46: 5940-5947.
[32]
RC Garvie. Stabilization of the tetragonal structure in zirconia microcrystals. J Phys Chem 1978, 82: 218-224.
[33]
HB Li, KM Liang, SR Gu. Stability of t-ZrO2 in zirconia powder prepared by sol-gel process. J Tsinghua Univ (Sci & Tech) 2001, 41: 13-15.
[34]
SQ Guo, Y Kagawa, T Nishimura, et al. Elastic properties of spark plasma sintered (SPSed) ZrB2-ZrC-SiC composites. Ceram Int 2008, 34: 1811-1817.
[35]
SQ Guo, T Nishimura, T Mizuguchi, et al. Mechanical properties of hot-pressed ZrB2-MoSi2-SiC composites. J Eur Ceram Soc 2008, 28: 1891-1898.
[36]
IG Talmy, JA Zaykoski, CA Martin. Flexural creep deformation of ZrB2/SiC ceramics in oxidizing atmosphere. J Am Ceram Soc 2008, 91: 1441-1447.
[37]
M Mallik, KK Ray, R Mitra. Effect of Si3N4 addition on compressive creep behavior of hot-pressed ZrB2-SiC composites. J Am Ceram Soc 2014, 97: 2957-2964.
[38]
J Meléndez-Martínez, A Domínguez-Rodríguez, F Monteverde, et al. Characterisation and high temperature mechanical properties of zirconium boride-based materials. J Eur Ceram Soc 2002, 22: 2543-2549.
[39]
WD Kingery, HK Bowen, DR Uhlmann. Introduction to Ceramics, 2nd edn. New York: Wiley, 1976.
Journal of Advanced Ceramics
Pages 544-557
Cite this article:
FENG B, WANG Z, FAN Y, et al. Creep deformation behavior during densification of ZrB2-SiBCN ceramics with ZrO2 additive. Journal of Advanced Ceramics, 2020, 9(5): 544-557. https://doi.org/10.1007/s40145-020-0393-6

823

Views

49

Downloads

20

Crossref

N/A

Web of Science

18

Scopus

1

CSCD

Altmetrics

Received: 08 March 2020
Revised: 14 May 2020
Accepted: 29 May 2020
Published: 19 June 2020
© The author(s) 2020

This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if changes were made.

The images or other third party material in this article are included in the article’s Creative Commons licence, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons licence and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder.

To view a copy of this licence, visit http://creativecommons.org/licenses/by/4.0/.

Return