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Research Article | Open Access

Single-source-precursor synthesis and phase evolution of SiC-TaC-C ceramic nanocomposites containing core-shell structured TaC@C nanoparticles

Zhaoju YUa,b( )Yujing YANGaKangwei MAOaYao FENGcQingbo WENc( )Ralf RIEDELc
College of Materials, Key Laboratory of High Performance Ceramic Fibers (Xiamen University), Ministry of Education, Xiamen 361005, China
College of Materials, Fujian Key Laboratory of Advanced Materials, Xiamen University, Xiamen 361005, China
Technische Universität Darmstadt, Institut für Materialwissenschaft, Darmstadt 64287, Germany
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Abstract

A novel single-source-precursor for SiC-TaC-C nanocomposites was successfully synthesized by the chemical reaction between a polycarbosilane (allylhydridopolycarbosilane, AHPCS) and tantalum(V) chloride (TaCl5), which was confirmed by Fourier transform infrared spectra (FTIR) measurement. After pyrolysis of the resultant single-source-precursors at 900 ℃, amorphous ceramic powders were obtained. The 900 ℃ ceramics were annealed at different temperatures in the range of 1200-1600 ℃ to gain SiC-TaC-C nanocomposites. The phase evolution of ceramic nanocomposites was investigated by X-ray diffraction (XRD) and transmission electron microscopy (TEM). The results indicate that the TaC starts to crystallize at lower temperature than the β-SiC. It is particularly worth pointing out that the unique core-shell structured TaC@C nanoparticles were in-situ formed and homogeneously distributed in the ceramic matrix after annealing at 1400 ℃. Even at a high temperature of 1600 ℃, the grain sizes of β-SiC and TaC are smaller than 30 nm, fulfilling the definition of nanocomposites. The present study related to SiC-TaC-C nanocomposites paves a new road for enriching ultra-high temperature ceramic family suitable for structural/functional applications in harsh environment.

References

[1]
E Ionescu, S Bernard, R Lucas, et al. Polymer-derived ultra-high temperature ceramics (UHTCs) and related materials. Adv Eng Mater 2019, 21: 1900269.
[2]
P Wu, SC Liu, XR Jiang. Effect of multi-walled carbon nanotube addition on the microstructures and mechanical properties of Ti(C,N)-based cermets. J Adv Ceram 2018, 7: 58-63.
[3]
CQ Xue, HJ Zhou, JB Hu, et al. Fabrication and microstructure of ZrB2-ZrC-SiC coatings on C/C composites by reactive melt infiltration using ZrSi2 alloy. J Adv Ceram 2018, 7: 64-71.
[4]
KX Gui, FY Liu, G Wang, et al. Microstructural evolution and performance of carbon fiber-toughened ZrB2 ceramics with SiC or ZrSi2 additive. J Adv Ceram 2018, 7: 343-351.
[5]
ZF Zhang, JJ Sha, YF Zu, et al. Fabrication and mechanical properties of self-toughening ZrB2-SiC composites from in situ reaction. J Adv Ceram 2019, 8: 527-536.
[6]
A Nisar, S Ariharan, T Venkateswaran, et al. Oxidation studies on TaC based ultra-high temperature ceramic composites under plasma arc jet exposure. Corros Sci 2016, 109: 50-61.
[7]
WG Fahrenholtz, EJ Wuchina, WE Lee, et al. Ultra-high Temperature Ceramics. Hoboken, NJ, USA: John Wiley & Sons, Inc, 2014.
[8]
YZ Liu, YH Jiang, R Zhou, et al. First principles study the stability and mechanical properties of MC (M=Ti, V, Zr, Nb, Hf and Ta) compounds. J Alloys Compd 2014, 582: 500-504.
[9]
F Rezaei, MG Kakroudi, V Shahedifar, et al. Densification, microstructure and mechanical properties of hot pressed tantalum carbide. Ceram Int 2017, 43: 3489-3494.
[10]
ZK Chen, X Xiong, GD Li, et al. Ablation behaviors of carbon/carbon composites with C-SiC-TaC multi- interlayers. Appl Surf Sci 2009, 255: 9217-9223.
[11]
S Madhavarao, CRB Raju, GSVS Kumar. Investigation of friction stir welding of metal matrix composites using a coated tool. Mater Today: Proc 2018, 5: 7735-7742.
[12]
A Nino, T Hirabara, S Sugiyama, et al. Preparation and characterization of tantalum carbide (TaC) ceramics. Int J Refract Met Hard Mater 2015, 52: 203-208.
[13]
L Silvestroni, L Pienti, S Guicciardi, et al. Strength and toughness: The challenging case of TaC-based composites. Compos Part B: Eng 2015, 72: 10-20.
[14]
D Bianchi, F Nasuti, M Onofri, et al. Thermochemical erosion analysis for chraphite/carbon-carbon rocket nozzles. J Propuls Power 2011, 27: 197-205.
[15]
LX Chen, ZQ Liu, Q Shen. Enhancing tribological performance by anodizing micro-textured surfaces with nano-MoS2 coatings prepared on aluminum-silicon alloys. Tribol Int 2018, 122: 84-95.
[16]
Z Cui, XZ Ke, EL Li, et al. Electronic and optical properties of titanium-doped GaN nanowires. Mater Des 2016, 96: 409-415.
[17]
Z Cui, EL Li, XZ Ke, et al. Adsorption of alkali-metal atoms on GaN nanowires photocathode. Appl Surf Sci 2017, 423: 829-835.
[18]
M Miller-Oana, P Neff, M Valdez, et al. Oxidation behavior of aerospace materials in high enthalpy flows using an oxyacetylene torch facility. J Am Ceram Soc 2015, 98: 1300-1307.
[19]
E Khaleghi, YS Lin, MA Meyers, et al. Spark plasma sintering of tantalum carbide. Scr Mater 2010, 63: 577-580.
[20]
JX Liu, YM Kan, GJ Zhang. Pressureless sintering of tantalum carbide ceramics without additives. J Am Ceram Soc 2010, 93: 370-373.
[21]
A Nieto, A Kumar, D Lahiri, et al. Oxidation behavior of graphene nanoplatelet reinforced tantalum carbide composites in high temperature plasma flow. Carbon 2014, 67: 398-408.
[22]
XH Zhang, GE Hilmas, WG Fahrenholtz. Densification and mechanical properties of TaC-based ceramics. Mater Sci Eng: A 2009, 501: 37-43.
[23]
IG Talmy, JA Zaykoski, MM Opeka. Synthesis, processing and properties of TaC-TaB2-C ceramics. J Eur Ceram Soc 2010, 30: 2253-2263.
[24]
H Liu, LM Liu, F Ye, et al. Microstructure and mechanical properties of the spark plasma sintered TaC/SiC composites: Effects of sintering temperatures. J Eur Ceram Soc 2012, 32: 3617-3625.
[25]
L Silvestroni, A Bellosi, C Melandri, et al. Microstructure and properties of HfC and TaC-based ceramics obtained by ultrafine powder. J Eur Ceram Soc 2011, 31: 619-627.
[26]
L Silvestroni, D Sciti. Transmission electron microscopy on Hf- and Ta-carbides sintered with TaSi2. J Eur Ceram Soc 2011, 31: 3033-3043.
[27]
H Pu, YR Niu, C Hu, et al. Ablation of vacuum plasma sprayed TaC-based composite coatings. Ceram Int 2015, 41: 11387-11395.
[28]
YR Niu, H Pu, LP Huang, et al. Microstructure and ablation property of TaC-SiC composite coatings. Key Eng Mater 2016, 697: 535-538.
[29]
LM Liu, F Ye, ZG Zhang, et al. Microstructure and mechanical properties of the spark plasma sintered TaC/ SiC composites. Mater Sci Eng: A 2011, 529: 479-484.
[30]
R Eatemadi, Z Balak. Investigating the effect of SPS‎ parameters on densification ‎and fracture toughness of ZrB2-SiC nanocomposite‎. Ceram Int 2019, 45: 4763-4770.
[31]
SQ Guo. High-temperature mechanical behavior of ZrB2-based composites with micrometer- and nano-sized SiC particles. J Am Ceram Soc 2018, 101: 2707-2711.
[32]
LJ Wang, W Jiang, LD Chen. Fabrication and characterization of nano-SiC particles reinforced TiC/SiC nanocomposites. Mater Lett 2004, 58: 1401-1404.
[33]
E Ionescu, HJ Kleebe, R Riedel. Silicon-containing polymer-derived ceramic nanocomposites (PDC-NCs): Preparative approaches and properties. Chem Soc Rev 2012, 41: 5032.
[34]
QB Wen, YP Xu, BB Xu, et al. Single-source-precursor synthesis of dense SiC/HfCxN1-x-based ultrahigh-temperature ceramic nanocomposites. Nanoscale 2014, 6: 13678-13689.
[35]
J Yuan, S Hapis, H Breitzke, et al. Single-source-precursor synthesis of hafnium-containing ultrahigh-temperature ceramic nanocomposites (UHTC-NCs). Inorg Chem 2014, 53: 10443-10455.
[36]
J Yuan, M Galetz, XG Luan, et al. High-temperature oxidation behavior of polymer-derived SiHfBCN ceramic nanocomposites. J Eur Ceram Soc 2016, 36: 3021-3028.
[37]
J Yuan, D Li, KE Johanns, et al. Preparation of dense SiHf(B)CN-based ceramic nanocomposites via rapid spark plasma sintering. J Eur Ceram Soc 2017, 37: 5157-5165.
[38]
QB Wen, Y Feng, ZJ Yu, et al. Microwave absorption of SiC/HfCxN1-x/C ceramic nanocomposites with HfCxN1-x- carbon core-shell particles. J Am Ceram Soc 2016, 99: 2655-2663.
[39]
QB Wen, R Riedel, E Ionescu. Solid-solution effects on the high-temperature oxidation behavior of polymer- derived (Hf,Ta)C/SiC and (Hf,Ti)C/SiC ceramic nanocomposites. Adv Eng Mater 2019, 21: 1800879.
[40]
QB Wen, R Riedel, E Ionescu. Significant improvement of the short-term high-temperature oxidation resistance of dense monolithic HfC/SiC ceramic nanocomposites upon incorporation of Ta. Corros Sci 2018, 145: 191-198.
[41]
QB Wen, ZJ Yu, YP Xu, et al. SiC/HfyTa1-yCxN1-x/C ceramic nanocomposites with HfyTa1-yCxN1-x-carbon core-shell nanostructure and the influence of the carbon- shell thickness on electrical properties. J Mater Chem C 2018, 6: 855-864.
[42]
QB Wen, XG Luan, L Wang, et al. Laser ablation behavior of SiHfC-based ceramics prepared from a single-source precursor: Effects of Hf-incorporation into SiC. J Eur Ceram Soc 2019, 39: 2018-2027.
[43]
QB Wen, ZJ Yu, XM Liu, et al. Mechanical properties and electromagnetic shielding performance of single-source- precursor synthesized dense monolithic SiC/HfCxN1-x/C ceramic nanocomposites. J Mater Chem C 2019, 7: 10683-10693.
[44]
T Cai, WF Qiu, D Liu, et al. Synthesis of soluble poly-yne polymers containing zirconium and silicon and corresponding conversion to nanosized ZrC/SiC composite ceramics. Dalton Trans 2013, 42: 4285.
[45]
YT Li, WJ Han, H Li, et al. Synthesis of nano-crystalline ZrB2/ZrC/SiC ceramics by liquid precursors. Mater Lett 2012, 68: 101-103.
[46]
J Cheng, XZ Wang, H Wang, et al. Preparation and high-temperature behavior of HfC-SiC nanocomposites derived from a non-oxygen single-source-precursor. J Am Ceram Soc 2017, 100: 5044-5055.
[47]
X Long, CW Shao, J Wang, et al. Synthesis of soluble and meltable pre-ceramic polymers for Zr-containing ceramic nanocomposites. Appl Organometal Chem 2018, 32: e3942.
[48]
ZJ Yu, X Lv, SY Lai, et al. ZrC-ZrB2-SiC ceramic nanocomposites derived from a novel single-source precursor with high ceramic yield. J Adv Ceram 2019, 8: 112-120.
[49]
TH Huang, ZJ Yu, XM He, et al. One-pot synthesis and characterization of a new, branched polycarbosilane bearing allyl groups. Chin Chem Lett 2007, 18: 754-757.
[50]
DF Shriver, MA Drezdzon. The Manipulation of Air-sensitive Compounds, 2nd edn. New York, USA: John Wiley &Sons Chichester, 1986.
[51]
J Rodríguez-Carvajal. Recent advances in magnetic structure determination by neutron powder diffraction. Phys B: Condens Matter 1993, 192: 55-69.
[52]
P Amorós, D Beltrán, C Guillem, et al. Synthesis and characterization of SiC/MC/C ceramics (M=Ti, Zr, Hf) starting from totally non-oxidic precursors. Chem Mater 2002, 14: 1585-1590.
[53]
WJ Li, D Li, X Gao, et al. A study on the thermal conversion of scheelite-type ABO4 into perovskite-type AB(O,N)3. Dalton Trans 2015, 44: 8238-8246.
[54]
QB Wen, ZJ Yu, R Riedel. The fate and role of in situ formed carbon in polymer-derived ceramics. Prog Mater Sci 2020, 109: 100623.
Journal of Advanced Ceramics
Pages 320-328
Cite this article:
YU Z, YANG Y, MAO K, et al. Single-source-precursor synthesis and phase evolution of SiC-TaC-C ceramic nanocomposites containing core-shell structured TaC@C nanoparticles. Journal of Advanced Ceramics, 2020, 9(3): 320-328. https://doi.org/10.1007/s40145-020-0371-z

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Received: 06 January 2020
Revised: 17 February 2020
Accepted: 27 February 2020
Published: 05 June 2020
© The Author(s) 2020

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