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Journal of Advanced Ceramics 2020, 9(2): 183-192 https://doi.org/10.1007/s40145-020-0358-9
Research Article | Open Access | Issue | Published: 07 April 2020

P–E hysteresis loop going slim in Ba0.3Sr0.7TiO3-modified Bi0.5Na0.5TiO3 ceramics for energy storage applications

Show Author's Information Dongxu LIa,  Zong-Yang SHENa( ),  Zhipeng LIa,  Wenqin LUOa,  Xingcai WANGb,  Zhumei WANGa,  Fusheng SONGa,  Yueming LIa
Energy Storage and Conversion Ceramic Materials Engineering Laboratory of Jiangxi Province, China National Light Industry Key Laboratory of Functional Ceramic Materials, School of Materials Science and Engineering, Jingdezhen Ceramic Institute, Jingdezhen 333000, China
Chengdu Hongke Electronic Technology Co., Ltd., Chengdu 610000, China
Keywords:
energy storage ceramics, Ba0.3Sr0.7TiO3 (BST), Bi0.5Na0.5TiO3 (BNT), relaxor ferroelectrics, pulsed power capacitor
Cite this article:
LI D, SHEN Z-Y, LI Z, et al. P–E hysteresis loop going slim in Ba0.3Sr0.7TiO3-modified Bi0.5Na0.5TiO3 ceramics for energy storage applications. Journal of Advanced Ceramics, 2020, 9(2): 183-192. https://doi.org/10.1007/s40145-020-0358-9
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Abstract Full text About this article

(Ba0.3Sr0.7)x(Bi0.5Na0.5)1-xTiO3 (BSxBNT, x = 0.3–0.8) ceramics were prepared to investigate their structure, dielectric and ferroelectric properties. BSxBNT ceramics possess pure perovskite structure accompanied from a tetragonal symmetry to pseudo-cubic one with the increase of x value, being confirmed by X-ray diffraction (XRD) and Raman results. The Tm corresponding to a temperature in the vicinity of maximum dielectric constant gradually decreases from 110 ℃ (x = 0.3) to –45 ℃ (x = 0.8), across Tm = 36 ℃ (x = 0.5) with a maximum dielectric constant (ɛr = 5920 @1 kHz) around room temperature. The saturated polarization Ps gradually while the remnant polarization Pr sharply decreases with the increase of x value, making the P–E hysteresis loop of BSxBNT ceramics goes slim. A maximum difference between Ps and Pr (Ps–Pr) is obtained for BSxBNT ceramics with x = 0.5, at which a high recoverable energy density (Wrec = 1.04 J/cm3) is achieved under an applied electric field of 100 kV/cm with an efficiency of η = 77%. Meanwhile, the varied temperature P–E loops, fatigue measurements, and electric breakdown characteristics for the sample with x = 0.5 indicate that it is promising for pulsed power energy storage capacitor candidate materials.


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About this article

P–E hysteresis loop going slim in Ba0.3Sr0.7TiO3-modified Bi0.5Na0.5TiO3 ceramics for energy storage applications

Show Author's information Dongxu LIa, Zong-Yang SHENa( ), Zhipeng LIa, Wenqin LUOa, Xingcai WANGb, Zhumei WANGa, Fusheng SONGa, Yueming LIa
Energy Storage and Conversion Ceramic Materials Engineering Laboratory of Jiangxi Province, China National Light Industry Key Laboratory of Functional Ceramic Materials, School of Materials Science and Engineering, Jingdezhen Ceramic Institute, Jingdezhen 333000, China
Chengdu Hongke Electronic Technology Co., Ltd., Chengdu 610000, China

Abstract

(Ba0.3Sr0.7)x(Bi0.5Na0.5)1-xTiO3 (BSxBNT, x = 0.3–0.8) ceramics were prepared to investigate their structure, dielectric and ferroelectric properties. BSxBNT ceramics possess pure perovskite structure accompanied from a tetragonal symmetry to pseudo-cubic one with the increase of x value, being confirmed by X-ray diffraction (XRD) and Raman results. The Tm corresponding to a temperature in the vicinity of maximum dielectric constant gradually decreases from 110 ℃ (x = 0.3) to –45 ℃ (x = 0.8), across Tm = 36 ℃ (x = 0.5) with a maximum dielectric constant (ɛr = 5920 @1 kHz) around room temperature. The saturated polarization Ps gradually while the remnant polarization Pr sharply decreases with the increase of x value, making the P–E hysteresis loop of BSxBNT ceramics goes slim. A maximum difference between Ps and Pr (Ps–Pr) is obtained for BSxBNT ceramics with x = 0.5, at which a high recoverable energy density (Wrec = 1.04 J/cm3) is achieved under an applied electric field of 100 kV/cm with an efficiency of η = 77%. Meanwhile, the varied temperature P–E loops, fatigue measurements, and electric breakdown characteristics for the sample with x = 0.5 indicate that it is promising for pulsed power energy storage capacitor candidate materials.

Keywords: energy storage ceramics, Ba0.3Sr0.7TiO3 (BST), Bi0.5Na0.5TiO3 (BNT), relaxor ferroelectrics, pulsed power capacitor

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Publication history

Received: 20 November 2019
Revised: 30 December 2019
Accepted: 02 January 2020
Published: 07 April 2020
Issue date: April 2020

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© The author(s) 2020

Acknowledgements

This work was financially supported by National Natural Science Foundation of China (51767010), Science & Technology Key Research Project of Jiangxi Provincial Education Department (GJJ170760), and Graduate Student Innovation Fund of Jiangxi Province (YC2018- S295).

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