AI Chat Paper
Note: Please note that the following content is generated by AMiner AI. SciOpen does not take any responsibility related to this content.
{{lang === 'zh_CN' ? '文章概述' : 'Summary'}}
{{lang === 'en_US' ? '中' : 'Eng'}}
Chat more with AI
Powered by AMiner. Clicking this button will take you away from SciOpen.
Home Journal of Advanced Ceramics Article
PDF (3.4 MB)
Cite
EndNote(RIS) BibTeX
Collect
Submit Manuscript AI Chat Paper
Show Outline
Outline
Show full outline
Hide outline
Outline
Show full outline
Hide outline
Research Article | Open Access

PZT-NZF/CF ferrite flexible thick films: Structural, dielectric, ferroelectric, and magnetic characterization

J. D. BOBIĆa( ), G. Ferreira TEIXEIRAb, R. GRIGALAITISc, S. GYERGYEKd, M. M. Vijatović PETROVIĆa, M. Ap. ZAGHETEe, B. D. STOJANOVICa
Institute for Multidisciplinary Research, Belgrade University, Kneza Viseslava 1, Belgrade, Serbia
Universidade Federal de Goiás - UFG, Instituto de Química, Av Esperança s/n, Goiânia, GO, Brazil
Faculty of Physics, Vilnius University, Sauletekio al. 9, Vilnius, Lithuania
Institute Jozef Stefan, Jamova cesta 39, Ljubljana, Slovenia
Instituto de Quimica-UNESP, Araraquara, S.P., Brazil
Show Author Information

Abstract

The preparation and properties of thick flexible three-phase composite films based on lead zirconium titanate (PZT) and various ferrites (nickel zinc ferrite (NZF) and cobalt ferrite (CF)) were reported in this study. Properties of three-phase composite films were compared with pure polyvinylidene fluoride (PVDF) and PZT-PVDF films. X-ray diffraction data indicated the formation of well crystallized structure of PZT and NZF/CF phases, without the presence of undesirable phases. Scanning electron micrographs showed that the ceramic particles were dispersed homogeneously in the PVDF matrix and atomic force microscopy confirmed that the size of the particles is around 30 nm. Non-saturated hysteresis loops were evident in all samples due to the presence of highly conductive ferrite phases. Under magnetic field of 10 kOe, composite films exhibited a typical ferromagnetic response. Dielectric properties were investigated in the temperature range from -128 to 250 ℃ and frequency range of 400 Hz-1 MHz. The results showed that the value of dielectric constant of the PVDF/PZT/ferrite composites increased about 25% above the one obtained for pure PVDF.

Keywords

flexible thick filmsthree-phase compositesferroelectricitymagnetic materials

References

[1]
R Moazzami, C Hu, WH Shepherd. Electrical characteristics of ferroelectric PZT thin films for DRAM application. IEEE T Electron Dev 1992, 39: 2044-2049.
Crossref Google Scholar
[2]
Y Ahn, J Seo, D Lim, et al. Ferroelectric domain structures and polarization switching characteristics of polycrystalline BiFeO3 thin films on glass substrates. Curr Appl Phys 2015, 15: 584-587.
Crossref Google Scholar
[3]
KP Pramoda, A Huang, SR Shannigrahi. On some properties of PZT-NZF composite films manufactured by hybrid synthesis route. Ceram Int 2011, 37: 431-435.
Crossref Google Scholar
[4]
R Gupta, L Rana, M Tomar, et al. Characterization of lead zirconium titanate thin films based multifunctional energy harvesters. Thin Solid Films 2018, 652: 39-42.
Crossref Google Scholar
[5]
BD Stojanovic, AS Dzunuzovic, NI Ilic, et al. 27-Complex composites: Polymer matrix-ferroics or multiferroics. In: Magnetic, Ferroelectric, and Multiferroic Metal Oxides. BD Stojanovic, Ed. Elsevier, 2018: 559-569.
Crossref
[6]
GT Hwang, M Byun, CK Jeong, et al. Flexible piezoelectric thin-film energy harvesters and nanosensors for biomedical applications. Adv Healthcare Mater 2014, 4: 646-658.
Crossref Google Scholar
[7]
A Almusallam, ZH Luo, A Komolafe, et al. Flexible piezoelectric nano-composite films for kinetic energy harvesting from textiles. Nano Energy 2017, 33: 146-156.
Crossref Google Scholar
[8]
C Behera, RNP Choudhary, PR Das. Development of multiferroic polymer nanocomposite from PVDF and (Bi0.5Ba0.25Sr0.25)(Fe0.5Ti0.5)O3. J Mater Sci: Mater Electron 2017, 28: 2586-2597.
Google Scholar
[9]
MN Khan, N Jelani, C Li, et al. Flexible and low cost lead free composites with high dielectric constant. Ceram Int 2017, 43: 3923-3926.
Crossref Google Scholar
[10]
V Pascariu, L Padurariu, O Avadanei, et al. Dielectric properties of PZT-epoxy composite thick films. J Alloys Compd 2013, 574: 591-599.
Crossref Google Scholar
[11]
V Pascariu, O Avadanei, P Gasner, et al. Preparation and characterization of PbTiO3-epoxy resin compositionally graded thick films. Phase Transitions 2013, 86: 715-725.
Crossref Google Scholar
[12]
T Badapanda, V Senthil, S Anwar, et al. Structural and dielectric properties of polyvinyl alcohol/barium zirconium titanate polymer-ceramic composite. Curr Appl Phys 2013, 13: 1490-1495.
Crossref Google Scholar
[13]
LK Namitha, MT Sebastian. High permittivity ceramics loaded silicone elastomer composites for flexible electronics applications. Ceram Int 2017, 43: 2994-3003.
Crossref Google Scholar
[14]
ST Wang, J Sun, L Tong, et al. Superior dielectric properties in Na0.35%Ba99.65%Ti99.65%Nb0.35%O3/PVDF composites. Mater Lett 2018, 211: 114-117.
Crossref Google Scholar
[15]
N Adhlakha, KL Yadav, M Truccato, et al. Reduced leakage current and improved multiferroic properties of 0.5((1-x)BLPFO-xPZT)-0.5PVDF composite films. Ceram Int 2016, 42: 18238-18246.
Crossref Google Scholar
[16]
BC Luo, XH Wang, YP Wang, et al. Fabrication, characterization, properties and theoretical analysis of ceramic/PVDF composite flexible films with high dielectric constant and low dielectric loss. J Mater Chem A 2014, 2: 510-519.
Crossref Google Scholar
[17]
L Ruan, X Yao, Y Chang, et al. Properties and applications of the β phase poly(vinylidene fluoride). Polymers 2018, 10: 228.
Crossref Google Scholar
[18]
O García-Zaldívar, T Escamilla-Díaz, M Ramírez-Cardona, et al. Ferroelectric-paraelectric transition in a membrane with quenched-induced δ-phase of PVDF. Sci Rep 2017, 7: 5566-5573.
Crossref Google Scholar
[19]
V Sencadas, Jr Gregorio. R, Lanceros-Méndez S. α to β phase transformation and microestructural changes of PVDF films induced by uniaxial stretch. J Macromol Sci Part B 2009, 48: 514-525.
Crossref Google Scholar
[20]
L Li, MQ Zhang, MZ Rong, et al. Studies on the transformation process of PVDF from α to β phase by stretching. RSC Adv 2014, 4: 3938-3943.
Crossref Google Scholar
[21]
R Popielarz, CK Chiang. Polymer composites with the dielectric constant comparable to that of barium titanate ceramics. Mat Sci Eng B 2007, 139: 48-54.
Crossref Google Scholar
[22]
JB Bobić, M Ivanov, NI Ilić, et al. PZT-nickel ferrite and PZT-cobalt ferrite comparative study: Structural, dielectric, ferroelectric and magnetic properties of composite ceramics. Ceram Int 2018, 44: 6551-6557.
Crossref Google Scholar
[23]
N Adhlakha, KL Yadav. Study of structural, dielectric and magnetic behaviour of Ni0.75Zn0.25Fe2O4-Ba(Ti0.85Zr0.15)O3 composites. Smart Mater Struct 2012, 21: 115021.
Google Scholar
[24]
G Suresh, S Jatav, MS Ramachandra Rao, et al. Enhancement of dielectric and ferroelectric properties in cobalt ferrite doped poly(vinylidene fluoride) multiferroic composites. Mater Res Express 2017, 4: 075301.
Crossref Google Scholar
[25]
S Godara, B Kumar. Effect of Ba-Nb co-doping on the structural, dielectric, magnetic and ferroelectric properties of BiFeO3 nanoparticles. Ceram Int 2015, 41: 6912-6919.
Crossref Google Scholar
[26]
W Cai, RL Gao, CL Fu, et al. Microstructure, enhanced electric and magnetic properties of Bi0.9La0.1FeO3 ceramics prepared by microwave sintering. J Alloys Compd 2019, 774: 61-68.
Crossref Google Scholar
[27]
EW Lim, R Ismail. Conduction mechanism of valence change resistive switching memory: A survey. Electronics 2015, 4: 586-613.
Crossref Google Scholar
[28]
A Jain, KJ Prashanth, AK Sharma, et al. Dielectric and piezoelectric properties of PVDF/PZT composites: A review. Polym Eng Sci 2015, 55: 1589-1616.
Crossref Google Scholar
[29]
J Banys, R Grigalaitis, A Mikonis, et al. Distribution of relaxation times of relaxors: Comparison with dipolar glasses. Phys Status Solidi C 2009, 6: 2725-2730.
Crossref Google Scholar
[30]
G Suresh, S Jatav, PM Geethu, et al. Poly(vinylidene fluoride)-Formvar blends: Dielectric, miscibility and mechanical studies. J Phys D: Appl Phys 2018, 51: 065604.
Crossref Google Scholar
[31]
B Hilczer, J Kułek, E Markiewicz, et al. Dielectric relaxation in ferroelectric PZT-PVDF nanocomposites. J Non-Cryst Solids 2002, 305: 167-173.
Crossref Google Scholar
[32]
S Svirskas, M Simenas, J Banys, et al. Dielectric relaxation and ferromagnetic resonance in magnetoelectric (polyvinylidene-fluoride)/ferrite composites. J Polym Res 2015, 22: 141.
Crossref Google Scholar
[33]
WY Zhou, LN Dong, XZ Sui, et al. High dielectric permittivity and low loss in PVDF filled by core-shell Zn@ZnO particles. J Polym Res 2016, 23: 45.
Crossref Google Scholar
[34]
J Fu, YD Hou, MP Zheng, et al. Improving dielectric properties of PVDF composites by employing surface modified strong polarized BaTiO3 particles derived by molten salt method. ACS Appl Mater Interfaces 2015, 7: 24480-24491.
Crossref Google Scholar
[35]
P Singh, H Borkar, BP Singh, et al. Ferroelectric polymer-ceramic composite thick films for energy storage applications. AIP Adv 2014, 4: 087117.
Crossref Google Scholar
[36]
G Chen, X Lin, J Li, et al. Enhanced dielectric properties and discharged energy density of composite films using submicron PZT particles. Ceram Int 2018, 44: 15331-15337.
Crossref Google Scholar
Journal of Advanced Ceramics
Volume 8 Issue 4,
December 2019
Pages 545-554
DOI: 10.1007/s40145-019-0337-1
Cite this article:
BOBIĆ JD, TEIXEIRA GF, GRIGALAITIS R, et al. PZT-NZF/CF ferrite flexible thick films: Structural, dielectric, ferroelectric, and magnetic characterization. Journal of Advanced Ceramics, 2019, 8(4): 545-554. https://doi.org/10.1007/s40145-019-0337-1

965

Views

39

Downloads

21

Crossref

N/A

Web of Science

23

Scopus

2

CSCD

Altmetrics
Received: 06 December 2018
Revised: 16 April 2019
Accepted: 03 May 2019
Published: 04 December 2019
© The author(s) 2019

Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if changes were made.

The images or other third party material in this article are included in the article’s Creative Commons licence, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons licence and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder.

To view a copy of this licence, visit http://creativecommons.org/licenses/by/4.0/.
Return