Phase evolution, microstructure, electric properties of (Ba1-xBi0.67xNa0.33x)(Ti1-xBi0.33xSn0.67x)O3 ceramics

Xiuli CHEN; Xu LI; Huanfu ZHOU; Jie SUN; Xiaoxia LI; Xiao YAN; Congcong SUN; Junpeng SHI

doi:10.1007/s40145-019-0326-4

Journal of Advanced Ceramics 2019, 8(3): 427-437 https://doi.org/10.1007/s40145-019-0326-4

Research Article |

Open Access | Issue | Published: 05 August 2019

Phase evolution, microstructure, electric properties of (Ba_1-xBi_0.67xNa_0.33x)(Ti_1-xBi_0.33xSn_0.67x)O₃ ceramics

Show Author's Information Hide Author's Information Xiuli CHEN(

), Xu LI, Huanfu ZHOU, Jie SUN, Xiaoxia LI, Xiao YAN, Congcong SUN, Junpeng SHI

Collaborative Innovation Center for Exploration of Hidden Nonferrous Metal Deposits and Development of New Materials in Guangxi, Key Laboratory of Nonferrous Materials and New Processing Technology, Ministry of Education, School of Materials Science and Engineering, Guilin University of Technology, Guilin 541004, China

Keywords:

energy storage, thermal stability, structure

Cite this article:

CHEN X, LI X, ZHOU H, et al. Phase evolution, microstructure, electric properties of (Ba_1-xBi_0.67xNa_0.33x)(Ti_1-xBi_0.33xSn_0.67x)O₃ ceramics. Journal of Advanced Ceramics, 2019, 8(3): 427-437. https://doi.org/10.1007/s40145-019-0326-4

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Abstract

(Ba_1-xBi_0.67xNa_0.33x)(Ti_1-xBi_0.33xSn_0.67x)O₃ (abbreviated as BBNTBS, 0.02 ≤ x ≤ 0.12) ceramics were fabricated via a traditional solid state reaction method. The phase transition of BBNTBS from tetragonal to pseudo cubic is demonstrated by XRD and Raman spectra. The BBNTBS (x = 0.1) ceramics have decent properties with a high ε_r (~2250), small Δε/ε_25°C values of ±15% over a wide temperature range from -58 to 171 ℃, and low tanδ ≤ 0.02 from 10 to 200 ℃. The basic mechanisms of conduction and relaxation processes in the high temperature region were thermal activation, and oxygen vacancies might be the ionic charge transport carriers. Meanwhile, BBNTBS (x = 0.1) exhibited decent energy storage density (J_d = 0.58 J/cm³) and excellent thermal stability (the variation of J_d is less than 3% in the temperature range of 25-120 ℃), which could be a potential candidate for high energy density capacitors.

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Phase evolution, microstructure, electric properties of (Ba_1-xBi_0.67xNa_0.33x)(Ti_1-xBi_0.33xSn_0.67x)O₃ ceramics

Show Author's information Hide Author's Information Xiuli CHEN(

), Xu LI, Huanfu ZHOU, Jie SUN, Xiaoxia LI, Xiao YAN, Congcong SUN, Junpeng SHI

Abstract

Keywords: energy storage, thermal stability, structure

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Publication history

Received: 28 December 2018

Revised: 08 March 2019

Accepted: 22 March 2019

Published: 05 August 2019

Issue date: September 2019

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Acknowledgements

This work was supported by National Natural Science Foundation of China (Nos. 11664008 and 61761015), and Natural Science Foundation of Guangxi (Nos. 2018GXNSFFA050001, 2017GXNSFDA198027, and 2017GXNSFFA198011).

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