Effect of the sintering technique on the ferroelectric and d33 piezoelectric coefficients of Bi0.5(Na0.84K0.16)0.5TiO3 ceramic

G. HERNANDEZ-CUEVAS; J. R. LEYVA MENDOZA; P. E. GARCÍA-CASILLAS; C. A. RODRÍGUEZ GONZÁLEZ; J. F. HERNANDEZ-PAZ; G. HERRERA-PÉREZ; L. FUENTES-COBAS; S. DÍAZ DE LA TORRE; O. RAYMOND-HERRERA; H. CAMACHO-MONTES

doi:10.1007/s40145-019-0314-8

Journal of Advanced Ceramics 2019, 8(2): 278-288 https://doi.org/10.1007/s40145-019-0314-8

Research Article |

Open Access | Issue | Published: 13 June 2019

Effect of the sintering technique on the ferroelectric and d₃₃ piezoelectric coefficients of Bi_0.5(Na_0.84K_0.16)_0.5TiO₃ ceramic

Show Author's Information Hide Author's Information G. HERNANDEZ-CUEVAS^{^a}, J. R. LEYVA MENDOZA^{^a}, P. E. GARCÍA-CASILLAS^{^a}, C. A. RODRÍGUEZ GONZÁLEZ^{^a}, J. F. HERNANDEZ-PAZ^{^a}, G. HERRERA-PÉREZ^{^b}, L. FUENTES-COBAS^{^b}, S. DÍAZ DE LA TORRE^{^c}, O. RAYMOND-HERRERA^{^d}, H. CAMACHO-MONTES^{^a}(

)

a Instituto de Ingeniería y Tecnología, Universidad Autónoma de Ciudad Juárez, Av. Del Charro 450 Norte Cd. Juárez, Chihuahua, 32310, México

b Centro de Investigación en Materiales Avanzados, Miguel de Cervantes 120, Chihuahua 31109, Chihuahua, México

c Centro de Investigación e Innovación Tecnológica, Instituto Politécnico Nacional, Cerrada de Cecati s/n, Azcapotzalco, Santa Catarina, 02250, Ciudad de México, México

d Centro de Nanociencias y Nanotecnología, Universidad Nacional Autónoma de México, Km. 107 Carretera Tijuana-Ensenada, AP. 14, Ensenada 22860, Baja California, México

Keywords:

spark plasma sintering (SPS), lead-free piezoelectrics, sol-gel, pressureless sintering (PLS), sinter-forging (SF), piezoresponse

Cite this article:

HERNANDEZ-CUEVAS G, LEYVA MENDOZA JR, GARCÍA-CASILLAS PE, et al. Effect of the sintering technique on the ferroelectric and d₃₃ piezoelectric coefficients of Bi_0.5(Na_0.84K_0.16)_0.5TiO₃ ceramic. Journal of Advanced Ceramics, 2019, 8(2): 278-288. https://doi.org/10.1007/s40145-019-0314-8

Download citation

EndNote(RIS)

BibTeX

387

Views

Downloads

Citations

Crossref

N/A

WoS

Scopus

CSCD

Abstract Full text Electronic supplementary material About this article

Abstract

In the search of lead-free piezoelectric materials, ceramic processing techniques offer potential tools to increase the piezoelectric and ferroelectric properties in addition to new chemical compositions. Powders of pure BNKT16 (Bi_0.5(Na_0.84K_0.16)_0.5TiO₃) phase were synthesized by sol-gel method with a low crystallization temperature (750 ℃). Ceramic samples were sintered by pressureless sintering (PLS), sinter-forging (SF), and spark plasma sintering (SPS) techniques. Structural, morphological, and chemical characterizations were performed by XRD, Raman, EDS, and SEM. Sintered samples by PLS and SF exhibit rod-like grains associated to bismuth volatility. The highest remanent polarization (11.05 µC/cm²), coercive field (26.2 kV/mm), and piezoelectric coefficient (165 pC/N) were obtained for SF sample. The piezoresponse force microscopy (PFM) analysis shows that the crystallites at the nanoscale exhibit piezoelectric phenomenon and the highest piezoelectric response is reported for PLS sample. The presence of the rhombohedral phase, the increase in grain and crystallite size, and the oriented rod-like inclusions favoring the crystallographic texture are facts that enhance the piezoelectric coefficient for BNKT16 piezoceramics.

Full text

Abstract

Full text

Outline

Electronic supplementary material

About this article

Effect of the sintering technique on the ferroelectric and d₃₃ piezoelectric coefficients of Bi_0.5(Na_0.84K_0.16)_0.5TiO₃ ceramic

Show Author's information Hide Author's Information G. HERNANDEZ-CUEVAS^{^a}, J. R. LEYVA MENDOZA^{^a}, P. E. GARCÍA-CASILLAS^{^a}, C. A. RODRÍGUEZ GONZÁLEZ^{^a}, J. F. HERNANDEZ-PAZ^{^a}, G. HERRERA-PÉREZ^{^b}, L. FUENTES-COBAS^{^b}, S. DÍAZ DE LA TORRE^{^c}, O. RAYMOND-HERRERA^{^d}, H. CAMACHO-MONTES^{^a}(

)

a Instituto de Ingeniería y Tecnología, Universidad Autónoma de Ciudad Juárez, Av. Del Charro 450 Norte Cd. Juárez, Chihuahua, 32310, México

b Centro de Investigación en Materiales Avanzados, Miguel de Cervantes 120, Chihuahua 31109, Chihuahua, México

c Centro de Investigación e Innovación Tecnológica, Instituto Politécnico Nacional, Cerrada de Cecati s/n, Azcapotzalco, Santa Catarina, 02250, Ciudad de México, México

d Centro de Nanociencias y Nanotecnología, Universidad Nacional Autónoma de México, Km. 107 Carretera Tijuana-Ensenada, AP. 14, Ensenada 22860, Baja California, México

Abstract

Keywords: spark plasma sintering (SPS), lead-free piezoelectrics, sol-gel, pressureless sintering (PLS), sinter-forging (SF), piezoresponse

References(37)

[1]

ND Quan, HL Bac, DV Thiet, et al. Current development in lead-free Bi_0.5(Na,K)_0.5TiO₃-based piezoelectric materials. Adv Mater Sci Eng 2014, 2014: 365391.

Google Scholar

[2]

J Rödel, W Jo, KTP Seifert, et al. Perspective on the development of lead-free piezoceramics. J Am Ceram Soc 2009, 92: 1153-1177.

DOI Google Scholar

[3]

J Camargo, L Ramajo, F Rubio-Marcos, et al. Ferroelectric properties of Bi_0.5(Na_0.8K_0.2)_0.5TiO₃ ceramics. Adv Mater Res 2014, 975: 3-8.

DOI Google Scholar

[4]

P-Y Chen, C-C Chou, T-Y Tseng, et al. Comparative study between conventional and microwave sintered lead-free BNKT ceramics. Ferroelectrics 2009, 381: 196-200.

DOI Google Scholar

[5]

A Ullah, CW Ahn, A Hussain, et al. The effects of sintering temperatures on dielectric, ferroelectric and electric field-induced strain of lead-free Bi_0.5(Na_0.78K_0.22)_0.5TiO₃ piezoelectric ceramics synthesized by the sol-gel technique. Curr Appl Phys 2010, 10: 1367-1371.

DOI Google Scholar

[6]

K Anjali, TG Ajithkumar, PA Joy. Correlations between structure, microstructure, density and dielectric properties of the lead-free ferroelectrics Bi_0.5(Na,K)_0.5TiO₃. J Adv Dielect 2015, 5: 1550028.

DOI Google Scholar

[7]

AM Gonzalez, L Pardo, ME Montero-Cabrera, et al. Analysis of the rhombohedral-tetragonal symmetries coexistence in lead-free 0.94(Bi_0.5Na_0.5)TiO₃-0.06BaTiO₃ ceramics from nanopowders. Adv Appl Ceram 2016, 115: 96-105.

DOI Google Scholar

[8]

X Liu, SD Xue, F Li, et al. Giant electrostrain accompanying structural evolution in lead-free NBT-based piezoceramics. J Mater Chem C 2018, 6: 814-822.

DOI Google Scholar

[9]

X Liu, F Li, P Li, et al. Tuning the ferroelectric-relaxor transition temperature in NBT-based lead-free ceramics by Bi nonstoichiometry. J Eur Ceram Soc 2017, 37: 4585-4595.

DOI Google Scholar

[10]

A Sasaki, T Chiba, Y Mamiya, et al. Dielectric and piezoelectric properties of (Bi_0.5Na_0.5)TiO₃-(Bi_0.5K_0.5)TiO₃ systems. Jpn J Appl Phys 1999, 38: 5564-5567.

Google Scholar

[11]

W Li, ZJ Xu, RQ Chu, et al. Synthesis and characterization of (Na_0.85K_0.15)_0.5Bi_0.5TiO₃ ceramics by different methods. Mater Res Bull 2011, 46: 871-874.

DOI Google Scholar

[12]

E Guilmeau, S Lambert, D Chateigner, et al. Quantitative texture analysis of polyphased oxides by diffraction: Example of Bi2223 sinter-forged ceramic and Y123 foam superconductors. Mat Sci Eng B 2003, 104: 107-112.

DOI Google Scholar

[13]

JJ Hao, XH Wang, RZ Chen, et al. Preparation of textured bismuth titanate ceramics using spark plasma sintering. J Am Ceram Soc 2004, 87: 1404-1406.

DOI Google Scholar

[14]

JO Herrera Robles, CA Rodríguez González, SD de la Torre, et al. Dielectric properties of bismuth titanate densified by spark plasma sintering and pressureless sintering. J Alloys Compd 2012, 536: S511-S515.

DOI Google Scholar

[15]

J Liu, ZJ Shen, M Nygren, et al. SPS processing of bismuth-layer structured ferroelectric ceramics yielding highly textured microstructures. J Eur Ceram Soc 2006, 26: 3233-3239.

DOI Google Scholar

[16]

YM Kan, PL Wang, T Xu, et al. Spark plasma sintering of bismuth titanate ceramics. J Am Ceram Soc 2005, 88: 1631-1633.

DOI Google Scholar

[17]

XM Chen, YW Liao, HP Wang, et al. Phase structure and electric properties of Bi_0.5(Na_0.825K_0.175)_0.5TiO₃ ceramics prepared by a sol-gel method. J Alloys Compd 2010, 493: 368-371.

DOI Google Scholar

[18]

D Pérez-Mezcua, ML Calzada, I Bretos, et al. Influence of excesses of volatile elements on structure and composition of solution derived lead-free (Bi_0.50Na_0.50)_1-xBa_xTiO₃ thin films. J Eur Ceram Soc 2016, 36: 89-100.

DOI Google Scholar

[19]

J Rodríguez-Carvajal. Recent advances in magnetic structure determination by neutron powder diffraction. Phys B: Condens Matter 1993, 192: 55-69.

DOI Google Scholar

[20]

G Herrera-Pérez, I Castillo-Sandoval, O Solís-Canto, et al. Local piezo-response for lead-free Ba_0.9Ca_0.1Ti_0.9Zr_0.1O₃ electro-ceramic by switching spectroscopy. Mat Res 2018, 21: e20170605.

Google Scholar

[21]

J Kreisel, AM Glazer, P Bouvier, et al. High-pressure Raman study of a relaxor ferroelectric: The Na_0.5Bi_0.5TiO₃ perovskite. Phys Rev B 2001, 63: 174106.

DOI Google Scholar

[22]

ME Montero-Cabrera, L Pardo, A García, et al. The global and local symmetries of nanostructured ferroelectric relaxor 0.94(Bi_0.5Na_0.5)TiO₃-0.06BaTiO₃. Ferroelectrics 2014, 469: 50-60.

DOI Google Scholar

[23]

GO Jones, PA Thomas. Investigation of the structure and phase transitions in the novel A-site substituted distorted perovskite compound Na_0.5Bi_0.5TiO₃. Acta Crystallogr Sect B 2002, 58: 168-178.

DOI Google Scholar

[24]

GO Jones, J Kreisel, PA Thomas. A structural study of the (Na_1-xK_x)_0.5Bi_0.5TiO₃ perovskite series as a function of substitution (x) and temperature. Powder Diffr 2002, 17: 301-319.

DOI Google Scholar

[25]

MI Aroyo, A Kirov, C Capillas, et al. Bilbao crystallographic server. II. Representations of crystallographic point groups and space groups. Acta Cryst Sect A 2006, 62: 115-128.

DOI Google Scholar

[26]

E Kroumova, MI Aroyo, JM Perez-Mato, et al. Bilbao crystallographic server: Useful databases and tools for phase-transition studies. Phase Transitions 2003, 76: 155-170.

DOI Google Scholar

[27]

J Wang, Z Zhou, J Xue. Phase transition, ferroelectric behaviors and domain structures of (Na_1/2Bi_1/2)_1−xTiPb_xO₃ thin films. Acta Mater 2006, 54: 1691-1698.

DOI Google Scholar

[28]

A Prado-Espinosa, J Camargo, A del Campo, et al. Exploring new methodologies for the identification of the morphotropic phase boundary region in the (BiNa)TiO₃-BaTiO₃ lead free piezoceramics: Confocal Raman microscopy. J Alloys Compd 2018, 739: 799-805.

DOI Google Scholar

[29]

D Rout, KS Moon, VS Rao, et al. Study of the morphotropic phase boundary in the lead-free Na_1/2Bi_1/2TiO₃-BaTiO₃ system by Raman spectroscopy. J Ceram Soc Jpn 2009, 117: 797-800.

DOI Google Scholar

[30]

L Ramajo, J Camargo, F Rubio-Marcos, et al. Influences of secondary phases on ferroelectric properties of Bi(Na,K)TiO₃ ceramics. Ceram Int 2015, 41: 5380-5386.

DOI Google Scholar

[31]

L Ramajo, M Castro, F Rubio-Marcos, et al. Influence of MoO₃ on electrical and microstructural properties of (K_0.44Na_0.52Li_0.04)(Nb_0.86Ta_0.10Sb_0.04)O₃. J Mater Sci: Mater Electron 2013, 24: 3587-3593.

Google Scholar

[32]

A Gruverman, A Kholkin. Nanoscale ferroelectrics: Processing, characterization and future trends. Rep Prog Phys 2006, 69: 2443-2474.

DOI Google Scholar

[33]

P Bharathi, P Thomas, KBR Varma. Piezoelectric properties of individual nanocrystallites of Ba_0.85Ca_0.15Zr_0.1Ti_0.9O₃ obtained by oxalate precursor route. J Mater Chem C 2015, 3: 4762-4770.

DOI Google Scholar

[34]

CJ Howard, EH Kisi. Preferred orientation in Debye-Scherrer geometry: Interpretation of the March coefficient. J Appl Cryst 2000, 33: 1434-1435.

DOI Google Scholar

[35]

E Zolotoyabko. Fast quantitative analysis of strong uniaxial texture using a March-Dollase approach. J Appl Cryst 2013, 46: 1877-1879.

DOI Google Scholar

[36]

H Camacho-Montes, PE García-Casillas, R Rodríguez-Ramos, et al. Simulation of the stress-assisted densification behavior of a powder compact: Effect of constitutive laws. J Am Ceram Soc 2008, 91: 836-845.

DOI Google Scholar

[37]

A Ayrikyan, O Prach, NH Khansur, et al. Investigation of residual stress in lead-free BNT-based ceramic/ceramic composites. Acta Mater 2018, 148: 432-441.

DOI Google Scholar

Electronic supplementary material

File

40145_2019_314_MOESM1_ESM.pdf (158.6 KB)

About this article

Publication history

Acknowledgements

Rights and permissions

Publication history

Received: 24 September 2018

Revised: 13 December 2018

Accepted: 03 January 2019

Published: 13 June 2019

Issue date: June 2019

Copyright

Acknowledgements

The authors are indebted to CONACYT grant A1-S-9232 for their valuable support. GHC and JRLM are grateful to CONACYT for the Ph.D. scholarship.

Rights and permissions

Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if changes were made.

The images or other third party material in this article are included in the article’s Creative Commons licence, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons licence and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder.

To view a copy of this licence, visit http://creativecommons.org/licenses/by/4.0/.