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Journal of Advanced Ceramics 2018, 7(4): 352-361 https://doi.org/10.1007/s40145-018-0285-1
Research Article | Open Access | Issue | Published: 28 November 2018

Luminescent sensing film based on sulfosalicylic acid modified Tb(III)-doped yttrium hydroxide nanosheets

Show Author's Information Wei YANG,  Qiang LI( ),  Xiaohong ZHENG,  Xi LI,  Xin LI
Department of Chemistry, East China Normal University, Shanghai 200062, China
Keywords:
rare-earth hydroxide, nanosheets, thin-film sensor, chromate (CrO42–), bilirubin (BR)
Cite this article:
YANG W, LI Q, ZHENG X, et al. Luminescent sensing film based on sulfosalicylic acid modified Tb(III)-doped yttrium hydroxide nanosheets. Journal of Advanced Ceramics, 2018, 7(4): 352-361. https://doi.org/10.1007/s40145-018-0285-1
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Abstract Full text About this article

Sulfosalicylic acid (SSA) was used as an intercalation agent and an excellent antenna to synthesize layered rare-earth hydroxide (LRH) materials and directly obtain SSA-modified terbium-doped ytterbium hydroxide nanosheets by mechanical exfoliation. The crystal structure and morphologies of the LRHs and nanosheets were determined by X-ray diffraction, scanning electron microscopy, and transmission electron microscopy. The particle size and zeta potential of the prepared nanosheets were also analyzed. The as-prepared nanosheets exhibited excellent luminescent properties. The positively charged nanosheets were electrophoretically deposited on a conductive glass to form a thin film. The luminescence of this thin film can be quenched by chromate (CrO42–) and bilirubin (BR), which shows good sensing properties. The quenching mechanism of the sensing film by CrO42– and BR was discussed based on the spectra and structure of the film.


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About this article

Luminescent sensing film based on sulfosalicylic acid modified Tb(III)-doped yttrium hydroxide nanosheets

Show Author's information Wei YANG, Qiang LI( ), Xiaohong ZHENG, Xi LI, Xin LI
Department of Chemistry, East China Normal University, Shanghai 200062, China

Abstract

Sulfosalicylic acid (SSA) was used as an intercalation agent and an excellent antenna to synthesize layered rare-earth hydroxide (LRH) materials and directly obtain SSA-modified terbium-doped ytterbium hydroxide nanosheets by mechanical exfoliation. The crystal structure and morphologies of the LRHs and nanosheets were determined by X-ray diffraction, scanning electron microscopy, and transmission electron microscopy. The particle size and zeta potential of the prepared nanosheets were also analyzed. The as-prepared nanosheets exhibited excellent luminescent properties. The positively charged nanosheets were electrophoretically deposited on a conductive glass to form a thin film. The luminescence of this thin film can be quenched by chromate (CrO42–) and bilirubin (BR), which shows good sensing properties. The quenching mechanism of the sensing film by CrO42– and BR was discussed based on the spectra and structure of the film.

Keywords: rare-earth hydroxide, nanosheets, thin-film sensor, chromate (CrO42–), bilirubin (BR)

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Publication history
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Publication history

Received: 19 April 2018
Revised: 27 May 2018
Accepted: 17 June 2018
Published: 28 November 2018
Issue date: December 2018

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© The author(s) 2018

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