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A series of h-BN based composites with Yb4Si2O7N2 as a secondary phase were successfully synthesized by an in situ reaction hot pressing method. It was found that the relative density and room-temperature mechanical properties monotonically increased with increasing the content of Yb4Si2O7N2 from 20 to 50 vol%. When 50 vol% Yb4Si2O7N2 was introduced, the relative density of the composite reached 98.75%, and its flexural strength, compressive strength, fracture toughness, and hardness reached 338±10 MPa, 803±49 MPa, 2.06±0.06 MPa·m1/2, and 2.69±0.10 GPa, respectively. The strengthening effect of Yb4Si2O7N2 was mainly attributed to its high modulus and high hardness. Fine microstructure was also advantageous to strength and could lead to more tortuous crack propagation paths and then improve the fracture toughness of the composites simultaneously. Meanwhile, the composites maintained good machinability.


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Microstructure and mechanical properties of h-BN/Yb4Si2O7N2 composites

Show Author's information Juanjuan CHENa,bJixin CHENa( )Hao ZHANGa,cMinmin HUa,cMeishuan LIa
Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang, China
University of Chinese Academy of Sciences, Beijing, China
School of Materials Science and Engineering, University of Science and Technology of China, Shenyang, China

Abstract

A series of h-BN based composites with Yb4Si2O7N2 as a secondary phase were successfully synthesized by an in situ reaction hot pressing method. It was found that the relative density and room-temperature mechanical properties monotonically increased with increasing the content of Yb4Si2O7N2 from 20 to 50 vol%. When 50 vol% Yb4Si2O7N2 was introduced, the relative density of the composite reached 98.75%, and its flexural strength, compressive strength, fracture toughness, and hardness reached 338±10 MPa, 803±49 MPa, 2.06±0.06 MPa·m1/2, and 2.69±0.10 GPa, respectively. The strengthening effect of Yb4Si2O7N2 was mainly attributed to its high modulus and high hardness. Fine microstructure was also advantageous to strength and could lead to more tortuous crack propagation paths and then improve the fracture toughness of the composites simultaneously. Meanwhile, the composites maintained good machinability.

Keywords: microstructure, mechanical properties, h-BN/Yb4Si2O7N2 composites, machinability

References(36)

[1]
W Sinclair, H Simmons. Microstructure and thermal shock behaviour of BN composites. J Mater Sci Lett 1987, 6: 627–629.
[2]
A Lipp, KA Schwetz, K Hunold. Hexagonal boron nitride: Fabrication, properties and applications. J Eur Ceram Soc 1989, 5: 3–9.
[3]
G-J Zhang, J-F Yang, T Ohji, et al. In-situ reaction synthesis of non-oxide boron nitride composites. Adv Eng Mater 2002, 4: 15–17.
DOI
[4]
J Eichler, C Lesniak. Boron nitride (BN) and BN composites for high-temperature applications. J Eur Ceram Soc 2008, 28: 1105–1109.
[5]
X Zhang, R Zhang, G Chen, et al. Microstructure, mechanical properties and thermal shock resistance of hot-pressed ZrO2(3Y)–BN composites. Mat Sci Eng A 2008, 497: 195–199.
[6]
F Liang, Z Xue, L Zhao, et al. Mechanical properties and thermal shock resistance of alumina/hexagonal boron nitride composite refractories. Metall and Mat Trans A 2015, 46: 4335–4341.
[7]
LN Rusanova, AG Romashln, GI Kullkova, et al. Boron nitride ceramics: Problems and development perspectives. Powder Metall Met Ceram 1988, 27: 21–28.
[8]
G-J Zhang, J-F Yang, M Andoa, et al. Nonoxide-boron nitride composites: in situ synthesis, microstructure and properties. J Eur Ceram Soc 2002, 22: 2551–2554.
[9]
R Haubner, M Wilhelm, R Weissenbacher, et al. Boron nitrides—Properties, synthesis and applications. In: High Performance Non-Oxide Ceramics II. Structure and Bonding, Vol. 102. M Jansen, Ed. Springer Berlin Heidelberg, 2002: 1–45.
DOI
[10]
Y Li, H Wu, J Yin, et al. High electrical resistivity of pressureless sintered in situ SiC-BN composites. Scripta Mater 2013, 69: 740–743.
[11]
HPR Frederikse, AH Kahn, AL Dargoo, et al. Electrical resistivity and microwave transmission of hexagonal boron nitride. J Am Ceram Soc 1985, 68: 131–135.
[12]
H-Y Jin, H Xu, G-J Qiao, et al. Study of machinable silicon carbide–boron nitride ceramic composites. Mat Sci Eng A 2008, 483–484: 214–217.
[13]
B Zhong, GL Zhao, XX Huang, et al. Microstructure and mechanical properties of ZTA/BN machinable ceramics fabricated by reactive hot pressing. J Eur Ceram Soc 2015, 35: 641–649.
[14]
Y Li, J Yin, H Wu, et al. Enhanced electrical resistivity in SiC–BN composites with highly-active BN nanoparticles synthesized via chemical route. J Eur Ceram Soc 2015, 35: 1647–1652.
[15]
MatWeb, The online materials database, GE advanced ceramics HBN hot-pressed boron nitride. Available at http://www.matweb.com/search/datasheet.aspx?matguid=8fbbb7d47809493e9afbb7778657d5bb.
[16]
RW Trice, JW Halloran. Investigation of the physical and mechanical properties of hot-pressed boron nitride/oxide ceramic composites. J Am Ceram Soc 1999, 82: 2563–2565.
[17]
Z Tian, DC Jia, XM Duan, et al. Effects of AlN content on phase composition, microstructure and mechanical properties of BN-based composite ceramics. J Chin Ceram Soc 2013, 41: 1603–1608. (in Chinese)
[18]
X Zhang. Preparation and properties of rare earth silicate (RE2SiO5, RE2Si2O7, RE = Y, Yb) modified boron nitride matrix composites. Ph.D. Thesis. Shenyang, China: Institute of Metal Research, Chinese Academy of Sciences, 2015. (in Chinese)
[19]
X Zhang, J Chen, J Zhang, et al. High-temperature mechanical and thermal properties of h-BN/30 vol%Y2SiO5 composite. Ceram Int 2015, 41: 10891–10896.
[20]
X Zhang, J Chen, X Li, et al. Microstructure and mechanical properties of h-BN/Y2SiO5 composites. Ceram Int 2015, 41: 1279–1283.
[21]
Chen L, Chen JX. Thermal shock resistance of Y4Si2O7N2–BN composites. J Henan Normal Univ: Nat Sci Ed 2011, 39: 7072. (in Chinese)
[22]
J Takahashi, H Yamane, M Shimada, et al. Crystal structure of Lu4Si2O7N2 analyzed by the Rietveld method using the time-of-flight neutron powder diffraction pattern. J Am Ceram Soc 2002, 85: 2072–2077.
[23]
J Takahashi, H Yamane, N Hirosaki, et al. Crystal structure of rare-earth silicon-oxynitride J-phases, Ln4Si2O7N2. J Eur Ceram Soc 2005, 25: 793–799.
[24]
H Park, H-E Kim, K Niihara. Microstructural evolution and mechanical properties of Si3N4 with Yb2O3 as a sintering additive. J Am Ceram Soc 1997, 80: 750–756.
[25]
T Nishimura, M Mitomo. Phase relationships in the system Si3N4–SiO2–Yb2O3. J Mater Res 1995, 10: 240–242.
[26]
T Nishimura, M Mitomo, H Suematsu. High temperature strength of silicon nitride ceramics with ytterbium silicon oxynitride. J Mater Res 1997, 12: 203–209.
[27]
H-H Lu, J-L Huang. Effect of Y2O3 and Yb2O3 on the microstructure and mechanical properties of silicon nitride. Ceram Int 2001, 27: 621–628.
[28]
S Guo, N Hirosaki, T Nishimura, et al. Compressive creep behaviour of Yb4Si2O7N2 containing silicon nitride ceramic between 1400 and 1500 ℃. Mater Sci Technol 2003, 19: 544–548.
[29]
G Wen, GL Wu, TQ Lei, et al. Co-enhanced SiO2–BN ceramics for high-temperature dielectric applications. J Eur Ceram Soc 2000, 20: 1923–1928.
[30]
RL Coble, WD Kingery. Effect of porosity on physical properties of sintered alumina. J Am Ceram Soc 1956, 39: 377–385.
[31]
S Özcan, G Açıkbaş, N Özbay, et al. The effect of silicon nitride powder characteristics on SiAlON microstructures, densification and phase assemblage. Ceram Int 2017, 43: 10057–10065.
[32]
L Chen. Synthesis, microstructure, and properties of Y4Si2O7N2–BN composites. M.Sc. Thesis. Shenyang, China: Institute of Metal Research, Chinese Academy of Sciences, 2011. (in Chinese)
[33]
X Duan, D Jia, Y Zhou, et al. Mechanical properties and plasma erosion resistance of BNp/Al2O3–SiO2 composite ceramics. J Cent South Univ 2013, 20: 1462–1468.
[34]
N Calis Acikbas, R Kumar, F Kara, et al. Influence of β-Si3N4 particle size and heat treatment on microstructural evolution of α:β-SiAlON ceramics. J Eur Ceram Soc 2011, 31: 629–635.
[35]
S Li, J Xie, J Zhao, et al. Mechanical properties and mechanism of damage tolerance for Ti3SiC2. Mater Lett 2002, 57: 119–123.
[36]
Z Sun, J Wang, M Li, et al. Mechanical properties and damage tolerance of Y2SiO5. J Eur Ceram Soc 2008, 28: 2895–2901.
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Publication history

Received: 28 March 2018
Revised: 06 May 2018
Accepted: 07 May 2018
Published: 21 November 2018
Issue date: December 2018

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© The author(s) 2018

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