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Research Article | Open Access

Preparation of transparent nanostructured N-doped TiO2 thin films by combination of sonochemical and CVD methods with visible light photocatalytic activity

Hossein RASOULNEZHADaGhader HOSSEINZADEHb( )Reza HOSSEINZADEHcNaser GHASEMIANb
Department of Electrical & Electronics Engineering, Standard Research Institute (SRI), Karaj, Iran
Department of Chemical Engineering, University of Bonab, Bonab, Iran
Medical Laser Research Group, Medical Laser Research Center, ACECR, Tehran, Iran
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Abstract

Pollution of water resources with pesticide compounds has raised serious environmental problems, and for photocatalytic degradation of these pollutants, thin film photocatalysts are preferred to colloidal ones due to the separation problem of colloidal nanoparticles. In this work, nanostructured TiO2 and N-doped TiO2 thin films with high transparency were deposited on glass and quartz substrates through sonochemical–chemical vapor deposition (CVD) method. The films prepared on glass and quartz substrates had nanocubic and nanospherical morphology, respectively. The presence of N atoms in the structure of TiO2 resulted in a decrease in the band gap energy of TiO2 and also in the reduction of photogenerated electron–hole recombination rate. Furthermore, the presence of N atoms induced the formation of Ti3+ species which can act as hole trapping centers. The prepared thin films were also used for the visible light photocatalytic degradation of paraoxon pesticide. According to these results among the prepared thin films, the N-doped TiO2 thin films have higher photocatalytic activity than pure TiO2 thin films. Moreover, in comparison with the thin films deposited on quartz substrate, the films on glass substrate have higher photocatalytic performance, which can be related to the special nanocubic morphology of these samples.

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Journal of Advanced Ceramics
Pages 185-196
Cite this article:
RASOULNEZHAD H, HOSSEINZADEH G, HOSSEINZADEH R, et al. Preparation of transparent nanostructured N-doped TiO2 thin films by combination of sonochemical and CVD methods with visible light photocatalytic activity. Journal of Advanced Ceramics, 2018, 7(3): 185-196. https://doi.org/10.1007/s40145-018-0270-8

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Received: 11 December 2017
Revised: 03 March 2018
Accepted: 16 March 2018
Published: 10 October 2018
© The author(s) 2018

Open Access The articles published in this journal are distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution, and reproduction in any medium, provided you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made.

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