Synthesis and formation mechanism of titanium lead carbide

C. LING; W. B. TIAN; P. ZHANG; W. ZHENG; Y. M. ZHANG; Z. M. SUN

doi:10.1007/s40145-018-0269-1

Journal of Advanced Ceramics 2018, 7(2): 178-183 https://doi.org/10.1007/s40145-018-0269-1

Research Article |

Open Access | Issue | Published: 17 April 2018

Synthesis and formation mechanism of titanium lead carbide

Show Author's Information Hide Author's Information C. LING^{^a}, W. B. TIAN^{^a}(

), P. ZHANG^{^a}, W. ZHENG^{^a}, Y. M. ZHANG^{^b}, Z. M. SUN^{^a}(

)

^a Jiangsu Key Laboratory of Advanced Metallic Materials, School of Materials Science and Engineering, Southeast University, Nanjing 211189, China

^b Jiangsu Key Laboratory of Construction Materials, School of Materials Science and Engineering, Southeast University, Nanjing 211189, China

Keywords:

MAX phase, thermal stability, Ti₂PbC, differential scanning calorimetry (DSC)

Cite this article:

LING C, TIAN WB, ZHANG P, et al. Synthesis and formation mechanism of titanium lead carbide. Journal of Advanced Ceramics, 2018, 7(2): 178-183. https://doi.org/10.1007/s40145-018-0269-1

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Abstract Full text About this article

Abstract

Ti₂PbC was synthesized for the first time by pressureless reaction synthesis using Ti/Pb/TiC as starting materials at a heating rate of 2 ℃/min and holding at 1370 ℃ for 2 h in a tube furnace protected by Ar atmosphere. The effects of starting powders, heating rates, and holding temperatures on the formation of Ti₂PbC were investigated. It was found that elementary mixture of Ti/Pb/C or higher heating rates fail to form Ti₂PbC. The decreased lattice parameters in the synthesized Ti₂PbC indicated the existence of Pb vacancies in the compound. A reaction mechanism was proposed to explain the formation of Ti₂PbC.

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About this article

Synthesis and formation mechanism of titanium lead carbide

Show Author's information Hide Author's Information C. LING^{^a}, W. B. TIAN^{^a}(

), P. ZHANG^{^a}, W. ZHENG^{^a}, Y. M. ZHANG^{^b}, Z. M. SUN^{^a}(

)

^a Jiangsu Key Laboratory of Advanced Metallic Materials, School of Materials Science and Engineering, Southeast University, Nanjing 211189, China

^b Jiangsu Key Laboratory of Construction Materials, School of Materials Science and Engineering, Southeast University, Nanjing 211189, China

Abstract

Keywords: MAX phase, thermal stability, Ti₂PbC, differential scanning calorimetry (DSC)

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Publication history

Received: 08 December 2017

Revised: 14 March 2018

Accepted: 16 March 2018

Published: 17 April 2018

Issue date: June 2018

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Open Access The articles published in this journal are distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution, and reproduction in any medium, provided you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made.