Upconversion 32Nb2O5-10La2O3-16ZrO2 glass activated with Er3+/Yb3+ and dye sensitized solar cell application

Xiaoyu LI; Jiaying LI; Jianqiang LI; Hong LIN; Bo LI

doi:10.1007/s40145-017-0243-3

Journal of Advanced Ceramics 2017, 6(4): 312-319 https://doi.org/10.1007/s40145-017-0243-3

Research Article |

Open Access | Issue | Published: 19 December 2017

Upconversion 32Nb₂O₅-10La₂O₃-16ZrO₂ glass activated with Er³⁺/Yb³⁺ and dye sensitized solar cell application

Show Author's Information Hide Author's Information Xiaoyu LI^{^†^,^a}, Jiaying LI^{^a^,^†^,^b}, Jianqiang LI^{^a^,^c}(

), Hong LIN^{^d}, Bo LI^{^b}

a National Engineering Laboratory for Hydrometallurgical Cleaner Production Technology, Key Laboratory of Green Process and Engineering, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China

b Advanced Materials Institute, Graduate School at Shenzhen, Tsinghua University, Shenzhen, Guangdong 518055, China

c University of Chinese Academy of Sciences, Beijing 100049, China

d State Key Laboratory of New Ceramics and Fine Processing, Department of Materials Science and Engineering, Tsinghua University, Beijing 100084, China

† These authors contributed equally to this work.

Keywords:

upconversion, aerodynamic levitation (ADL), niobium pentoxide, rare earth concentration, solar cell

Cite this article:

LI X, LI J, LI J, et al. Upconversion 32Nb₂O₅-10La₂O₃-16ZrO₂ glass activated with Er³⁺/Yb³⁺ and dye sensitized solar cell application. Journal of Advanced Ceramics, 2017, 6(4): 312-319. https://doi.org/10.1007/s40145-017-0243-3

Download citation

EndNote(RIS)

BibTeX

754

Views

Downloads

Citations

Crossref

N/A

WoS

Scopus

CSCD

Abstract Full text About this article

Abstract

Er³⁺/Yb³⁺ codoped niobium pentoxide glasses were fabricated by the aerodynamic levitation (ADL) method with rapid cooling rate. All samples with various doping concentrations showed good upconversion luminescence properties under 980 nm laser excitation. The structure, transmittance spectrum, and luminescence properties of the samples were systemically investigated by XRD, UV-Vis-NIR spectrophotometer, and upconversion spectra. All transparent samples exhibited green and red upconversion emissions centered at 532, 547, and 670 nm. Experimental results showed that the sample codoped with 1 mol% Er³⁺/Yb³⁺ has the strongest upconversion emissions, and the increase of the doped Yb³⁺ concentration results in the increased red emission and reduced green emission. The logI-logP plot of green emission indicated that the green emissions reach the saturation at high pump power excitation, deviating from the low-power regime. After one-photon energy transfer (ET) process, ⁴I_11/2+⁴I_11/2→⁴F_7/2+⁴I_15/2 process between the two neighboring Er³⁺ ions was responsible for the population of the ⁴S_3/2/⁴H_11/2 states. The niobium pentoxide codoped with Er³⁺/Yb³⁺ bulk glasses could be used in the dye sensitized solar cell (DSSC) to improve the efficiency.

Full text

Abstract

Full text

Outline

About this article

Upconversion 32Nb₂O₅-10La₂O₃-16ZrO₂ glass activated with Er³⁺/Yb³⁺ and dye sensitized solar cell application

Show Author's information Hide Author's Information Xiaoyu LI^{^†^,^a}, Jiaying LI^{^a^,^†^,^b}, Jianqiang LI^{^a^,^c}(

), Hong LIN^{^d}, Bo LI^{^b}

b Advanced Materials Institute, Graduate School at Shenzhen, Tsinghua University, Shenzhen, Guangdong 518055, China

c University of Chinese Academy of Sciences, Beijing 100049, China

d State Key Laboratory of New Ceramics and Fine Processing, Department of Materials Science and Engineering, Tsinghua University, Beijing 100084, China

† These authors contributed equally to this work.

Abstract

Keywords: upconversion, aerodynamic levitation (ADL), niobium pentoxide, rare earth concentration, solar cell

References(33)

[1]

H Rodríguez-Rodríguez, MH Imanieh, F Lahoz, et al. Analysis of the upconversion process in Tm³⁺ doped glasses for enhancement of the photocurrent in silicon solar cells. Sol Energ Mat Sol C 2016, 144: 29-32.

DOI Google Scholar

[2]

VK Tikhomirov, VD Rodriguez, J Mendez-Ramos, et al. Optimizing Er/Yb ratio and content in Er-Yb co-doped glass-ceramics for enhancement of the up- and down-conversion luminescence. Sol Energ Mat Sol C 2012, 100: 209-215.

DOI Google Scholar

[3]

SK Maji, S Sreejith, J Joseph, et al. Upconversion nanoparticles as a contrast agent for photoacoustic imaging in live mice. Adv Mater 2014, 26: 5633-5638.

DOI Google Scholar

[4]

A Sarakovskis, G Krieke. Upconversion luminescence in erbium doped transparent oxyfluoride glass ceramics containing hexagonal NaYF₄ nanocrystals. J Eur Ceram Soc 2015, 35: 3665-3671.

DOI Google Scholar

[5]

D Chen, Z Wan, Y Zhou, et al. Tailoring Er³⁺ spectrally pure upconversion in bulk nano-glass-ceramics via lanthanide doping. J Eur Ceram Soc 2016, 36: 679-688.

DOI Google Scholar

[6]

R Dey, A Pandey, VK Rai. The Er³⁺-Yb³⁺ codoped La₂O₃ phosphor in finger print detection and optical heating. Spectrochim Acta A 2014, 128: 508-513.

DOI Google Scholar

[7]

SK Singh, K Kumar, SB Rai. Multifunctional Er³⁺-Yb³⁺ codoped Gd₂O₃ nanocrystalline phosphor synthesized through optimized combustion route. Appl Phys B 2009, 94: 165-173.

DOI Google Scholar

[8]

M Nyk, R Kumar, TY Ohulchanskyy, et al. High contrast in vitro and in vivo photoluminescence bioimaging using near infrared to near infrared up-conversion in Tm³⁺ and Yb³⁺ doped fluoride nanophosphors. Nano Lett 2008, 8: 3834-3838.

DOI Google Scholar

[9]

L Wang, R Yan, Z Huo, et al. Fluorescence resonant energy transfer biosensor based on upconversion-luminescent nanoparticles. Angew Chem Int Edit 2005, 44: 6054-6057.

DOI Google Scholar

[10]

E Zych, J Trojan-Piegza, L Kępiński. Homogeneously precipitated Lu₂O₃:Eu nanocrystalline phosphor for X-ray detection. Sensor Actuat B: Chem 2005, 109: 112-118.

DOI Google Scholar

[11]

VK Rai, A Pandey, R Dey. Photoluminescence study of Y₂O₃:Er³⁺-Eu³⁺-Yb³⁺ phosphor for lighting and sensing applications. J Appl Phys 2013, 113: 083104.

DOI Google Scholar

[12]

KVR Murthy. Up-conversion phosphors synthesis and application in solar converters. Int J Lumin Appl 2013, 3: 1-5.

Google Scholar

[13]

JD Furman, AY Warner, SJ Teat, et al. Tunable ligand-based emission from inorganic-organic frameworks: A new approach to phosphors for solid state lighting and other applications. Chem Mater 2010, 22: 2255-2260.

DOI Google Scholar

[14]

Z Chen, S He, H-J Butt, et al. Photon upconversion lithography: Patterning of biomaterials using near-infrared light. Adv Mater 2015, 27: 2203-2206.

DOI Google Scholar

[15]

R Qiao, C Liu, M Liu, et al. Ultrasensitive in vivo detection of primary gastric tumor and lymphatic metastasis using upconversion nanoparticles. ACS Nano 2015, 9: 2120-2129.

DOI Google Scholar

[16]

C Yuan, G Chen, L Li, et al. Simultaneous multiple wavelength upconversion in a core-shell nanoparticle for enhanced near infrared light harvesting in a dye-sensitized solar cell. ACS Appl Mater Interfaces 2014, 6: 18018-18025.

DOI Google Scholar

[17]

S Ivanova, F Pellé. Strong 1.53 μm to NIR-VIS-UV upconversion in Er-doped fluoride glass for high-efficiency solar cells. J Opt Soc Am B 2009, 26: 1930-1938.

DOI Google Scholar

[18]

M Liu, Y Lu, ZB Xie, et al. Enhancing near-infrared solar cell response using upconverting transparent ceramics. Sol Energ Mat Sol C 2011, 95: 800-803.

DOI Google Scholar

[19]

F Lahoz, C Pérez-Rodríguez, SE Hernández, et al. Upconversion mechanisms in rare-earth doped glasses to improve the efficiency of silicon solar cells. Sol Energ Mat Sol C 2011, 95: 1671-1677.

DOI Google Scholar

[20]

X Ma, Z Peng, J Li. Effect of Ta₂O₅ Substituting on thermal and optical properties of high refractive index La₂O₃-Nb₂O₅ glass system prepared by aerodynamic levitation method. J Am Ceram Soc 2015, 98: 770-773.

DOI Google Scholar

[21]

J Li, J Li, B Li, et al. An upconversion niobium pentoxide bulk glass codoped with Er³⁺/Yb³⁺ fabricated by aerodynamic levitation method. J Am Ceram Soc 2015, 98: 1865-1869.

DOI Google Scholar

[22]

K Yoshimoto, A Masuno, H Inoue, et al. Transparent and high refractive index La₂O₃-WO₃ glass prepared using containerless processing. J Am Ceram Soc 2012, 95: 3501-3504.

DOI Google Scholar

[23]

V Pukhkaya, P Goldner, A Ferrier, et al. Impact of rare earth element clusters on the excited state lifetime evolution under irradiation in oxide glasses. Opt Express 2015, 23: 3270-3281.

DOI Google Scholar

[24]

J Li, G Ba, P Hu, et al. Amorphous titanate nanospheres fabricated using contactless phase change process. J Mater Chem 2012, 22: 9450-9454.

DOI Google Scholar

[25]

H Xiang, L Guan, Z Peng, et al. Preparation of high refractive index La₂O₃-TiO₂ glass by aerodynamic levitation technique and effects of Bi₂O₃ substitution on its thermal and optical properties. Ceram Int 2014, 40: 4985-4988.

DOI Google Scholar

[26]

K Nagashio, H Takamura, K Kuribayashi. Containerless solidification of peritectic and eutectic ceramics using aero-acoustic levitator. Mater Sci Forum 2000, 329-330: 173-178

DOI Google Scholar

[27]

Y Liu, H Lin, TD Joanne, et al. Kinetics versus energetics in dye-sensitized solar cells based on an ethynyl-linked porphyrin heterodimer. J Phys Chem C 2014, 118: 1426-1435.

DOI Google Scholar

[28]

J Zhao. Foundation of Material Science. Dalian, China: DUT Press, 2010: 45.

DOI

[29]

L Shi, Q Shen, Z Qiu. Concentration-dependent upconversion emission in Er-doped and Er/Yb-codoped LiTaO₃ polycrystals. J Lumin 2014, 148: 94-97.

DOI Google Scholar

[30]

X Pan, J Yu, Y Liu, et al. Thermal, mechanical, and upconversion properties of Er³⁺/Yb³⁺ co-doped titanate glass prepared by levitation method. J Alloys Compd 2011, 509: 7504-7507.

DOI Google Scholar

[31]

D Li, B Dong, X Bai, et al. Influence of the TGA modification on upconversion luminescence of hexagonal-phase NaYF₄:Yb³⁺,Er³⁺ nanoparticles. J Phys Chem C 2010, 114: 8219-8226.

DOI Google Scholar

[32]

DH Choi, DH Kang, SS Yi, et al. Up-conversion luminescent properties of La(_0.80-x)VO₄:Yb_x,Er_0.20 phosphors. Mater Res Bull 2015, 71: 16-20.

DOI Google Scholar

[33]

M Marín-Dobrincic, JA Sanz-García, E Cantelar, et al. LiNbO₃:Yb³⁺/Er³⁺/Tm³⁺—power driven green to blue tenability. Mater Lett 2013, 96: 63-66.

DOI Google Scholar

About this article

Publication history

Acknowledgements

Rights and permissions

Publication history

Received: 10 April 2017

Revised: 08 August 2017

Accepted: 22 August 2017

Published: 19 December 2017

Issue date: December 2017

Copyright

Acknowledgements

This work was financially supported by the National Natural Science Foundation of China (Grant Nos. 51671181, 51674232, and 51471158), Beijing Natural Science Foundation (No. 2152032), the Science and Technology Plan of Shenzhen City (Grant No. JCYJ20150827165038323), State Key Laboratory of New Ceramic and Fine Processing Tsinghua University (No. KF201417), the Open Funding Project of Key Laboratory of Photochemical Conversion and Optoelectronic Materials (TIPC in CAS), and the Instrument Developing Project of the Chinese Academy of Sciences (Grant No. YZ201520).

Rights and permissions

Open Access The articles published in this journal are distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons. org/licenses/by/4.0/), which permits unrestricted use, distribution, and reproduction in any medium, provided you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made.