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The specific dynamic magnetic response and magnetic relaxation phenomena in magnetite-based glass-ceramics by controlled crystallization of Fe-rich borosilicate glasses with 25 wt% Fe2O3, in the presence of two types of nucleating agents, Cr2O3 and P2O5, were investigated. The magnetic response is complex and shows contributions arising from two subsystems: a system with collective characteristics, superspin-glass like, and another one with single particle characteristics (superparamagnetic) with dipolar interaction. The nucleating agents have strong influence on the characteristic temperatures and anisotropy energy.


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Magnetic properties of glass-ceramics obtained by crystallization of iron-rich borosilicate glasses

Show Author's information V. SANDUa( )E. CIMPOIASUbA. KUNCSERa,cM. S. NICOLESCUa
National Institute of Materials Physics, Bucharest Magurele, 077125, Romania
Department of Physics, US Naval Academy, Annapolis, MD, USA
Faculty of Physics, Bucharest University, Bucharest-Magurele, 077125, Romania

Abstract

The specific dynamic magnetic response and magnetic relaxation phenomena in magnetite-based glass-ceramics by controlled crystallization of Fe-rich borosilicate glasses with 25 wt% Fe2O3, in the presence of two types of nucleating agents, Cr2O3 and P2O5, were investigated. The magnetic response is complex and shows contributions arising from two subsystems: a system with collective characteristics, superspin-glass like, and another one with single particle characteristics (superparamagnetic) with dipolar interaction. The nucleating agents have strong influence on the characteristic temperatures and anisotropy energy.

Keywords:

magnetite, glass-ceramics, AC susceptibility, magnetic relaxation, nucleating agent
Received: 01 February 2017 Revised: 25 April 2017 Accepted: 07 June 2017 Published: 29 September 2017 Issue date: September 2017
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Publication history
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Acknowledgements
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Publication history

Received: 01 February 2017
Revised: 25 April 2017
Accepted: 07 June 2017
Published: 29 September 2017
Issue date: September 2017

Copyright

© The author(s) 2017

Acknowledgements

This work was supported by a grant of the Romanian National Authority for Scientific Research and Innovation, CNCS/CCCDI-UEFISCDI, project number PN-III-P2- 2.1-PED-2016-1741 (contract 163PED⁄2017), ROMBRICKS, Core Program PN 10/2016 at NIMP and by the Office of Naval Research at USNA.

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