Magnetic properties of glass-ceramics obtained by crystallization of iron-rich borosilicate glasses

V. SANDU; E. CIMPOIASU; A. KUNCSER; M. S. NICOLESCU

doi:10.1007/s40145-017-0236-2

Journal of Advanced Ceramics 2017, 6(3): 251-261 https://doi.org/10.1007/s40145-017-0236-2

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Open Access | Issue | Published: 29 September 2017

Magnetic properties of glass-ceramics obtained by crystallization of iron-rich borosilicate glasses

Show Author's Information Hide Author's Information V. SANDU^{^a}(

), E. CIMPOIASU^{^b}, A. KUNCSER^{^a^,^c}, M. S. NICOLESCU^{^a}

a National Institute of Materials Physics, Bucharest Magurele, 077125, Romania

b Department of Physics, US Naval Academy, Annapolis, MD, USA

c Faculty of Physics, Bucharest University, Bucharest-Magurele, 077125, Romania

Keywords:

glass-ceramics, magnetite, AC susceptibility, magnetic relaxation, nucleating agent

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SANDU V, CIMPOIASU E, KUNCSER A, et al. Magnetic properties of glass-ceramics obtained by crystallization of iron-rich borosilicate glasses. Journal of Advanced Ceramics, 2017, 6(3): 251-261. https://doi.org/10.1007/s40145-017-0236-2

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Abstract

The specific dynamic magnetic response and magnetic relaxation phenomena in magnetite-based glass-ceramics by controlled crystallization of Fe-rich borosilicate glasses with 25 wt% Fe₂O₃, in the presence of two types of nucleating agents, Cr₂O₃ and P₂O₅, were investigated. The magnetic response is complex and shows contributions arising from two subsystems: a system with collective characteristics, superspin-glass like, and another one with single particle characteristics (superparamagnetic) with dipolar interaction. The nucleating agents have strong influence on the characteristic temperatures and anisotropy energy.

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Magnetic properties of glass-ceramics obtained by crystallization of iron-rich borosilicate glasses

Show Author's information Hide Author's Information V. SANDU^{^a}(

), E. CIMPOIASU^{^b}, A. KUNCSER^{^a^,^c}, M. S. NICOLESCU^{^a}

a National Institute of Materials Physics, Bucharest Magurele, 077125, Romania

b Department of Physics, US Naval Academy, Annapolis, MD, USA

c Faculty of Physics, Bucharest University, Bucharest-Magurele, 077125, Romania

Abstract

Keywords: glass-ceramics, magnetite, AC susceptibility, magnetic relaxation, nucleating agent

References(60)

[1]

N Kreidl. Phase separation in glasses. J Non-Cryst Solids 1991, 129: 1-11.

DOI Google Scholar

[2]

D Manara, A Grandjean, DR Neuville. Structure of borosilicate glasses and melts: A revision of the Yun, Bray and Dell model. J Non-Cryst Solids 2009, 355: 2528-2531.

DOI Google Scholar

[3]

P Auric, N Van Dang, AK Bandyopadhyay, et al. Superparamagnetism and ferrimagnetism of the small particles of magnetite in a silicate matrix. J Non-Cryst Solids 1982, 50: 97-106.

DOI Google Scholar

[4]

A Hoell, R Kranold, U Lembke, et al. Structural investigation of ferrimagnetic particles formed by glass crystallization. Berichte der Bunsengesellschaft für physikalische Chemie 1996, 100: 1646-1650.

DOI Google Scholar

[5]

A Bretcanu, S Spriano, E Verné, et al. The influence of crystallised Fe₃O₄ on the magnetic properties of coprecipitation-derived ferrimagnetic glass-ceramics. Acta Biomater 2005, 1: 421-429.

DOI Google Scholar

[6]

S Woltz, R Hiergeist, P Görnert, et al. Magnetite nanoparticles prepared by the glass crystallization method and their physical properties. J Magn Magn Mater 2006, 298: 7-13.

DOI Google Scholar

[7]

SAM Abdel-Hameed, MM Hessien, MA Azooz. Preparation and characterization of some ferromagnetic glass-ceramics contains high quantity of magnetite. Ceram Int 2009, 35: 1539-1544.

DOI Google Scholar

[8]

R Harizanova, G Völksch, C Rüssel. Crystallization and microstructure of glasses in the system Na₂O/MnO/ SiO₂/Fe₂O₃. Mater Res Bull 2011, 46: 81-86.

DOI Google Scholar

[9]

Z Amirahmadi, VK Marghussian, A Beitollahi, et al. Magnetite nanoparticles prepared by the crystallization of Na₂O-Fe₂O₃-B₂O₃-SiO₂ glasses. J Non-Cryst Solids 2011, 357: 3195-3199.

DOI Google Scholar

[10]

V Sandu, MS Nicolescu, V Kuncser, et al. Magnetic glass-ceramics. J Adv Ceram 2012, 1: 138-143.

DOI Google Scholar

[11]

C Worsch, M Büttner, P Schaaf, et al. Magnetic properties of multicore magnetite nanoparticles prepared by glass crystallization. J Mater Sci 2013, 48: 2299-2307.

DOI Google Scholar

[12]

M Georgieva, D Tzankov, R Harizanova, et al. Magnetic properties of magnetite nanoparticles crystallized in sodium-aluminoborosilicate glass matrix. Appl Phys A 2016, 122: 160.

DOI Google Scholar

[13]

K Oda, T Yoshio, KO Oka, et al. Morphology and magnetic properties of BaFe₁₂O₁₉ particles prepared by the glass-ceramic method. J Mater Sci Lett 1985, 4: 876-879.

DOI Google Scholar

[14]

C-K Lee, RF Speyer. Glass formation and crystallization of barium ferrite in the Na₂O-BaO-Fe₂O₃-SiO₂ system. J Mater Sci 1994, 29: 1348-1351.

DOI Google Scholar

[15]

T Klupsch, E Steinbeiss, R Müller, et al. Magnetic glass ceramics—preparation and properties. J Magn Magn Mater 1999, 196-197: 264-265.

DOI Google Scholar

[16]

R Müller, C Ulbrich, W Shüppel, et al. Preparation and properties of barium-ferrite-containing glass ceramics. J Eur Ceram Soc 1999, 19: 1547-1550.

DOI Google Scholar

[17]

S-B Sohn, S-Y Choi, I-B Shim. Preparation of Ba-ferrite containing glass-ceramics in BaO-Fe₂O₃-SiO₂. J Magn Magn Mater 2002, 239: 533-536.

DOI Google Scholar

[18]

VK Marghussian, A Beitollahi, M Haghi. The effect of SiO₂ and Cr₂O₃ additions on the crystallization behaviour and magnetic properties of a B₂O₃-BaO-Fe₂O₃ glass. Ceram Int 2003, 29: 455-462.

DOI Google Scholar

[19]

M Mirkazemi, VK Marghussian, A Beitollahi. Crystallisation behaviour, microstructure and magnetic properties of BaO-Fe₂O₃-B₂O₃-SiO₂ glass ceramics Ceram Int 2006, 32: 43-51.

DOI Google Scholar

[20]

M Mirkazemi, VK Marghussian, A Beitollahi, et al. Effect of ZrO₂ nucleant on crystallisation behaviour, microstructure and magnetic properties of BaO-Fe₂O₃- B₂O₃-SiO₂ glass ceramics. Ceram Int 2007, 33: 463-469.

DOI Google Scholar

[21]

PE Kazin, LA Trusov, DD Zaitsev, et al. Glass crystallization synthesis of ultrafine hexagonal M-type ferrites: Particle morphology and magnetic characteristics. Russ J Inorg Chem 2009, 54: 2081-2090.

DOI Google Scholar

[22]

K Oda, T Yoshio, KO Oka, et al. Magnetic properties of SrFe₁₂O₁₉ particles prepared by the glass-ceramic method. J Mater Sci Lett 1984, 3: 1007-1010.

DOI Google Scholar

[23]

DD Zaitsev, PE Kazin, PE Garshev, et al. Synthesis and magnetic properties of SrO-Fe₂O₃-B₂O₃ glass-ceramics. Inorg Mater 2004, 40: 881-885.

DOI Google Scholar

[24]

DD Zaitsev, PE Kazin, EA Gravchikova, et al. Synthesis of magnetic glass ceramics containing fine SrFe₁₂O₁₉ particles. Mendeleev Commun 2004, 14: 171-173.

DOI Google Scholar

[25]

DD Zaitsev, SE Kushnir, PE Kazin, et al. Preparation of the SrFe₁₂O₁₉-based magnetic composites via boron oxide glass devitrification. J Magn Magn Mater 2006, 301: 489-494.

DOI Google Scholar

[26]

SE Shabrawy, C Bocker, M Miglierini, et al. Mössbauer study and magnetic properties of MgFe₂O₄ crystallized from the glass system B₂O₃/K₂O/P₂O₅/MgO/Fe₂O₃. J Magn Magn Mater 2017, 421: 306-315.

DOI Google Scholar

[27]

V Sandu, MS Nicolescu, V Kuncser, et al. Structure and magnetic properties of nanosized magnetite obtained by glass recrystallization. J Nanosci Nanotechnol 2012, 12: 5043-5050.

DOI Google Scholar

[28]

X Batlle, A Labarta. Finite-size effects in fine particles: Magnetic and transport properties. J Phys D: Appl Phys 2002, 35: R15-R42.

DOI Google Scholar

[29]

T Jonsson, J Mattsson, C Djurberg, et al. Aging in a magnetic particle system. Phys Rev Lett 1995, 75: 4138.

DOI Google Scholar

[30]

MG Rasteiro, T Gassman, R Santos, et al. Crystalline phase characterization of glass-ceramic glazes. Ceram Int 2007, 33: 345-354.

DOI Google Scholar

[31]

S Scholes, FCF Wilkinso. Glassy phase separation in sodium borosilicate glasses. Discuss Faraday Soc 1970, 50: 175-181.

DOI Google Scholar

[32]

VE Eremyashev, LA Shabunina, AB Mironov. Structural particulars of iron-containing borosilicate glasses. Glass Ceram 2014, 70: 391-394.

DOI Google Scholar

[33]

Z Kąkol, D Owoc, J Przewoźnik, et al. The effect of doping on global lattice properties of magnetite Fe₃_-xMe_xO₄ (Me = Zn, Ti and Al). J Solid State Chem 2012, 192: 120-126.

DOI Google Scholar

[34]

JA Tangeman, RA Lange. The effect of Al³⁺, Fe³⁺, and Ti⁴⁺ on the configurational heat capacities of sodium silicate liquids. Phys Chem Minerals 1998, 26: 83-99.

DOI Google Scholar

[35]

B Cochain, DR Neuville, D de Ligny, et al. Dynamics of iron-bearing borosilicate melts: Effects of melt structure and composition on viscosity, electrical conductivity and kinetics of redox reactions. J Non-Cryst Solids 2013, 373-374: 18-27.

DOI Google Scholar

[36]

U Lembke, A Hoell, R Kranold, et al. Formation of magnetic nanocrystals in a glass ceramic studied by small-angle scattering. J Appl Phys 1999, 85: 2279.

DOI Google Scholar

[37]

J Blasco, J García, G Subías. Structural transformation in magnetite below the Verwey transition. Phys Rev B 2011, 83: 104105.

DOI Google Scholar

[38]

S Bedanta, W Kleemann. Supermagnetism. J Phys D: Appl Phys 2009, 42: 013001.

DOI Google Scholar

[39]

L Lundgren, P Svedlindh, O Beckman. Measurement of complex susceptibility on a metallic spin glass with broad relaxation spectrum. J Magn Magn Mater 1981, 25: 33-38.

DOI Google Scholar

[40]

J-O Andersson, C Djurberg, T Jonsson, et al. Monte Carlo studies of the dynamics of an interacting monodispersive magnetic-particle system. Phys Rev B 1997, 56: 13983.

DOI Google Scholar

[41]

JC Denardin, AL Brandl, M Knobel, et al. Thermoremanence and zero-field-cooled/field-cooled magnetization study of Co_x(SiO₂)₁_-x granular films. Phys Rev B 2002, 65: 064422.

DOI Google Scholar

[42]

FC Fonseca, GF Goya, RF Jardim, et al. Superparamagnetism and magnetic properties of Ni nanoparticles embedded in SiO₂. Phys Rev B 2002, 66: 104406.

DOI Google Scholar

[43]

K Nadeem, H Krenn, T Traussing, et al. Distinguishing magnetic blocking and surface spin-glass freezing in nickel ferrite. J Appl Phys 2011, 109: 013912.

DOI Google Scholar

[44]

V Sandu, S Greculeasa, A Kuncser, et al. Effect of P₂O₅ on the structural and magnetic properties of magnetite-based glass-ceramics. J Am Ceram Soc 2016, 99: 4013-4021.

DOI Google Scholar

[45]

V Sandu, S Greculeasa, A Kuncser, et al. Effect of Cr₂O₃ on the magnetic properties of magnetite-based glass-ceramics obtained by controlled crystallization of Fe-containing aluminoborosilicate glass. J Eur Ceram Soc 2017, 37: 3089-3099.

DOI Google Scholar

[46]

YL Raikher, VI Stepanov. Linear and cubic dynamic susceptibilities of superparamagnetic fine particles Phys Rev B 1997, 55: 15005.

DOI Google Scholar

[47]

JL Tholence.On the frequency dependence of the transition temperature in spin glasses. Solid State Commun 1993, 88: 917-921.

DOI Google Scholar

[48]

N Bontemps, J Rajchenbach, RV Chamberlin, et al. Dynamic scaling in the Eu_0.4Sr_0.6S spin-glass. Phys Rev B 1984, 30: 6514-6520.

DOI Google Scholar

[49]

J Souletie, JL Tholence. Critical slowing down in spin glasses and other glasses: Fulcher versus power law. Phys Rev B 1985, 32: 516-519.

DOI Google Scholar

[50]

K Nadeem, H Krenn, T Traussnig, et al. Spin-glass freezing of maghemite nanoparticles prepared by microwave plasma synthesis. J Appl Phys 2012, 111: 113911.

DOI Google Scholar

[51]

JL Dormann, L Bessais, D Fiorani. A dynamic study of small interacting particles: Superparamagnetic model and spin-glass laws. J Phys C: Solid State Phys 1988, 21: 2015-2034.

DOI Google Scholar

[52]

J-L Tholence. Recent experiments about the spin-glass transition. Physica B+C 1984, 126: 157-164.

DOI Google Scholar

[53]

P Cizeau, JP Bouchaud. Mean field theory of dilute spin-glasses with power-law interactions. J Phys A: Math Gen 1993, 26: L187-L193.

DOI Google Scholar

[54]

X Chen, S Bedanta, O Petracic, et al. Superparamagnetism versus superspin glass behavior in dilute magnetic nanoparticle systems. Phys Rev B 2005, 72: 214436.

DOI Google Scholar

[55]

D Parker, V Dupuis, F Ladieu, et al. Spin-glass behavior in an interacting γ-Fe₂O₃ nanoparticle system. Phys Rev B 2008, 77: 104428.

DOI Google Scholar

[56]

T Jonsson, P Nordblad, P Svedlindh. Dynamic study of dipole-dipole interaction effects in a magnetic nanoparticle system. Phys Rev B 1998, 57: 497-504.

DOI Google Scholar

[57]

M Sasaki, PE Jönsson, H Takayama, et al. Aging and memory effects in superparamagnets and superspin glasses. Phys Rev B 2005, 71: 104405.

DOI Google Scholar

[58]

S Disch, E Wetterskog, RP Hermann, et al. Quantitative spatial magnetization distribution in iron oxide nanocubes and nanospheres by polarized small-angle neutron scattering. New J Phys 2012, 14: 013025.

DOI Google Scholar

[59]

RH Kodama, AE Berkowitz. Atomic-scale magnetic modeling of oxide nanoparticles. Phys Rev B 1999, 59: 6321.

DOI Google Scholar

[60]

D Fiorani. Surface Effects in Magnetic Nanoparticles. New York: Springer, 2005.

DOI

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Acknowledgements

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Publication history

Received: 01 February 2017

Revised: 25 April 2017

Accepted: 07 June 2017

Published: 29 September 2017

Issue date: September 2017

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Acknowledgements

This work was supported by a grant of the Romanian National Authority for Scientific Research and Innovation, CNCS/CCCDI-UEFISCDI, project number PN-III-P2- 2.1-PED-2016-1741 (contract 163PED⁄2017), ROMBRICKS, Core Program PN 10/2016 at NIMP and by the Office of Naval Research at USNA.

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