Synthesis of ferromagnetic La1-xSrxMnO3 nanoparticles by precipitation from diethylene glycol solution and their properties

Yulia SHLAPA; Sergii SOLOPAN; Oleksandr YELENICH; Volodymyr TRACHEVSKII; Anatolii BELOUS

doi:10.1007/s40145-016-0190-4

Journal of Advanced Ceramics 2016, 5(3): 197-203 https://doi.org/10.1007/s40145-016-0190-4

Research Article |

Open Access | Issue | Published: 29 June 2016

Synthesis of ferromagnetic La₁_-xSr_xMnO₃ nanoparticles by precipitation from diethylene glycol solution and their properties

Show Author's Information Hide Author's Information Yulia SHLAPA^{^a}(

), Sergii SOLOPAN^{^a}, Oleksandr YELENICH^{^a}, Volodymyr TRACHEVSKII^{^b}, Anatolii BELOUS^{^a}

^a V.I. Vernadsky Institute of General and Inorganic Chemistry, NAS of Ukraine, 32/34 Palladina Avenue, 03680, Kyiv 142, Ukraine

^b Technical Center NAS of Ukraine

Keywords:

manganite, perovskite, precipitation, complexation reaction, diethylene glycol, nuclear magnetic resonance (NMR)

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SHLAPA Y, SOLOPAN S, YELENICH O, et al. Synthesis of ferromagnetic La₁_-xSr_xMnO₃ nanoparticles by precipitation from diethylene glycol solution and their properties. Journal of Advanced Ceramics, 2016, 5(3): 197-203. https://doi.org/10.1007/s40145-016-0190-4

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Abstract

La₁_-xSr_xMnO₃ nanoparticles were synthesized by precipitation from diethylene glycol solution. Features of synthesis were studied using ¹Н, ¹³С, ¹³⁹La nuclear magnetic resonance (NMR) investigations. The obtained results showed that the complexation reaction between diethylene glycol and metal cations takes place during the synthesis. These complexes decomposed at 200 ℃ and an amorphous precursor (La,Sr)MnO₃ was formed. According to X-ray results, the crystallization of the perovskite structure began at 600 ℃ and finished at 800 ℃. Microstructural studies showed that obtained nanoparticles are weakly agglomerated and have small sizes. Based on these nanoparticles, magnetic fluid was prepared which was effectively heated under an alternating magnetic field.

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Synthesis of ferromagnetic La₁_-xSr_xMnO₃ nanoparticles by precipitation from diethylene glycol solution and their properties

Show Author's information Hide Author's Information Yulia SHLAPA^{^a}(

), Sergii SOLOPAN^{^a}, Oleksandr YELENICH^{^a}, Volodymyr TRACHEVSKII^{^b}, Anatolii BELOUS^{^a}

^a V.I. Vernadsky Institute of General and Inorganic Chemistry, NAS of Ukraine, 32/34 Palladina Avenue, 03680, Kyiv 142, Ukraine

^b Technical Center NAS of Ukraine

Abstract

Keywords: manganite, perovskite, precipitation, complexation reaction, diethylene glycol, nuclear magnetic resonance (NMR)

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Publication history

Received: 30 November 2015

Revised: 12 April 2016

Accepted: 25 April 2016

Published: 29 June 2016

Issue date: September 2016

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Open Access The articles published in this journal are distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons. org/licenses/by/4.0/), which permits unrestricted use, distribution, and reproduction in any medium, provided you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made.