Preparation of porous Si3N4 ceramics via tailoring solid loading of Si3N4 slurry and Si3N4 poly-hollow microsphere content

Jia-Min WU; Xiao-Yan ZHANG; Jie XU; Ke GAN; Jia-Lu LI; Chen-Hui LI; Jin-Long YANG; Yu-Sheng SHI

doi:10.1007/s40145-015-0158-9

Journal of Advanced Ceramics 2015, 4(4): 260-266 https://doi.org/10.1007/s40145-015-0158-9

Research Article |

Open Access | Issue | Published: 21 September 2015

Preparation of porous Si₃N₄ ceramics via tailoring solid loading of Si₃N₄ slurry and Si₃N₄ poly-hollow microsphere content

Show Author's Information Hide Author's Information Jia-Min WU^{^a^,^b}, Xiao-Yan ZHANG^{^b}, Jie XU^{^b}, Ke GAN^{^b}, Jia-Lu LI^{^b}, Chen-Hui LI^{^a}(

), Jin-Long YANG^{^b}(

), Yu-Sheng SHI^{^a}

a State Key Laboratory of Materials Processing and Die & Mould Technology, School of Materials Science and Engineering, Huazhong University of Science and Technology, Wuhan 430074, China

b State Key Laboratory of New Ceramic and Fine Processing, School of Materials Science and Engineering, Tsinghua University, Beijing 100084, China

Keywords:

mechanical properties, porous Si₃N₄ ceramics, Si₃N₄ poly-hollow microspheres (PHMs), solid loading, aqueous gelcasting

Cite this article:

WU J-M, ZHANG X-Y, XU J, et al. Preparation of porous Si₃N₄ ceramics via tailoring solid loading of Si₃N₄ slurry and Si₃N₄ poly-hollow microsphere content. Journal of Advanced Ceramics, 2015, 4(4): 260-266. https://doi.org/10.1007/s40145-015-0158-9

Download citation

EndNote(RIS)

BibTeX

704

Views

Downloads

Citations

Crossref

N/A

WoS

Scopus

CSCD

Abstract Full text About this article

Abstract

Porous Si₃N₄ ceramics were prepared by aqueous gelcasting using Si₃N₄ poly-hollow microspheres (PHMs) as pore-forming agent. The effects of solid loading of Si₃N₄ slurry and Si₃N₄ PHM content on the properties of porous Si₃N₄ ceramics were investigated. Only β-Si₃N₄ phase is observed in porous Si₃N₄ ceramics, and Si₃N₄ PHMs distribute uniformly both in Si₃N₄ green samples and porous Si₃N₄ ceramics. Results show that solid loading of Si₃N₄ slurry and Si₃N₄ PHM content could considerably influence the properties of porous Si₃N₄ ceramics. With the increase of solid loading of Si₃N₄ slurry (decrease of Si₃N₄ PHM content), the distributing state of Si₃N₄ PHMs changes from contacting with each other to just embedding in the matrix, thus their porosity decreases, while their shrinkage, flexural strength, and fracture toughness increase.

Full text

Abstract

Full text

Outline

About this article

Preparation of porous Si₃N₄ ceramics via tailoring solid loading of Si₃N₄ slurry and Si₃N₄ poly-hollow microsphere content

Show Author's information Hide Author's Information Jia-Min WU^{^a^,^b}, Xiao-Yan ZHANG^{^b}, Jie XU^{^b}, Ke GAN^{^b}, Jia-Lu LI^{^b}, Chen-Hui LI^{^a}(

), Jin-Long YANG^{^b}(

), Yu-Sheng SHI^{^a}

a State Key Laboratory of Materials Processing and Die & Mould Technology, School of Materials Science and Engineering, Huazhong University of Science and Technology, Wuhan 430074, China

b State Key Laboratory of New Ceramic and Fine Processing, School of Materials Science and Engineering, Tsinghua University, Beijing 100084, China

Abstract

Keywords: mechanical properties, porous Si₃N₄ ceramics, Si₃N₄ poly-hollow microspheres (PHMs), solid loading, aqueous gelcasting

References(22)

[1]

Kalemtas A, Topates G, Özcoban H, et al. Mechanical characterization of highly porous β-Si₃N₄ ceramics fabricated via partial sintering & starch addition. J Eur Ceram Soc 2013, 33: 1507-1515.

DOI Google Scholar

[2]

Díaz A, Hampshire S. Characterisation of porous silicon nitride materials produced with starch. J Eur Ceram Soc 2004, 24: 413-419.

DOI Google Scholar

[3]

Xia Y, Zeng Y-P, Jiang D. Microstructure and mechanical properties of porous Si₃N₄ ceramics prepared by freeze-casting. Mater Design 2012, 33: 98-103.

DOI Google Scholar

[4]

Fan L, Zhou M, Wang H, et al. Low-temperature preparation of β-Si₃N₄ porous ceramics with a small amount of Li₂O–Y₂O₃. J Am Ceram Soc 2014, 97: 1371-1374.

DOI Google Scholar

[5]

Li X, Wu P, Zhu D. Effect of foaming pressure on the properties of porous Si₃N₄ ceramic fabricated by a technique combining foaming and pressureless sintering. Scripta Mater 2013, 68: 877-880.

DOI Google Scholar

[6]

Li X, Zhang L, Yin X. Microstructure and mechanical properties of three porous Si₃N₄ ceramics fabricated by different techniques. Mat Sci Eng A 2012, 549: 43-49.

DOI Google Scholar

[7]

Yu J, Yang J, Li S, et al. Preparation of Si₃N₄ foam ceramics with nest-like cell structure by particle-stabilized foams. J Am Ceram Soc 2012, 95: 1229-1233.

DOI Google Scholar

[8]

Yue J, Dong B, Wang H. Porous Si₃N₄ fabricated by phase separation method using benzoic acid as pore-forming agent. J Am Ceram Soc 2011, 94: 1989-1991.

DOI Google Scholar

[9]

Chen F, Shen Q, Yan F, et al. Pressureless sintering of α-Si₃N₄ porous ceramics using a H₃PO₄ pore-forming agent. J Am Ceram Soc 2007, 90: 2379-2383.

DOI Google Scholar

[10]

Inagaki Y, Shigegaki Y, Ando M, et al. Synthesis and evaluation of anisotropic porous silicon nitride. J Eur Ceram Soc 2004, 24: 197-200.

DOI Google Scholar

[11]

Yu J, Yang J, Li H, et al. Study on particle-stabilized Si₃N₄ ceramic foams. Mater Lett 2011, 65: 1801-1804.

DOI Google Scholar

[12]

Chen D, Zhang B, Zhuang H, et al. Combustion synthesis of network silicon nitride porous ceramics. Ceram Int 2003, 29: 363-364.

DOI Google Scholar

[13]

Shan S-Y, Yang J-F, Lu Y, et al. Effects of carbon source on microstructural evolution and sintering behavior of porous silicon nitride ceramics. Scripta Mater 2007, 56: 193-196.

DOI Google Scholar

[14]

Zou C, Zhang C, Li B, et al. Microstructure and properties of porous silicon nitride ceramics prepared by gel-casting and gas pressure sintering. Mater Design 2013, 44: 114-118.

DOI Google Scholar

[15]

Fukasawa T, Deng Z-Y, Ando M, et al. Synthesis of porous silicon nitride with unidirectionally aligned channels using freeze-drying process. J Am Ceram Soc 2002, 85: 2151-2155.

DOI Google Scholar

[16]

Li S, Wang C-A, Zhou J. Effect of starch addition on microstructure and properties of highly porous alumina ceramics. Ceram Int 2013, 39: 8833-8839.

DOI Google Scholar

[17]

Augustin C, Hungerbach W. Production of hollow spheres (HS) and hollow sphere structures (HSS). Mater Lett 2009, 63: 1109-1112.

DOI Google Scholar

[18]

Thijs I, Luyten J, Mullens S. Producing ceramic foams with hollow spheres. J Am Ceram Soc 2004, 87: 170-172.

DOI Google Scholar

[19]

Shao Y, Jia D, Liu B. Characterization of porous silicon nitride ceramics by pressureless sintering using fly ash cenosphere as pore-forming agent. J Eur Ceram Soc 2009, 29: 1529-1534.

DOI Google Scholar

[20]

Su Z, Xi X, Hu Y, et al. A new Al₂O₃ porous ceramic prepared by addition of hollow spheres. J Porous Mater 2014, 21: 601-609.

DOI Google Scholar

[21]

Qi F, Xu X, Xu J, et al. A novel way to prepare hollow sphere ceramics. J Am Ceram Soc 2014, 97: 3341-3347.

DOI Google Scholar

[22]

Yang J-L, Xu X-X, Wu J-M, et al. Preparation of Al₂O₃ poly-hollow microsphere (PHM) ceramics using Al₂O₃ PHMs coated with sintering additive via co-precipitation method. J Eur Ceram Soc 2015, 35: 2593-2598.

DOI Google Scholar

About this article

Publication history

Acknowledgements

Rights and permissions

Publication history

Received: 21 February 2015

Revised: 07 June 2015

Accepted: 12 June 2015

Published: 21 September 2015

Issue date: April 2015

Copyright

Acknowledgements

Our research work presented in this paper was supported by China Postdoctoral Science Foundation (Nos. 2013M530618 and 2015M572136), National Natural Science Foundation of China (Nos. 51172120 and 51372093), Fundamental Research Funds for the Central Universities (HUST: 2015J07), Open Fund of State Key Laboratory of New Ceramic and Fine Processing (Tsinghua University) (No. KF201518) and the 02 Important and Special Project for the State Science and Technology (No. 2013ZX2104-001-002).

Rights and permissions

This article is distributed under the terms of the Creative Commons Attribution License which permits any use, distribution, and reproduction in any medium, provided the original author(s) and the source are credited.