Catalytic liquid phase oxidation of 1,4-dioxane over a Pt/CeO2–ZrO2–Bi2O3/SBA-16 catalyst

Pil-Gyu CHOI; Takanobu OHNO; Nashito FUKUHARA; Toshiyuki MASUI; Nobuhito IMANAKA

doi:10.1007/s40145-015-0135-3

Journal of Advanced Ceramics 2015, 4(1): 71-75 https://doi.org/10.1007/s40145-015-0135-3

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Open Access | Issue | Published: 31 January 2015

Catalytic liquid phase oxidation of 1,4-dioxane over a Pt/CeO₂–ZrO₂–Bi₂O₃/SBA-16 catalyst

Show Author's Information Hide Author's Information Pil-Gyu CHOI, Takanobu OHNO, Nashito FUKUHARA, Toshiyuki MASUI, Nobuhito IMANAKA(

)

Department of Applied Chemistry, Faculty of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871, Japan

Keywords:

composite materials, oxidation, porous materials, 1,4-dioxane, catalyst

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CHOI P-G, OHNO T, FUKUHARA N, et al. Catalytic liquid phase oxidation of 1,4-dioxane over a Pt/CeO₂–ZrO₂–Bi₂O₃/SBA-16 catalyst. Journal of Advanced Ceramics, 2015, 4(1): 71-75. https://doi.org/10.1007/s40145-015-0135-3

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Abstract

A Pt/CeO₂–ZrO₂–Bi₂O₃/SBA-16 (Santa Barbara Amorphous No. 16) catalyst was prepared by hydrothermal and wet impregnation methods for catalytic purification of 1,4-dioxane in water. SBA-16 has a number of mesopores and the average size of the pores is 9.4 nm. In the present catalyst, platinum and CeO₂–ZrO₂–Bi₂O₃ were successfully dispersed in the pores of the SBA-16 support, and the temperature dependence of the liquid phase oxidation of 1,4-dioxane was examined. The oxidation reaction proceeded effectively in the air atmosphere in the temperature range of 40– 80 ℃.

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Catalytic liquid phase oxidation of 1,4-dioxane over a Pt/CeO₂–ZrO₂–Bi₂O₃/SBA-16 catalyst

Show Author's information Hide Author's Information Pil-Gyu CHOI, Takanobu OHNO, Nashito FUKUHARA, Toshiyuki MASUI, Nobuhito IMANAKA(

)

Department of Applied Chemistry, Faculty of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871, Japan

Abstract

Keywords: composite materials, oxidation, porous materials, 1,4-dioxane, catalyst

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Publication history

Received: 20 August 2014

Revised: 29 October 2014

Accepted: 06 November 2014

Published: 31 January 2015

Issue date: March 2015

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Open Access: This article is distributed under the terms of the Creative Commons Attribution License which permits any use, distribution, and reproduction in any medium, provided the original author(s) and the source are credited.