AI Chat Paper
Note: Please note that the following content is generated by AMiner AI. SciOpen does not take any responsibility related to this content.
{{lang === 'zh_CN' ? '文章概述' : 'Summary'}}
{{lang === 'en_US' ? '中' : 'Eng'}}
Chat more with AI
PDF (5.4 MB)
Collect
Submit Manuscript AI Chat Paper
Show Outline
Outline
Show full outline
Hide outline
Outline
Show full outline
Hide outline
Research Article | Open Access

Microstructure and mechanical properties of SiCf/SiBCN ceramic matrix composites

Jiaying WANGZhihua YANGXiaoming DUANDechang JIA( )Yu ZHOU
Institute for Advanced Ceramics, Harbin Institute of Technology, Harbin 150080, China
Show Author Information

Abstract

SiC fiber reinforced SiBCN ceramic matrix composites (CMCs) have been prepared by mechanical alloying and consolidated by hot pressing. During the sintering process, amorphous SiC fibers crystallized seriously and transformed into β-SiC. Meanwhile, the interfacial carbothermal reactions caused the strong bonding between the matrix and fibers. As a result, SiCf/SiBCN fractured in a typical catastrophic manner. Room-temperature mechanical properties reached the maximums for the CMC samples sintered at 1900 ℃/60 MPa/30 min. The density, flexural strength, Young’s modulus and fracture toughness are 2.56±0.02 g/cm3, 284.3±17.9 MPa, 183.5±11.1 GPa and 2.78±0.14 MPa·m1/2, respectively.

References

[1]
Colombo P, Mera G, Riedel R, et al. Polymer-derived ceramics: 40 years of research and innovation in advanced ceramics. J Am Ceram Soc 2010, 93:1805-1837.
[2]
Schiavon MA, Sorarù GD, Yoshida IVP. Poly (borosilazanes) as precursors of Si–B–C–N glasses: Synthesis and high temperatures properties. J Non-Cryst Solids 2004, 348:156-161.
[3]
Weinmann M, Schuhmacher J, Kummer H, et al. Synthesis and thermal behavior of novel Si–B–C–N ceramic precursors. Chem Mater 2000, 12:623-632.
[4]
Christ M, Thurn G, Weinmann M, et al. High-temperature mechanical properties of Si–B–C–N-precursor-derived amorphous ceramics and the applicability of deformation models developed for metallic glasses. J Am Ceram Soc 2000, 83:3025-3032.
[5]
Kumar NVR, Prinz S, Cai Y, et al. Crystallization and creep behavior of Si–B–C–N ceramics. Acta Mater 2005, 53:4567-4578.
[6]
Riedel R, Ruswisch LM, An LN, et al. Amorphous silicoboron carbonitride ceramic with very high viscosity at temperatures above 1500 ℃. J Am Ceram Soc 1998, 81:3341-3344.
[7]
Widgeon S, Mera G, Gao Y, et al. Effect of precursor on speciation and nanostructure of SiBCN polymer-derived ceramics. J Am Ceram Soc 2013, 96:1651-1659.
[8]
Vijayakumar A, Todi RM, Sundaram KB. Effect of N2/Ar gas mixture composition on the chemistry of SiCBN thin films prepared by RF reactive sputtering. J Electrochem Soc 2007, 154:H271-H274.
[9]
Vishnyakov VM, Ehiasarian AP, Vishnyakov VV, et al. Amorphous boron containing silicon carbo-nitrides created by ion sputtering. Surf Coat Technol 2011, 206:149-154.
[10]
Yang Z-H, Zhou Y, Jia D-C, et al. Microstructures and properties of SiB0.5C1.5N0.5 ceramics consolidated by mechanical alloying and hot pressing. Mat Sci Eng A 2008, 489:187-192.
[11]
Weinmann M, Kamphowe TW, Schuhmacher J, et al. Design of polymeric Si–B–C–N ceramic precursors for application in fiber-reinforced composite materials. Chem Mater 2000, 12:2112-2122.
[12]
Lee SH, Weinmann M, Aldinger F. Processing and properties of C/Si–B–C–N fiber-reinforced ceramic matrix composites prepared by precursor impregnation and pyrolysis. Acta Mater 2008, 56:1529-1538.
[13]
Lee S-H, Weinmann M. Cfiber/SiCfiller/Si–B–C–Nmatrix composites with extremely high thermal stability. Acta Mater 2009, 57:4374-4381.
[14]
Lee S-H, Weinmann M, Aldinger F. Fabrication of fiber-reinforced ceramic composites by the modified slurry infiltration technique. J Am Ceram Soc 2007, 90:2657-2660.
[15]
Lee S-H, Weinmann M, Gerstel P, et al. Extraordinary thermal stability of SiC particulate-reinforced polymer-derived Si–B–C–N composites. Scripta Mater 2008, 59:607-610.
[16]
Zhang P, Jia D, Yang Z, et al. Progress of a novel non-oxide Si–B–C–N ceramic and its matrix composites. J Adv Ceram 2012, 1:157-178.
[17]
Wang J, Duan X, Yang Z, et al. Ablation mechanism and properties of SiCf/SiBCN ceramic composites under an oxyacetylene torch environment. Corros Sci 2014, 82:101-107.
[18]
Zhang P, Jia D, Yang Z, et al. Physical and surface characteristics of the mechanically alloyed SiBCN powder. Ceram Int 2012, 38:6399-6404.
[19]
Zhang P, Jia D, Yang Z, et al. Influence of ball milling parameters on the structure of the mechanically alloyed SiBCN powder. Ceram Int 2013, 39:1963-1969.
[20]
Zhang P, Jia D, Yang Z, et al. Crystallization and microstructural evolution process from the mechanically alloyed amorphous SiBCN powder to the hot-pressed nano SiC/BN(C) ceramic. J Mater Sci 2012, 47:7291-7304.
[21]
Chen L, Zhang L, Cai Z, et al. Effects of oxidation curing and sintering additives on the formation of polymer-derived near-stoichiometric silicon carbide fibers. J Am Ceram Soc 2008, 91:428-436.
[22]
Schreck P, Vix-Guterl C, Ehrburger P, et al. Reactivity and molecular structure of silicon carbide fibres derived from polycarbosilanes. J Mater Sci 1992, 27:4237-4242.
[23]
Schreck P, Vix-Gguterl C, Ehrburger P, et al. Reactivity and molecular structure of silicon carbide fibres derived from polycarbosilanes. J Mater Sci 1992, 27:4243-4246.
[24]
Ponthieu C, Marhic C, Lancin M, et al. SIMS, EDX, EELS, AES, XPS study of interphases in nicalon fibre–LAS glass matrix composites II. J Mater Sci 1994, 29:4535-4544.
[25]
Lancin M, Ponthieu C, Marhic C, et al. SIMS, EDX, EELS, AES, XPS study of interphases in nicalon fibre–LAS glass matrix composites I. J Mater Sci 1994, 29:3759-3766.
[26]
Bois L, Maquet J, Babonneau F, et al. Structural characterization of sol–gel derived oxycarbide glasses. 2. Study of the thermal stability of the silicon oxycarbide phase. Chem Mater 1995, 7:975-981.
[27]
Honstein G, Chatillon C, Baillet F. Thermodynamic approach to the vaporization and growth phenomena of SiC ceramics. I. SiC and SiC–SiO2 mixtures under neutral conditions. J Eur Ceram Soc 2012, 32:1117-1135.
[28]
Ding D, Zhou W, Luo F, et al. Mechanical properties and oxidation resistance of SiCf/CVI–SiC composites with PIP–SiC interphase. Ceram Int 2012, 38:3929-3934.
Journal of Advanced Ceramics
Pages 31-38
Cite this article:
WANG J, YANG Z, DUAN X, et al. Microstructure and mechanical properties of SiCf/SiBCN ceramic matrix composites. Journal of Advanced Ceramics, 2015, 4(1): 31-38. https://doi.org/10.1007/s40145-015-0128-2

847

Views

46

Downloads

32

Crossref

N/A

Web of Science

35

Scopus

4

CSCD

Altmetrics

Received: 29 August 2014
Accepted: 17 September 2014
Published: 31 January 2015
© The author(s) 2015

Open Access: This article is distributed under the terms of the Creative Commons Attribution License which permits any use, distribution, and reproduction in any medium, provided the original author(s) and the source are credited.

Return