AI Chat Paper
Note: Please note that the following content is generated by AMiner AI. SciOpen does not take any responsibility related to this content.
{{lang === 'zh_CN' ? '文章概述' : 'Summary'}}
{{lang === 'en_US' ? '中' : 'Eng'}}
Chat more with AI
Powered by AMiner. Clicking this button will take you away from SciOpen.
Home Journal of Advanced Ceramics Article
PDF (833.1 KB)
Cite
EndNote(RIS) BibTeX
Collect
Submit Manuscript AI Chat Paper
Show Outline
Outline
Show full outline
Hide outline
Outline
Show full outline
Hide outline
Research Article | Open Access

pH-controlled hydrothermal synthesis of titanium phosphates and their powder properties

Hiroaki ONODA( ), Taisuke YAMAGUCHI
Department of Informatics and Environmental Sciences, Kyoto Prefectural University, 1-5, Shimogamo Nakaragi-cyo, Sakyo-ku, Kyoto 606-8522, Japan
Show Author Information

Abstract

Titanium phosphates were prepared from titanium chloride and sodium pyrophosphate at various pH in hydrothermal process as a novel white pigment for cosmetics. Their chemical composition, powder properties, photo catalytic activity, colour phase and smoothness were studied. The obtained materials had a higher Ti/P ratio than that used in preparation conditions because of the formation of titanium oxide and hydroxide. The samples prepared at pH = 4 had particles smaller than 100 µm. Titanium phosphates had less photo catalytic activity to protect the sebum on the skin. The obtained materials in hydrothermal process and their thermal products at 100 ℃ showed high reflectance in the range of visible light.

Keywords

titanium phosphatespyrophosphatepHphoto catalytic activitysmoothness

References

[1]
Diebold U. The surface science of titanium dioxide. Surf Sci Rep 2003, 48:53-229.
Crossref Google Scholar
[2]
Senzui M, Tamura T, Miura K, et al. Study on penetration of titanium dioxide (TiO2) nanoparticles into intact and damaged skin in vitro. J Toxicol Sci 2010, 35:107-113.
Crossref Google Scholar
[3]
Gamer AO, Leibold E, van Ravenzwaay B. The in vitro absorption of microfine zinc oxide and titanium dioxide through porcine skin. Toxicol in Vitro 2006, 20:301-307.
Crossref Google Scholar
[4]
Onoda H, Nariai H, Moriwaki A, et al. Formation and catalytic characterization of various rare earth phosphates. J Mater Chem 2002, 12:1754-1760.
Crossref Google Scholar
[5]
Onoda H, Ohta T, Tamaki J, et al. Decomposition of trifluoromethane over nickel pyrophosphate catalysts containing metal cation. Appl Catal A: Gen 2005, 288:98-103.
Crossref Google Scholar
[6]
He Y, Zhao M, Song Y, et al. Effect of Bi3+ on fluorescence properties of YPO4:Dy3+ phosphors synthesized by a modified chemical co-precipitation method. J Lumin 2011, 131:1144-1148.
Crossref Google Scholar
[7]
Onoda H, Matsui H, Tanaka I. Improvement of acid and base resistance of nickel phosphate pigment by the addition of lanthanum cation. Mat Sci Eng B 2007, 141:28-33.
Crossref Google Scholar
[8]
Rao GV. Shashikala HD. Optical, dielectric and mechanical properties of silver nanoparticle embedded calcium phosphate glass. J Non-Cryst Solids 2014, 402:204-209.
Crossref Google Scholar
[9]
Xu C, Lee J, Teja AS. Continuous hydrothermal synthesis of lithium iron phosphate particles in subcritical and supercritical water. J Supercrit Fluid 2008, 44:92-97.
Crossref Google Scholar
[10]
Vani R, Girija EK, Elayaraja K, et al. Hydrotehrmal synthesis of porous triphasic hydroxyapatite/(α and β) tricalcium phosphate. J Mater Sci: Mater M 2009, 20:43-48.
Crossref Google Scholar
[11]
Tomozawa M, Hiromoto S. Microstructure of hydroxyapatite- and octacalcium phosphate-coatings formed on magnesium by a hydrothermal treatment at various pH values. Acta Mater 2011, 59:355-363.
Crossref Google Scholar
[12]
Onoda H, Yamaguchi T. Synthesis of titanium phosphate with additives and their powder properties for cosmetics. Mater Sci Appl 2012, 3:18-23.
Crossref Google Scholar
[13]
Onoda H, Yamaguchi T, Takenaka A. Synthesis and pigmental properties of titanium phosphates with the addition of urea. Int J Cosmetic Sci 2012, 34:86-90.
Crossref Google Scholar
[14]
Raynaud S, Champion E, Bernache-Assollant D, et al. Calcium phosphate apatites with variable Ca/P atomic ratio I. Synthesis, characterisation and thermal stability of powders. Biomaterials 2002, 23:1065-1072.
Crossref Google Scholar
[15]
Averbuch MT, Durif A. Topics in Phosphate Chemistry. Singapore:World Scientific Publishing, 1996.
[16]
Onoda H, Ohta T, Kojima K. Mechanochemical reforming of nickel pyrophosphate. Mater Chem Phys 2006, 98:363-367.
Crossref Google Scholar
[17]
Lucena-Conde F, Prat L. A new reagent for the colorimetric and spectrophotometric determination of phosphorus, arsenic and germanium. Anal Chim Acta 1957, 16:473-479.
Crossref Google Scholar
[18]
Ramaswamy V, Jagtap NB, Vijayanand S, et al. Photocatalytic decomposition of methylene blue on nanocrystalline titania prepared by different methods. Mater Res Bull 2008, 43:1145-1152.
Crossref Google Scholar
[19]
Du P, Bueno-López A, Verbaas M, et al. The effect of surface OH-population on the photocatalytic activity of rare earth-doped P25-TiO2 in methylene blue degradation. J Catal 2008, 260:75-80.
Crossref Google Scholar
[20]
Cheng SY, Yuen CWM, Kan CW, et al. A comprehensive study of silicone-based cosmetic textile agent. Fiber Polym 2009, 10:132-140.
Crossref Google Scholar
Journal of Advanced Ceramics
Volume 3 Issue 4,
December 2014
Pages 326-331
DOI: 10.1007/s40145-014-0124-y
Cite this article:
ONODA H, YAMAGUCHI T. pH-controlled hydrothermal synthesis of titanium phosphates and their powder properties. Journal of Advanced Ceramics, 2014, 3(4): 326-331. https://doi.org/10.1007/s40145-014-0124-y

921

Views

17

Downloads

3

Crossref

N/A

Web of Science

3

Scopus

0

CSCD

Altmetrics
Received: 24 June 2014
Revised: 12 August 2014
Accepted: 18 August 2014
Published: 30 November 2014
© The author(s) 2014

Open Access: This article is distributed under the terms of the Creative Commons Attribution License which permits any use, distribution, and reproduction in any medium, provided the original author(s) and the source are credited.
Return