Journal Home > Volume 3 , Issue 4
Journal of Advanced Ceramics 2014, 3(4): 259-268 https://doi.org/10.1007/s40145-014-0115-z
Research Article | Open Access | Issue | Published: 30 November 2014

Utilization of iron oxide bearing pellets waste for preparing hard and soft ferromagnetic glass ceramics

Show Author's Information Salwa A. M. ABDEL-HAMEEDa( ),  Ibrahim M. HAMEDb,  Nehal A. ERFANb
Glass Research Department, National Research Center, Dokki, Cairo, Egypt
Chemical Engineering Department, Faculty of Engineering, Minia University, Minia, Egypt
Keywords:
nanostructure, magnetic materials, pellets waste
Cite this article:
ABDEL-HAMEED SAM, HAMED IM, ERFAN NA. Utilization of iron oxide bearing pellets waste for preparing hard and soft ferromagnetic glass ceramics. Journal of Advanced Ceramics, 2014, 3(4): 259-268. https://doi.org/10.1007/s40145-014-0115-z
Download citation
EndNote(RIS)
BibTeX

584

Views

24

Downloads

Citations

3

Crossref

N/A

WoS

3

Scopus

0

CSCD

Abstract Full text About this article

About 8% of the imported iron oxide pellets burdens to Egypt are wasted. In this paper, broken pellets waste (BPW) is used as raw material for the preparation of hard magnetic glass ceramics (HMGC) as well as soft magnetic glass ceramics (SMGC). About 54 wt% and 37 wt% of BPW are used to prepare SMGC and HMGC, respectively. Differential thermal analysis (DTA) reveals two broad exothermic peaks for HMGC at 591 ℃ and 697 ℃, whereas one exothermic peak at 820 ℃ is detected for SMGC. X-ray diffraction (XRD) shows the crystallization of hematite as the sol phase in BPW, and meanwhile, Zn–ferrite and Ba–hexaferrite are identified in SMGC and HMGC, respectively. Transmission electron microscopy (TEM) reveals the crystallization of nanosize particles of ~20 nm for SMGC and ~12 nm for HMGC. Vibrating scanning magnetometer (VSM) reveals an increase in saturation magnetization from ~1 emu/g for BPW to ~77 emu/g for SMGC and 21 emu/g for HMGC.


menu
Abstract
Full text
Outline
About this article

Utilization of iron oxide bearing pellets waste for preparing hard and soft ferromagnetic glass ceramics

Show Author's information Salwa A. M. ABDEL-HAMEEDa( ), Ibrahim M. HAMEDb, Nehal A. ERFANb
Glass Research Department, National Research Center, Dokki, Cairo, Egypt
Chemical Engineering Department, Faculty of Engineering, Minia University, Minia, Egypt

Abstract

About 8% of the imported iron oxide pellets burdens to Egypt are wasted. In this paper, broken pellets waste (BPW) is used as raw material for the preparation of hard magnetic glass ceramics (HMGC) as well as soft magnetic glass ceramics (SMGC). About 54 wt% and 37 wt% of BPW are used to prepare SMGC and HMGC, respectively. Differential thermal analysis (DTA) reveals two broad exothermic peaks for HMGC at 591 ℃ and 697 ℃, whereas one exothermic peak at 820 ℃ is detected for SMGC. X-ray diffraction (XRD) shows the crystallization of hematite as the sol phase in BPW, and meanwhile, Zn–ferrite and Ba–hexaferrite are identified in SMGC and HMGC, respectively. Transmission electron microscopy (TEM) reveals the crystallization of nanosize particles of ~20 nm for SMGC and ~12 nm for HMGC. Vibrating scanning magnetometer (VSM) reveals an increase in saturation magnetization from ~1 emu/g for BPW to ~77 emu/g for SMGC and 21 emu/g for HMGC.

Keywords: nanostructure, magnetic materials, pellets waste

References(34)

[1]
Cetas TC, Gross EJ, Contractor Y. A ferrite core/metallic sheath thermoseed for interstitial thermal therapies. IEEE T Bio-med Eng 1998, 45:68-77.
DOI Google Scholar
[2]
Jordan A, Scholz R, Wust P, et al. Magnetic fluid hyperthermia (MFH): Cancer treatment with AC magnetic field induced excitation of biocompatible superparamagnetic nanoparticles. J Magn Magn Mater 1999, 201:413-419.
DOI Google Scholar
[3]
Gómez-Lopera SA, Plaza RC, Delgado AV. Synthesis and characterization of spherical magnetite/ biodegradable polymer composite particles. J Colloid Interface Sci 2001, 240:40-47.
DOI Google Scholar
[4]
Lee YK, Kim DH, Lee YJ, et al. Ceramics, cells and tissues. Eighth Annual Seminar and Meeting, Faenza, 2003.
[5]
Takegami K, Sano T, Wakabayashi H, et al. New ferromagnetic bone cement for local hyperthermia. J Biomed Mater Res A 1998, 43:210-214.
DOI
[6]
Borrelli NF, Young PL. Positive imaging method using doped silver halide medium. US Patent 4,323,640. 1982.
[7]
Kokubo T, Yamamuro T, Ebisawa Y, et al. European Patent 361797. 1990.
[8]
Oh S-H, Choi S-Y, Lee Y-K, et al. Research on annihilation of cancer cells by glass–ceramics for cancer treatment with external magnetic field. I. Preparation and cytotoxicity. J Biomed Mater Res A 2001, 54:360-365.
DOI
[9]
Ebisawa Y, Miyaji F, Kokubo T, et al. Surface reaction of bioactive and ferrimagnetic glass–ceramics in the system FeO–Fe2O3–CaO–SiO2. J Ceram Soc Jpn 1997, 105:947-951.
DOI Google Scholar
[10]
Arcos D, del Real RP, Vallet-Regı́ M. A novel bioactive and magnetic biphasic material. Biomaterials 2002, 23:2151-2158.
DOI Google Scholar
[11]
Ebisawa Y, Miyaji F, Kokubo T, et al. Bioactivity of ferrimagnetic glass–ceramics in the system FeO–Fe2O3–CaO–SiO2. Biomaterials 1997, 18:1277-1284.
DOI Google Scholar
[12]
O'Horo M, Steinitz R. Characterization of devitrification of an iron-containing glass by electrical and magnetic properties. Mater Res Bull 1968, 3:117-125.
DOI Google Scholar
[13]
Auric P, Van Dang N, Bandyopadhyay AK, et al. Superparamagnetism and ferrimagnetism of the small particles of magnetite in a silicate matrix. J Non-Cryst Solids 1982, 50:97-106.
DOI Google Scholar
[14]
Bretcanu O, Spriano S, Verné E, et al. The influence of crystallised Fe3O4 on the magnetic properties of coprecipitation-derived ferrimagnetic glass–ceramics. Acta Biomater 2005, 1:421-429.
DOI Google Scholar
[15]
Abdel-Hameed SAM, Hessien MM, Azooz MA. Preparation and characterization of some ferromagnetic glass–ceramics contains high quantity of magnetite. Ceram Int 2009, 35:1539-1544.
DOI Google Scholar
[16]
Abdel-Hameed SAM, El Kady AM. Effect of different additions on the crystallization behavior and magnetic properties of magnetic glass–ceramic in the system Fe2O3–ZnO–CaO–SiO2. J Adv Mater 2012, 3:167-175
DOI Google Scholar
[17]
Shirk BT, Buessem WR. Magnetic properties of barium ferrite formed by crystallization of a glass. J Am Ceram Soc 1970, 53:192-196.
DOI Google Scholar
[18]
Gornert P, Sinn E, Schuppel W, et al. Structural and magnetic properties of BaFe12-2xCoxTixO19 powders prepared by the glass crystallization method. IEEE T Magn 1990, 26:12-14.
DOI Google Scholar
[19]
Evans BJ, Hafner SS, Weber HP. Electric field gradients at 57Fe in ZnFe2O4 and CdFe2O4. J Chem Phys 1971, 55:5282.
DOI Google Scholar
[20]
Ata-Allah SS, Fayek MK. Effect of Cu substitution on conductivity of Ni–Al ferrite. J Phys Chem Solids 2000, 61:1529-1534.
DOI Google Scholar
[21]
Mahmoud MH, Hamdeh HH, Ho JC, et al. Mössbauer studies of manganese ferrite fine particles processed by ball-milling. J Magn Magn Mater 2000, 220:139-146.
DOI Google Scholar
[22]
Müller R, Ulbrich C, Schüppel W, et al. Preparation and properties of barium-ferrite-containing glass ceramics. J Eur Ceram Soc 1999, 19:1547-1550.
DOI Google Scholar
[23]
Lee C-K, Speyer RF. Glass formation and crystallization of barium ferrite in the Na2O–BaO–Fe2O3–SiO2 system. J Mater Sci 1994, 29:1348-1351.
DOI Google Scholar
[24]
Sohn S-B, Choi S-Y, Shim IB. Preparation of Ba–ferrite containing glass–ceramics in BaO–Fe2O3–SiO2. J Magn Magn Mater 2002, 239:533-536.
DOI Google Scholar
[25]
Rezlescu L, Rezlescu E, Popa PD, et al. Fine barium hexaferrite powder prepared by the crystallisation of glass. J Magn Magn Mater 1999, 193:288-290.
DOI Google Scholar
[26]
Görnert P, Sinn E, Rösler M. Crystalline materials: Growth and characterization. Key Eng Mat 1991, 58:129-148.
DOI Google Scholar
[27]
Abdel-Hameed SAM, Marzouk MA, Abdel-Ghany AE. Magnetic properties of nanoparticles glass–ceramic rich with copper ions. J Non-Cryst Solids 2011, 357:3888-3896.
DOI Google Scholar
[28]
Safarikova M, Safarik I. The application of magnetic techniques in biosciences. Magnetic and Electrical Separation 2001, 10:223-252.
DOI Google Scholar
[29]
Sharifi I, Shokrollahi H, Amiri S. Ferrite-based magnetic nanofluids used in hyperthermia applications. J Magn Magn Mater 2012, 324:903-915.
DOI Google Scholar
[30]
El-Shennawi AWA, Moris MM, Khater GA, et al. Thermodynamic investigation of crystallization behaviour of pyroxenic basalt-based glasses. J Therm Anal Calorim 1998, 51:553-560.
DOI Google Scholar
[31]
Roy MK, Haldar B, Verma HC. Characteristic length scales of nanosize zinc ferrite. Nanotechnology 2006, 17:232.
DOI Google Scholar
[32]
Bretcanu O, Verné E, Cöisson M, et al. Temperature effect on the magnetic properties of the coprecipitation derived ferrimagnetic glass–ceramics. J Magn Magn Mater 2006, 300:412-417.
DOI Google Scholar
[33]
Cullity RD. Introduction of Magnetic Materials. Addison-Wesley, 1972.
[34]
Abdel-Hameed SAM, Elwan RL. Effect of La2O3, CoO, Cr2O3 and MoO3 nucleating agents on crystallization behavior and magnetic properties of ferromagnetic glass–ceramic in the system Fe2O3·CaO·ZnO·SiO2. Mater Res Bull 2012, 47:1233-1238.
DOI Google Scholar
Publication history
Copyright
Rights and permissions

Publication history

Received: 04 May 2014
Revised: 18 June 2014
Accepted: 20 June 2014
Published: 30 November 2014
Issue date: December 2014

Copyright

© The author(s) 2014

Rights and permissions

Open Access: This article is distributed under the terms of the Creative Commons Attribution License which permits any use, distribution, and reproduction in any medium, provided the original author(s) and the source are credited.

Return