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Journal of Advanced Ceramics 2014, 3(2): 155-164 https://doi.org/10.1007/s40145-014-0107-z
Research Article | Open Access | Issue | Published: 01 June 2014

Influence of Fe2O3 on the physical, structural and electrical properties of sodium lead borate glasses

Show Author's Information Safeya IBRAHIMa,  Mohamed Mahmoud GOMAAb( ),  Hussein DARWISHa
Glass Research Department, National Research Centre, Dokki, Cairo, Egypt
Geophysical Sciences Department, National Research Centre, Dokki, Cairo, Egypt
Keywords:
thermal expansion, microhardness, borate glasses, Fourier transform infrared (FTIR) spectra, AC electrical properties
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IBRAHIM S, GOMAA MM, DARWISH H. Influence of Fe2O3 on the physical, structural and electrical properties of sodium lead borate glasses. Journal of Advanced Ceramics, 2014, 3(2): 155-164. https://doi.org/10.1007/s40145-014-0107-z
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Abstract Full text About this article

The influence of adding Fe2O3 at the expense of Na2O in sodium lead borate glasses on the structural, physical and electrical properties have been investigated. Results obtained from Fourier transform infrared (FTIR) spectra indicated that Fe2O3 plays an important role in converting three coordinated boron atoms [BO3] to four coordinated boron atoms [BO4]. The physical properties such as density and molar volume helped to evaluate the compact structure of the prepared glass samples due to presence of [BO4] groups. The increase of Fe2O3/Na2O replacements led to increasing the microhardness values and decreasing the thermal expansion coefficients of the studied glasses. The increase of Fe2O3/Na2O replacements generally decreased the AC conductivity. That decrease might be due to converting of the three coordinated boron atoms [BO3] to four coordinated boron atoms [BO4]. Dielectric constants of the samples might be an indication of the distortion in the coordinated boron atoms. The obtained experimental data indicated the internal structure of glass network and the change of the structure of the samples from three [BO3] to four coordinated boron atoms [BO4].


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About this article

Influence of Fe2O3 on the physical, structural and electrical properties of sodium lead borate glasses

Show Author's information Safeya IBRAHIMa, Mohamed Mahmoud GOMAAb( ), Hussein DARWISHa
Glass Research Department, National Research Centre, Dokki, Cairo, Egypt
Geophysical Sciences Department, National Research Centre, Dokki, Cairo, Egypt

Abstract

The influence of adding Fe2O3 at the expense of Na2O in sodium lead borate glasses on the structural, physical and electrical properties have been investigated. Results obtained from Fourier transform infrared (FTIR) spectra indicated that Fe2O3 plays an important role in converting three coordinated boron atoms [BO3] to four coordinated boron atoms [BO4]. The physical properties such as density and molar volume helped to evaluate the compact structure of the prepared glass samples due to presence of [BO4] groups. The increase of Fe2O3/Na2O replacements led to increasing the microhardness values and decreasing the thermal expansion coefficients of the studied glasses. The increase of Fe2O3/Na2O replacements generally decreased the AC conductivity. That decrease might be due to converting of the three coordinated boron atoms [BO3] to four coordinated boron atoms [BO4]. Dielectric constants of the samples might be an indication of the distortion in the coordinated boron atoms. The obtained experimental data indicated the internal structure of glass network and the change of the structure of the samples from three [BO3] to four coordinated boron atoms [BO4].

Keywords: thermal expansion, microhardness, borate glasses, Fourier transform infrared (FTIR) spectra, AC electrical properties

References(50)

[1]
Pisarski WA, Goryczka T, Wodecka-Duś B, et al. Structure and properties of rare earth-doped lead borate glasses. Mat Sci Eng B 2005, 122: 94–99.
DOI Google Scholar
[2]
Agarwal A, Seth VP, Gahlot PS, et al. Effect of Bi2O3 on EPR, optical transmission and DC conductivity of vanadyl doped alkali bismuth borate glasses. J Phys Chem Solids 2003, 64: 2281–2288.
DOI Google Scholar
[3]
Farouk H, Solimani AA, Aly SA, et al. Role of iron addition on structure and electrical and magnetic properties of lithium lead borate glasses. Mat Sci Eng B 1996, 38: 217–221.
DOI Google Scholar
[4]
Kumar RR, Bhatnagar AK, Rao JL. EPR of vanadyl ions in alkali lead borate glasses. Mater Lett 2002, 57: 178–182.
DOI Google Scholar
[5]
Lee SW, Shim KB, Auh KH. Effects of BaO on the glass formation of the PbO–B2O3–TiO2–BaO system in relation to transition temperatures. J Mater Sci 2002, 37: 2011–2016.
DOI Google Scholar
[6]
Koudelka L, Mošner P, Zeyer M, et al. Lead borophosphate glasses doped with titanium dioxide. J Non-Cryst Solids 2003, 326–327: 72–76.
DOI Google Scholar
[7]
Metwalli E. Copper redox behavior, structure and properties of copper lead borate glasses. J Non-Cryst Solids 2003, 317: 221–230.
DOI Google Scholar
[8]
Pisarska J, Pisarski WA, Ryba-Romanowski W. Laser spectroscopy of Nd3+ and Dy3+ ions in lead borate glasses. Opt Laser Technol 2010, 42: 805–809.
DOI Google Scholar
[9]
Pisarska J. Luminescence behavior of Dy3+ ions in lead borate glasses. Opt Mater 2009, 31: 1784–1786.
DOI Google Scholar
[10]
Saddeek YB. Structural and acoustical studies of lead sodium borate glasses. J Alloys Compd 2009, 467: 14–21.
DOI Google Scholar
[11]
Ciceo-Lucacel R, Ardelean I. FT-IR and Raman study of silver lead borate-based glasses. J Non-Cryst Solids 2007, 353: 2020–2024.
DOI Google Scholar
[12]
Sears VF. Neutron scattering lengths and cross sections. Neutron News 1992, 3: 26–37.
DOI Google Scholar
[13]
Ushida H, Iwadate Y, Hattori T, et al. Network structure of B2O3–PbO and B2O3–PbO–PbBr2 glasses analyzed by pulsed neutron diffraction and Raman spectroscopy. J Alloys Compd 2004, 377: 167–173.
DOI Google Scholar
[14]
Ganguli M, Rao KJ. Structural role of PbO in Li2O–PbO–B2O3 glasses. J Solid State Chem 1999, 145: 65–76.
DOI Google Scholar
[15]
Rao KJ, Rao BG, Elliott SR. Glass formation in the system PbO–PbCl2. J Mater Sci 1985, 20: 1678–1682.
DOI Google Scholar
[16]
Chakradhar RPS, Sivaramaiah G, Rao JL, et al. Fe3+ ions in alkali lead tetraborate glasses—an electron paramagnetic resonance and optical study. Spectrochim Acta A 2005, 62: 51–57.
DOI Google Scholar
[17]
Moustafa YM, El-Egili K, Doweidar H, et al. Structure and electric conduction of Fe2O3–P2O5 glasses. Physica B 2004, 353: 82–91.
DOI Google Scholar
[18]
Mansour E, Moustafa YM, El-Damrawi GM, et al. Memory switching of Fe2O3–BaO–V2O5 glasses. Physica B 2001, 305: 242–249.
DOI Google Scholar
[19]
Collins DW, Mulay LN. Precipitation and magnetic behavior of beta NaFeO2 in glasses along the Na2SiO3–Fe2O3 join. J Am Ceram Soc 1971, 54: 69–72.
DOI Google Scholar
[20]
Veerabhadra Rao A, Laxmikanth C, Appa Rao B, et al. Dielectric relaxation and a.c. conduction phenomena of PbO–PbF2–B2O3 glasses doped with FeO. J Phys Chem Solids 2006, 67: 2263–2274.
DOI Google Scholar
[21]
Chimalawonga P, Kaewkhao J, Kedkaew C, et al. Optical and electronic polarizability investigation of Nd3+-doped soda-lime silicate glasses. J Phys Chem Solids 2010, 71: 965–970.
DOI Google Scholar
[22]
Gomaa MM. Saturation effect on electrical properties of hematitic sandstone in the audio frequency range using non-polarizing electrodes. Geophys Prospect 2009, 57: 1091–1100.
DOI Google Scholar
[23]
Gomaa MM, Alikaj P. Effect of electrode contact impedance on A.C. electrical properties of wet hematite sample. Mar Geophys Res 2009, 30: 265–276.
DOI Google Scholar
[24]
Gomaa MM. Chapter 1: Factors affecting electrical properties of some rocks. In Horizons in Earth Science Research, Volume 6. Veress B, Szigethy J, Eds. New York: Nova Science Publishers, Inc., 2012.
[25]
Gomaa MM, Abo-Mosallam HA, Darwish H. Electrical and mechanical properties of alkali barium titanium alumino borosilicate glass-ceramics containing strontium or magnesium. J Mater Sci: Mater El 2009, 20: 507–516.
DOI Google Scholar
[26]
Stefan R, Culea E, Pascuta P. The effect of copper ions addition on structural and optical properties of zinc borate glasses. J Non-Cryst Solids 2012, 358: 839–846.
DOI Google Scholar
[27]
Uchino T, Yoko T. Ab initio molecular orbital calculations on the structure and the low-frequency vibrational modes in B2O3 and alkali borate glasses. Borate Glasses Crystals and Melts International Conference, Society of Glass Technology, Sheffield, 1997: 417–424.
[28]
Pal Singh G, Singh DP. Spectroscopic study of ZnO doped CeO2–PbO–B2O3 glasses. Physica B 2011, 406: 3402–3405
DOI Google Scholar
[29]
Singh DP, Singh GP. Conversion of covalent to ionic behavior of Fe2O3–CeO2–PbO–B2O3 glasses for ionic and photonic application. J Alloys Compd 2013, 546: 224–228.
DOI Google Scholar
[30]
Singh GP, Kaur P, Kaur S, et al. Conversion of covalent to ionic character of V2O5–CeO2–PbO–B2O3 glasses for solid state ionic devices. Physica B 2012, 407: 4269–4273.
DOI Google Scholar
[31]
Bobkova NM, Khot'ko SA. Structure of zinc-borate low-melting glasses derived from IR spectroscopy data. J Appl Spectrosc 2005, 72: 853–857.
DOI Google Scholar
[32]
El-Alaily NA, Mohamed RM. Effect of irradiation on some optical properties and density of lithium borate glass. Mat Sci Eng B 2003, 98: 193–203.
DOI Google Scholar
[33]
Sambasiva Rao K, Krishna Mohan N, Veeraiah N. Physical properties of (Li2O)0.40(Fe2O3)0.05-x(P2O5)0.55: (Ag2O)x glasses. Turk J Phys 2007, 31: 11–30.
Google Scholar
[34]
Fang X, Ray CS, Marasinghe GK, et al. Properties of mixed Na2O and K2O iron phosphate glasses. J Non-Cryst Solids 2000, 263–264: 293–298.
DOI Google Scholar
[35]
Kashif I, Rahman SA, Mostafa AG, et al. Structural analysis and physical properties of iron–molybdenum lithium-borate glasses. J Alloys Compd 2008, 450: 352–358.
DOI Google Scholar
[36]
Singh SP, Chakradhar RPS, Rao JL, et al. EPR, FTIR, optical absorption and photoluminescence studies of Fe2O3 and CeO2 doped ZnO–Bi2O3–B2O3 glasses. J Alloys Compd 2010, 493: 256–262.
DOI Google Scholar
[37]
Rada M, Rada S, Pascuta P, et al. Structural properties of molybdenum-lead-borate glasses. Spectrochim Acta A 2010, 77: 832–837.
DOI Google Scholar
[38]
Rajyasree Ch, Rao DK. Spectroscopic investigations on alkali earth bismuth borate glasses doped with CuO. J Non-Cryst Solids 2010, 357: 836–841.
DOI Google Scholar
[39]
Gandhi Y, Sudhakar KSV, Nagarjuna M, et al. Influence of WO3 on some physical properties of MO–Sb2O3–B2O3 (M = Ca, Pb and Zn) glass system. J Alloys Compd 2009, 485: 876–886.
DOI Google Scholar
[40]
Gaafar MS, El-Aal NSA, Gerges OS, et al. Elastic properties and structural studies on some zinc-borate glasses derived from ultrasonic, FT-IR and X-ray techniques. J Alloys Compd 2009, 475: 535–542.
DOI Google Scholar
[41]
Sharma G, Singh K, Manupriya , et al. Effect of gamma irradiation on optical and physical properties of PbO–Bi2O3–B2O3 glasses. Radiat Phys Chem 2006, 75: 959–966.
DOI Google Scholar
[42]
Saritha D, Markandeya Y, Salagram M, et al. Effect of Bi2O3 on physical, optical and structural studies of ZnO–Bi2O3–B2O3 glasses. J Non-Cryst Solids 2008, 354: 5573–5579.
DOI Google Scholar
[43]
Gao G, Hu L, Fan H, et al. Effect of Bi2O3 on physical, optical and structural properties of boron silicon bismuthate glasses. Opt Mater 2009, 32: 159–163.
DOI Google Scholar
[44]
Simon V, Spinu M, Stefan R. Structure and dissolution investigation of calcium–bismuth–borate glasses and vitroceramics containing silver. J Mater Sci: Mater M 2007, 18: 507–512.
DOI Google Scholar
[45]
Karthikeyan B, Philip R, Mohan S. Optical and non-linear optical properties of Nd3+-doped heavy metal borate glasses. Opt Commun 2005, 246: 153–162.
DOI Google Scholar
[46]
Fan H, Wang G, Hu L. Infrared, Raman and XPS spectroscopic studies of Bi2O3–B2O3–Ga2O3 glasses. Solid State Sci 2009, 11: 2065–2070.
DOI Google Scholar
[47]
Pascuta P, Pop L, Rada S, et al. The local structure of bismuth borate glasses doped with europium ions evidenced by FT-IR spectroscopy. J Mater Sci: Mater El 2008, 19: 424–428.
DOI Google Scholar
[48]
Gavriliu G. Thermal expansion and characteristic points of –Na2O–SiO2 glass with added oxides. J Eur Ceram Soc 2002, 22: 1375–1379.
DOI Google Scholar
[49]
Singh SP, Karmakar B. Synthesis and characterization of low softening point high Bi2O3 glasses in the K2O–B2O3–Bi2O3 system. Mater Charact 2011, 62: 626–634.
DOI Google Scholar
[50]
Gomaa MM. Relation between electric properties and water saturation for hematitic sandstone with frequency. Annals of Geophysics 2008, 51: 801–811.
DOI Google Scholar
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Publication history

Received: 19 March 2014
Revised: 24 April 2014
Accepted: 27 April 2014
Published: 01 June 2014
Issue date: June 2014

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© The author(s) 2014

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Open Access: This article is distributed under the terms of the Creative Commons Attribution License which permits any use, distribution, and reproduction in any medium, provided the original author(s) and the source are credited.

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