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Journal of Advanced Ceramics 2014, 3(2): 132-136 https://doi.org/10.1007/s40145-014-0103-3
Research Article | Open Access | Issue | Published: 01 June 2014

Preparation of titanium phosphate white pigments with titanium sulfate and their powder properties

Show Author's Information Hiroaki ONODAa( ),  Syohei FUJIKADOa,  Takeshi TOYAMAb
Department of Informatics and Environmental Sciences, Kyoto Prefectural University, 1-5, Shimogamo Nakaragi-cyo, Sakyo-ku, Kyoto 606-8522, Japan
Department of Materials and Applied Chemistry, College of Science and Technology, Nihon University, 1-8-14 Kanda-Surugadai, Chiyoda-ku, Tokyo 101-8308, Japan
Keywords:
white pigment, titanium phosphates, photocatalytic activity, smoothness
Cite this article:
ONODA H, FUJIKADO S, TOYAMA T. Preparation of titanium phosphate white pigments with titanium sulfate and their powder properties. Journal of Advanced Ceramics, 2014, 3(2): 132-136. https://doi.org/10.1007/s40145-014-0103-3
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Abstract Full text About this article

Titanium oxide that has photocatalytic activity is used as white pigment for cosmetics. A certain degree of sebum on the skin is decomposed by the ultraviolet radiation in sunlight. In this work, as novel white pigment, titanium phosphates were synthesized with titanium sulfate and phosphoric acid for cosmetics. Their chemical composition, powder properties, photocatalytic activity, color phase, moisture retention, and smoothness were studied. These titanium phosphates had less photocatalytic activity to protect the sebum on the skin. Samples without heating and those heated at 100 ℃ showed high reflectance in the range of visible light. Sample prepared in Ti/P = 3/2 had higher moisture retention than samples prepared in other Ti/P ratios.


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About this article

Preparation of titanium phosphate white pigments with titanium sulfate and their powder properties

Show Author's information Hiroaki ONODAa( ), Syohei FUJIKADOa, Takeshi TOYAMAb
Department of Informatics and Environmental Sciences, Kyoto Prefectural University, 1-5, Shimogamo Nakaragi-cyo, Sakyo-ku, Kyoto 606-8522, Japan
Department of Materials and Applied Chemistry, College of Science and Technology, Nihon University, 1-8-14 Kanda-Surugadai, Chiyoda-ku, Tokyo 101-8308, Japan

Abstract

Titanium oxide that has photocatalytic activity is used as white pigment for cosmetics. A certain degree of sebum on the skin is decomposed by the ultraviolet radiation in sunlight. In this work, as novel white pigment, titanium phosphates were synthesized with titanium sulfate and phosphoric acid for cosmetics. Their chemical composition, powder properties, photocatalytic activity, color phase, moisture retention, and smoothness were studied. These titanium phosphates had less photocatalytic activity to protect the sebum on the skin. Samples without heating and those heated at 100 ℃ showed high reflectance in the range of visible light. Sample prepared in Ti/P = 3/2 had higher moisture retention than samples prepared in other Ti/P ratios.

Keywords: white pigment, titanium phosphates, photocatalytic activity, smoothness

References(12)

[1]
Diebold U. The surface science of titanium dioxide. Surf Sci Rep 2003, 48: 53–229.
DOI Google Scholar
[2]
Senzui M, Tamura T, Miura K, et al. Study on penetration of titanium dioxide (TiO2) nanoparticles into intact and damaged skin in vitro. J Toxicol Sci 2010, 35: 107–113.
DOI Google Scholar
[3]
Sarkar K, Nandi M, Bhaumik A. Enhancement in microporosity and catalytic activity on grafting silica and organosilica moieties in lamellar titanium phosphate framework. Appl Catal A: Gen 2008, 343: 55–61.
DOI Google Scholar
[4]
Gamer AO, Leibold E, van Ravenzwaay B. The in vitro absorption of microfine zinc oxide and titanium dioxide through porcine skin. Toxicol in Vitro 2006, 20: 301–307.
DOI Google Scholar
[5]
Jones DJ, Aptel G, Brandhorst M, et al. High surface area mesoporous titanium phosphate: Synthesis and surface acidity determination. J Mater Chem 2000, 10: 1957–1963.
DOI Google Scholar
[6]
Bhaumik A, Inagaki S. Mesoporous titanium phosphate molecular sieves with ion-exchange capacity. J Am Chem Soc 2001, 123: 691–696.
DOI Google Scholar
[7]
Dutta A, Patra AK, Dutta S, et al. Hierarchically porous titanium phosphate nanoparticles: An efficient solid acid catalyst for microwave assisted conversion of biomass and carbohydrates into 5-hydroxymethylfurfural. J Mater Chem 2012, 22: 14094–14100.
DOI Google Scholar
[8]
Onoda H, Yamaguchi T. Influence of ultrasonic treatment on preparation and powder properties of titanium phosphates. J Mater Chem 2012, 22: 19826–19830.
DOI Google Scholar
[9]
Onoda H, Yamaguchi T, Takenaka A. Synthesis and pigmental properties of titanium phosphates with the addition of urea. Int J Cosmetic Sci 2012, 34: 86–90.
DOI Google Scholar
[10]
Ramaswamy V, Jagtap NB, Vijayanand S, et al. Photocatalytic decomposition of methylene blue on nanocrystalline titania prepared by different methods. Mater Res Bull 2008, 43: 1145–1152.
DOI Google Scholar
[11]
Du P, Bueno-López A, Verbaas M, et al. The effect of surface OH-population on the photocatalytic activity of rare earth-doped P25-TiO2 in methylene blue degradation. J Catal 2008, 260: 75–80.
DOI Google Scholar
[12]
Cheng SY, Yuen CWM, Kan CW, et al. A comprehensive study of silicone-based cosmetic textile agent. Fiber Polym 2009, 10: 132–140.
DOI Google Scholar
Publication history
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Publication history

Received: 31 December 2013
Revised: 14 March 2014
Accepted: 18 March 2014
Published: 01 June 2014
Issue date: June 2014

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© The author(s) 2014

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Open Access: This article is distributed under the terms of the Creative Commons Attribution License which permits any use, distribution, and reproduction in any medium, provided the original author(s) and the source are credited.

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