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It is possible to fabricate highly sensitive NTCR (negative temperature coefficient of resistance) thermistor using nano crystalline CaTiO3 synthesized by high energy ball milling. Disc shaped green pellets were prepared and effects of sintering on the disc pellets were studied as thermistor by sintering the samples at 1000 ℃, 1100 ℃ and 1200 ℃. The as-prepared samples were characterized by X-ray diffraction (XRD), impedance analysis and electrical measurement. The resistivity of the prepared samples varies predictably with temperature: this makes them promising material for temperature sensor. The experimental results prove that nano crystalline CaTiO3 ceramic is one kind of thermistor with exponential negative temperature coefficient of resistance in the temperature range of 300–500 ℃. The samples have the advantages of rapid response, high sensitivity and capability to withstand thermal surges over the temperature range of 300–500 ℃. Resistance–temperature characteristics are described by thermistor equation with thermistor constant around 4003 K to 10795 K and thermal coefficient of resistance α around -1%/℃ to -13%/℃. The activation energy is in the range of 0.34–0.93 eV. The observed thermistor parameters are found to be comparable with many of the known thermistor materials. This suggests that the electrical properties can be adjusted to desirable values by controlling the temperature parameter. The influence of fabrication process of disc thermistor and electrical properties are discussed. The study shows the potential of nano crystalline CaTiO3 to act as an NTCR material for thermistor applications.


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CaTiO3 nano ceramic for NTCR thermistor based sensor application

Show Author's information Subhanarayan SAHOOa,b( )S. K. S. PARASHARcS. M. ALIa
School of Electrical Engineering, KIIT University, Bhubaneswar-751024, India
Department of Electrical and Electronics Engineering, Trident Academy of Technology, Bhubaneswar-751024, India
School of Applied Sciences, KIIT University, Bhubaneswar-751024, India

Abstract

It is possible to fabricate highly sensitive NTCR (negative temperature coefficient of resistance) thermistor using nano crystalline CaTiO3 synthesized by high energy ball milling. Disc shaped green pellets were prepared and effects of sintering on the disc pellets were studied as thermistor by sintering the samples at 1000 ℃, 1100 ℃ and 1200 ℃. The as-prepared samples were characterized by X-ray diffraction (XRD), impedance analysis and electrical measurement. The resistivity of the prepared samples varies predictably with temperature: this makes them promising material for temperature sensor. The experimental results prove that nano crystalline CaTiO3 ceramic is one kind of thermistor with exponential negative temperature coefficient of resistance in the temperature range of 300–500 ℃. The samples have the advantages of rapid response, high sensitivity and capability to withstand thermal surges over the temperature range of 300–500 ℃. Resistance–temperature characteristics are described by thermistor equation with thermistor constant around 4003 K to 10795 K and thermal coefficient of resistance α around -1%/℃ to -13%/℃. The activation energy is in the range of 0.34–0.93 eV. The observed thermistor parameters are found to be comparable with many of the known thermistor materials. This suggests that the electrical properties can be adjusted to desirable values by controlling the temperature parameter. The influence of fabrication process of disc thermistor and electrical properties are discussed. The study shows the potential of nano crystalline CaTiO3 to act as an NTCR material for thermistor applications.

Keywords: thermistor, CaTiO3, sensitivity index, temperature coefficient

References(26)

[1]
Jagtap S, Rane S, Gosavi S, et al. Study on I–V characteristics of lead free NTC thick film thermistor for self heating application. Microelectron Eng 2011, 88: 82–86.
[2]
Shpotyuk O, Kovalskiy A, Mrooz O, et al. Technological modification of spinel-based CuxNi1–xyCo2yMn2–yO4 ceramics. J Eur Ceram Soc 2001, 21: 2067–2070.
[3]
Metz R. Electrical properties of N.T.C. thermistors made of manganite ceramics of general spinel structure: Mn3−xxMxNxO4 (0 ≤ x + x′ ≤ 1; M and N being Ni, Co or Cu). Aging phenomenon study. J Mater Sci 2000, 35: 4705–4711.
[4]
Nagai T, Itoh M. SiC thin-film thermistor. IEEE T Ind Appl 1990, 26: 1139–1143.
[5]
Jadhav RN, Mathad SN, Puri V. Studies on the properties of Ni0.6Cu0.4Mn2O4 NTC ceramic due to Fe doping. Ceram Int 2012, 38: 5181–5188.
[6]
Nenova ZP, Nenov TG. Linearization circuit of the thermistor connection. IEEE T Instrum Meas 2009, 58: 441–449.
[7]
Edwards L. Selecting NTC thermistors for control applications. Sensors Rev 1988, 8: 205–206.
[8]
Wang CC, Akbar SA, Chen W, et al. High-temperature thermistors based on yttria and calcium zirconate. Sensor Actuat A: Phys 1997, 58: 237–243.
[9]
Steinhart JS, Hart SR. Calibration curves for thermistors. Deep-Sea Res 1968, 15: 497–503.
[10]
Alexander MD, MacQuarrie KTB. Toward standard thermistor calibration method: Data correction spreadsheets. Groundwater Monitoring & Remediation 2005, 25: 75–81.
[11]
Singla ML, Sharma S, Raj B, et al. Characterization of transition metal oxide ceramic material for continuous thermocouple and its use as NTC fire wire sensor. Sensor Actuat A: Phys 2005, 120: 337–342.
[12]
Jagtap S, Rane S, Gosav S, et al. Low-temperature synthesis and characterization of NTC powder and its 'lead free' thick film thermistors. Microelectron Eng 2010, 87: 104–107.
[13]
Jagtap S, Rane S, Gosavi S, et al. Preparation, characterization and electrical properties of spinel-type environment friendly thick film NTC thermistors. J Eur Ceram Soc 2008, 28: 2501–2507.
[14]
Macklen ED. Thermistors. Ayr (Scotland): Electrochemical Publications Ltd., 1979, 19: 188–217.
DOI
[15]
Nenov TG, Yordanov SP. Ceramic Sensors, Technology and Application. Lancaster (USA): Technomic Publishing Company, 1996, 20–42: 134–145.
[16]
Lai PT, Li B, Chan CL, et al. Spreading resistance temperature sensors silicon-on-insulator. IEEE Electr Device L 1999, 20: 589–591.
[17]
Sachse ΗB. Semi-conducting Temperature Sensors and Their Applications. New York: John Wiley & Sons, Inc., 1975.
[18]
Dorris SE, Mason TO. Electrical properties cation vacancies in Mn3O4. J Am Ceram Soc 1988, 71: 379–385.
[19]
Aleksic OS, Nikolic MV, Lukovic MD, et al. Analysis and optimaization of a thermal sensor system for measuring water flow. Sensor Actuat A: Phys 2013, 201: 371–376.
[20]
Luo W, Yao H-M, Yang P-H, et al. Negative temperature coefficient material with low thermal constant and high resistivity for low-temperature thermistor application. J Am Ceram Soc 2009, 92: 2682–2686.
[21]
Zhao C, Zhao Y. The investigation of Zn content on the structure and electrical properties of ZnxCu0.2Ni0.66Mn2.14-xO4 negative temperature coefficient ceramics. J Mater Sci: Mater El 2012, 23: 1788–1792.
[22]
Park K, Lee JK. The effect of ZnO content and sintering temperature on the electrical properties of Cu containing Mn1.95-xNi0.45Co0.15Cu0.45ZnxO4 (0 ≤ x ≤ 0.3) NTC thermistor. J Alloys Compd 2009, 475: 513–517.
[23]
BetaTHERM Sensors. Available at www.betatherm.com.
[24]
Wen S, Wang S, Chung DDL. Carbon fiber structural composites as thermistors. Sensor Actuat A: Phys 1999, 78: 180–188.
[25]
Jagtap S, Rane S, Mulik U, et al. Thick film NTC thermistor for wide range of temperature sensing. Microelectronics International 2007, 24: 7–13.
[26]
Sahoo S, Dash U, Parashar SKS, et al. Frequency and temperature dependent electrical characteristics of CaTiO3 nano-ceramic prepared by high-energy ball milling. J Adv Ceram 2013, 2: 291–300.
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Publication history

Received: 28 November 2013
Revised: 27 February 2014
Accepted: 13 March 2014
Published: 01 June 2014
Issue date: June 2014

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Open Access: This article is distributed under the terms of the Creative Commons Attribution License which permits any use, distribution, and reproduction in any medium, provided the original author(s) and the source are credited.

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