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The SiC/SiC joints were vacuum brazed at 700 ℃, 740 ℃, 780 ℃ and 800 ℃ for 10 min respectively, using Ag–Cu–In–Ti active filler alloy. The microstructure and joining strength of the joints were characterized by electron probe X-ray microanalyser (EPMA), energy dispersive spectroscopy (EDS), transmission electron microscopy (TEM) and four-point bending strength test. The interface of the joints was composed of three parts: SiC substrate, reaction layer and filler alloy. A representative microstructure of the reaction layer: In-containing layer/TiC layer/Ti5Si3 layer was found from the TEM image. The forming of the In-containing layer could be attributed to the crack or delamination of SiC/TiC interface. The In-containing layer intensified the coefficient of thermal expansion (CTE) mismatch of SiC and the reaction layer, and affected the joining strength. With the increase of the reaction layer's thickness, the joining strength firstly increased, then declined, and the maximum four-point bending strength reached 234 MPa.


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Microstructure of reaction layer and its effect on the joining strength of SiC/SiC joints brazed using Ag–Cu–In–Ti alloy

Show Author's information Yan LIU( )Yunzhou ZHUYong YANGXuejian LIUZhengren HUANG
Key Laboratory of High Performance Ceramics and Superfine Microstructure of Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, P.R. China

Abstract

The SiC/SiC joints were vacuum brazed at 700 ℃, 740 ℃, 780 ℃ and 800 ℃ for 10 min respectively, using Ag–Cu–In–Ti active filler alloy. The microstructure and joining strength of the joints were characterized by electron probe X-ray microanalyser (EPMA), energy dispersive spectroscopy (EDS), transmission electron microscopy (TEM) and four-point bending strength test. The interface of the joints was composed of three parts: SiC substrate, reaction layer and filler alloy. A representative microstructure of the reaction layer: In-containing layer/TiC layer/Ti5Si3 layer was found from the TEM image. The forming of the In-containing layer could be attributed to the crack or delamination of SiC/TiC interface. The In-containing layer intensified the coefficient of thermal expansion (CTE) mismatch of SiC and the reaction layer, and affected the joining strength. With the increase of the reaction layer's thickness, the joining strength firstly increased, then declined, and the maximum four-point bending strength reached 234 MPa.

Keywords:

Ag–Cu–In–Ti, SiC/SiC joints, reaction layer, microstructure, joining strength
Received: 10 September 2013 Revised: 31 December 2013 Accepted: 21 January 2014 Published: 05 March 2014 Issue date: March 2014
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Publication history

Received: 10 September 2013
Revised: 31 December 2013
Accepted: 21 January 2014
Published: 05 March 2014
Issue date: March 2014

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© The author(s) 2014

Acknowledgements

The authors gratefully acknowledge the financial support from Chinese Academy of Sciences.

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