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Research Article | Open Access

Transport and physical properties of V2O5–P2O5–B2O3 glasses doped with Dy2O3

Department of Engineering Physics, Shri Hanuman Vyayam Prasarak Mandal’s College of Engineering and Technology, Amravati 444 605, India
Department of Physics, Sant Gadge Baba Amravati University, Amravati 444 602, India
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We investigate the DC transport properties of 60V2O5–5P2O5–(35-x)B2O3xDy2O3 (x = 0.4, 0.6, 0.8, 1.0 and 1.2 mol%) glasses as function of temperature which were prepared using the conventional melt-quenching method. These glasses are characterised by thermo gravimetric-differential thermal analysis (TG-DTA). Activation energy (EDC) is obtained from Arrhenius plots of temperature-dependent DC conductivity, and it is found to be 0.30 eV for high conducting glass. In order to understand the role of Dy2O3 in these glasses, the density and molar volume are investigated. The results show that molar volume of the glass increases with the increasing of Dy2O3 concentration. The ionic conductivity is found to be dominant over the electronic conductivity and varies between 82% and 96%.


Al-Hajry A, Soliman AA, El-Desoky MM. Electrical and thermal properties of semiconducting Fe2O3–Bi2O3–Na2B4O7 glasses. Thermochim Acta 2005, 427: 181-186.
El-Desoky MM, Al-Shahrani A. Variable—Range hopping in Fe2O3–Bi2O3–K2B4O7 glasses. J Mater Sci: Mater El 2005, 16: 221-224.
Al-Hajry A, Tashtoush N, El-Desoky MM. Characterization and transport properties of semiconducting Fe2O3–Bi2O3–Na2B4O7 glasses. Physica B 2005, 368: 51-57.
Saddeek YB, Shaaban ER, Aly KA, et al. Characterization of some lead vanadate glasses. J Alloys Compd 2009, 478: 447-452.
El-Desoky MM. Small polaron transport in V2O5–NiO–TeO2 glasses. J Mater Sci: Mater El 2003, 14: 215-221.
Al-Shahrani A, Al-Hajry A, El-Desoky MM. Non-adiabatic small polaron hopping conduction in sodium borate tungstate glasses. Phys Status Solidi a 2003, 200: 378-387.
El-Desoky MM, Tashtoush NM, Habib MH. Characterization and electrical properties of semiconducting Fe2O3–Bi2O3–K2B4O7 glasses. J Mater Sci: Mater El 2005, 16: 533-539.
El-Desoky MM, Al-Hajry A, Tokunaga M, et al. Effect of sulfur addition on the redox state of iron in iron phosphate glasses. Hyperfine Interact 2004, 156–157: 547-553.
Mahmoud KH, Abdel-Rahim FM, Atef K, et al. Dielectric dispersion in lithim–bismuth–borate glasses. Curr Appl Phys 2011, 11: 55-60.
Terczynska-Madej A, Cholewa-Kowalska K, Laczka M. The effect of silicate network modifiers on colour and electron spectra of transition metal ions. Opt Mater 2010, 32: 1456-1462.
Venkat Reddy P, Laxmi Kanth C, Prasanth Kumar V, et al. Optical and thermoluminescence properties of R2O–RF–B2O3 glass systems doped with MnO. J Non-Cryst Solids 2005, 351: 3752-3759.
Ramesh Babu A, RajyaSree C, Srinivasa Rao P, et al. Vanadyl ions influence on spectroscopic and dielectric properties of glass network. J Mol Struct 2011, 1005: 83-90.
Ramesh Babu A, RajyaSree C, Vinaya Teja PM, et al. Influence of manganese ions on spectroscopic and dielectric properties of LiF–SrO–B2O3 glasses. J Non-Cryst Solids 2012, 358: 1391-1398.
Srinivasa Rao P, Bala Murali Krishna S, Yusub S, et al. Spectroscopic and dielectric investigations of tungsten ions doped zinc bismuth phosphate glass-ceramics. J Mol Struct 2013, 1036: 452-463.
Takahashi H, Karasawa T, Sakuma T, et al. Electrical conduction in the vitreous and crystallized Li2O–V2O5–P2O5 system. Solid State Ionics 2010, 181: 27-32.
Kiran N, Kesavulu CR, Suresh Kumar A, et al. Spectral studies on Cr3+ ions doped in sodium–lead borophosphate glasses. Physica B 2011, 406: 1897-1901.
Kim CE, Hwang HC, Yoon MY, et al. Fabrication of a high lithium ion conducting lithium borosilicate glass. J Non-Cryst Solids 2011, 357: 2863-2867.
Pisarski WA, Goryczka T, Wodecka-Dus B, et al. Structure and properties of rare earth-doped lead borate glasses. Mat Sci Eng B 2005, 122: 94-99.
Qiu J, Igarashi H, Makishima A. Long-lasting phosphorescence in Mn2+:Zn2GeO4 crystallites containing transparent GeO2–B2O3–ZnO glass-ceramics. Sci Technol Adv Mater 2005, 6: 431-434.
Barde RV, Waghuley SA. Study of AC electrical properties of V2O5–P2O5–B2O3–Dy2O3 glasses. Ceram Int 2013, 39: 6303-6311.
Yoon HJ, Jun DH, Yang JH, et al. Carbon dioxide gas sensor using a graphene sheet. Sensor Actuat B: Chem 2011, 157: 310-313.
Sekhon SS, Chandra S. Mixed cation effect in silver borate ion conducting glass. J Mater Sci 1999, 34: 2899-2902.
Das SS, Srivastava V, Singh P. Ionic transport sodium phosphate glasses doped with chloride of Co, Cd and Ag. Indian J Eng Mater Sci 2006, 13: 455-461.
Sheha E. Ionic conductivity and dielectric properties of plasticized PVA0.7(LiBr)0.3(H2SO4)2.7M solid acid membrane and its performance in a magnesium battery. Solid State Ionics 2009, 180: 1575-1579.
Reddy J, Ramesh Ch, Kumar S, et al. Conductivity study of PEO complex with Mg2+ borate glass polymer electrolyte—Its application as electrochemical cell. Int J Appl Engng Res Dindigul 2011, 2: 147-156.
Govindaraj G, Mariappan CR. Synthesis, characterization and ion dynamic studies of NASICON type glasses. Solid State Ionics 2002, 147: 49-59.
Abid M, Et-tabirou M, Taibi M. Structure and DC conductivity of lead sodium ultraphosphate glasses. Mat Sci Eng B 2003, 97: 20-24.
Mansour E, El-Damrawi GM, Moustafa YM, et al. Polaronic conduction in barium borate glasses containing iron oxide. Physica B 2001, 293: 268-275.
Ramadevudu G, Laxmi Srinivasa Rao S, Hameed A, et al. FTIR and some physical properties of alkaline earth borate glasses containing heavy metal oxides. Int J Eng Sci Tech 2011, 3: 6998-7005.
Insiripong S, Chimalawong P, Kaewkhao J, et al. Optical and physical properties of bismuth borate glasses doped with Dy3+. Am J Applied Sci 2011, 8: 574-578.
Bale S, Rahman S. Spectroscopic and physical properties of Bi2O3–B2O3–ZnO–Li2O glasses. Int Sch Res Netw Spectrosc 2012, .
Gedam RS, Deshpande VK. An anomalous enhancement in the electrical conductivity of Li2O: B2O3:Al2O3 glasses. Solid State Ionics 2006, 177: 2589-2592.
Alexander MN, Onorato PIK, Struck CW, et al. Structure of alkali (alumino) silicate glasses: I. Tl+ luminescence and the nonbridging oxygen issue. J Non-Cryst Solids 1986, 79: 137-154.
El-Desoky MM, Ibrahim FA, Mostafa AG, et al. Effect of nanocrystallization on the electrical conductivity enhancement and Mössbauer hyperfine parameters of iron based glasses. Mater Res Bull 2010, 45: 1122-1126.
Abid M, Et-tabirou M, Taibi M. Structure and DC conductivity of lead sodium ultraphosphate glasses. Mat Sci Eng B 2003, 97: 20-24.
Abdel-Baki M, El-Diasty F. Role of oxygen on the optical properties of borate glass doped with ZnO. J Solid State Chem 2011, 184: 2762-2769.
Veeranna Gowda VC, Anavekar RV. Elastic properties and spectroscopic studies of lithium lead borate glasses. Ionics 2004, 10: 103-108.
Silim HA. Composition effect on some physical properties and FTIR spectra of alumino–borate glasses containing lithium, sodium, potassium and barium oxides. Egypt J Solids 2006, 29: 293-301.
Journal of Advanced Ceramics
Pages 246-251
Cite this article:
BARDE RV, WAGHULEY SA. Transport and physical properties of V2O5–P2O5–B2O3 glasses doped with Dy2O3. Journal of Advanced Ceramics, 2013, 2(3): 246-251.








Web of Science






Received: 26 February 2013
Revised: 02 April 2013
Accepted: 26 April 2013
Published: 07 September 2013
© The author(s) 2013

Open Access: This article is distributed under the terms of the Creative Commons Attribution Noncommercial License which permits any noncommercial use, distribution, and reproduction in any medium, provided the original author(s) and source are credited.