AI Chat Paper
Note: Please note that the following content is generated by AMiner AI. SciOpen does not take any responsibility related to this content.
{{lang === 'zh_CN' ? '文章概述' : 'Summary'}}
{{lang === 'en_US' ? '中' : 'Eng'}}
Chat more with AI
Powered by AMiner. Clicking this button will take you away from SciOpen.
Home Journal of Advanced Ceramics Article
PDF (2 MB)
Cite
EndNote(RIS) BibTeX
Collect
Submit Manuscript AI Chat Paper
Show Outline
Outline
Show full outline
Hide outline
Outline
Show full outline
Hide outline
Research Article | Open Access

Effect of the addition of TEOS on the SiC fibers fabricated by electrospinning

Jiayan LI, Panpan CAO, Yi TAN*( ), Lei ZHANG
School of Materials Science and Engineering, Dalian University of Technology, Dalian 116024, China
Show Author Information

Abstract

Polycarbosilane (PCS) has been widely used to fabricate silicon carbide (SiC) fibers via pyrolysis. In this paper, for improving the morphology of SiC fibers, tetraethyl orthosilicate (TEOS, m = 1 g, 3 g and 5 g, respectively) was added into the PCS precursor solution (containing 1.5 g PCS). The continuous fibers have been prepared by electrospinning, and then the SiC fibers were synthesized by calcination at 1300 ℃, 1400 ℃ and 1600 ℃ for 4 h respectively with a heating rate of 10 ℃/min in flowing nitrogen (N2). The morphologies of the fibers were investigated by the scanning electron microscope (SEM) and it could be seen that the crystallinity of the SiC fibers was lower, the length of the SiC fibers was increased, and the diameter was uniform with the increase of the addition amount of TEOS.

Keywords

electrospinningsilicon carbide (SiC)fiberstetraethyl orthosilicate (TEOS)

References

[1]
Ahmadi TS, Wang ZL, Green TC, et al. Shape-controlled synthesis of colloidal platinum nanoparticles. Science 1996, 272: 1924-1925.
Crossref Google Scholar
[2]
Huynh WU, Peng X, Alivisatos AP. CdSe nanocrystal rods/poly (3-hexylthiophene) composite photovoltaic devices. Adv Mater 1999, 11: 923-927.
Crossref
[3]
Chan WCW, Nie S. Quantum dot bioconjugates for ultrasensitive nonisotopic detection. Science 1998, 281: 2016-2018.
Crossref Google Scholar
[4]
Wang ZL, Dai ZR, Gao RP, et al. Side-by-side silicon carbide–silica biaxial nanowires: Synthesis, structure, and mechanical properties. Appl Phys Lett 2000, 77: 3349.
Crossref Google Scholar
[5]
Zhang Y, Nishitani-Gamo M, Xiao C, et al. A novel synthesis method for aligned carbon nanotubes in organic liquids. Jpn J Appl Phys 2002, 41: L408-L411.
Crossref Google Scholar
[6]
Choi H-J, Seong H-K, Lee J-C, et al. Growth and modulation of silicon carbide nanowires. J Cryst Growth 2004, 269: 472-478.
Crossref Google Scholar
[7]
Bootsma GA, Knippenberg WF, Verspui G. Growth of SiC whiskers in the system SiO2–C–H2 nucleated by iron. J Cryst Growth 1971, 11: 297-309.
Crossref Google Scholar
[8]
Wang L, Wada H, Allard LF. Synthesis and characterization of SiC whiskers. J Mater Res 1992, 7: 148-163.
Crossref Google Scholar
[9]
Meng GW, Zhang LD, Mo CM, et al. Preparation of β-SiC nanorods with and without amorphous SiO2 wrapping layers. J Mater Res 1998, 13: 2533-2538.
Crossref Google Scholar
[10]
Zhou XT, Lai HL, Peng HY, et al. Thin β-SiC nanorods and their field emission properties. Chem Phys Lett 2000, 318: 58-62.
Crossref Google Scholar
[11]
Leu I-C, Lu Y-M, Hon M-H. Substrate effect on the preparation of silicon carbide whiskers by chemical vapor deposition. J Cryst Growth 1996, 167: 607-611.
Crossref Google Scholar
[12]
Motojima S, Hasegawa M, Hattori T. Chemical vapour growth of β-SiC whiskers from a gas mixture of Si2Cl6–CH4–H2–Ar. J Cryst Growth 1988, 87: 311-317.
Crossref Google Scholar
[13]
Tang CC, Fan SS, Dang HY, et al. Growth of SiC nanorods prepared by carbon nanotubes-confined reaction. J Cryst Growth 2000, 210: 595-599.
Crossref Google Scholar
[14]
Cheng XZ, Xiao JY, Xie ZF, et al. Research on curing of polycarbosilane fiber and preparation of SiC fiber. J Mater Eng 2004, 1: 29-37 (in Chinese).
Google Scholar
[15]
Zheng CM, Li XD, Wang H, et al. Thermal stability and curing kinetics of polycarbosilane fibers. Trans Nonferrous Met Soc China 2006, 16: 44-48.
Crossref Google Scholar
Journal of Advanced Ceramics
Volume 2 Issue 3,
September 2013
Pages 242-245
DOI: 10.1007/s40145-013-0066-9
Cite this article:
LI J, CAO P, TAN Y, et al. Effect of the addition of TEOS on the SiC fibers fabricated by electrospinning. Journal of Advanced Ceramics, 2013, 2(3): 242-245. https://doi.org/10.1007/s40145-013-0066-9

1002

Views

52

Downloads

3

Crossref

N/A

Web of Science

5

Scopus

0

CSCD

Altmetrics
Received: 02 April 2013
Revised: 24 April 2013
Accepted: 25 April 2013
Published: 07 September 2013
© The author(s) 2013

Open Access: This article is distributed under the terms of the Creative Commons Attribution Noncommercial License which permits any noncommercial use, distribution, and reproduction in any medium, provided the original author(s) and source are credited.
Return